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An experimental investigation to improve the hydrogen production by water photoelectrolysis when cyanin-chloride is used as sensibilizer

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  • Rossi, Federico
  • Nicolini, Andrea

Abstract

This paper deals with an experimental investigation to improve the hydrogen production by water photoelectrolysis. An experimental facility was built: it is mainly constituted by a solar simulator, the photoelectrolytic cell, the electric power supply system and a recirculating and gas sampling hydraulic circuit. Titanium dioxide was chosen as catalyst because of its good photocatalytic efficiency and its high stability to pH variations in watery solutions. Cyanin chloride was tested as sensibilizer: it is a flavonoid, an organic dye, which gives to the watery solution better solar radiation absorption performances. The catalyst and the sensibilizer were deposited on the cathode surface. A sacrificial reducing agent, ethylenediaminetetraacetic acid (EDTA), was also introduced in the solution to reduce the sensibilizer and restore the original conditions. Different radiation power and electrolytic pH conditions were tested in order to verify the proposed arrangements. Results showed a growing in the hydrogen production by the proposed photoelectrolytic arrangements with respect to the performance of a simple electrolysis. Thus, the obtained results showed that this technology has good possibilities of improvement and interesting perspective of future development.

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  • Rossi, Federico & Nicolini, Andrea, 2012. "An experimental investigation to improve the hydrogen production by water photoelectrolysis when cyanin-chloride is used as sensibilizer," Applied Energy, Elsevier, vol. 97(C), pages 763-770.
    • Handle: RePEc:eee:appene:v:97:y:2012:i:c:p:763-770
    DOI: 10.1016/j.apenergy.2011.11.034
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    References listed on IDEAS

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    1. Ni, Meng & Leung, Michael K.H. & Leung, Dennis Y.C. & Sumathy, K., 2007. "A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(3), pages 401-425, April.
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    2. Kang, H.Y. & Wang, H. Paul, 2012. "Cu@C dispersed TiO2 for dye-sensitized solar cell photoanodes," Applied Energy, Elsevier, vol. 100(C), pages 144-147.
    3. Calise, Francesco & Figaj, Rafal Damian & Massarotti, Nicola & Mauro, Alessandro & Vanoli, Laura, 2017. "Polygeneration system based on PEMFC, CPVT and electrolyzer: Dynamic simulation and energetic and economic analysis," Applied Energy, Elsevier, vol. 192(C), pages 530-542.
    4. Rossi, Federico & Pisello, Anna Laura & Nicolini, Andrea & Filipponi, Mirko & Palombo, Massimo, 2014. "Analysis of retro-reflective surfaces for urban heat island mitigation: A new analytical model," Applied Energy, Elsevier, vol. 114(C), pages 621-631.
    5. Antzaras, Andy N. & Lemonidou, Angeliki A., 2022. "Recent advances on materials and processes for intensified production of blue hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
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    9. Wang, Shuofeng & Ji, Changwei & Zhang, Bo & Liu, Xiaolong, 2014. "Lean burn performance of a hydrogen-blended gasoline engine at the wide open throttle condition," Applied Energy, Elsevier, vol. 136(C), pages 43-50.

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