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Cu@C dispersed TiO2 for dye-sensitized solar cell photoanodes

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  • Kang, H.Y.
  • Wang, H. Paul

Abstract

Nanosize copper embedded in the inert carbon shell (Cu@C) prepared by carbonization of Cu2+-β-CD at 573K was dispersed in TiO2. The Cu@C (0.1% and 0.3%) dispersed TiO2 was used in assembling of photoanodes for dye-sensitized solar cells (DSSCs). By small angle X-ray scattering (SAXS) spectroscopy, it is found that the Cu@C dispersed TiO2 having an average Cu diameter of 18.3nm and carbon shell thickness of 3–5nm. Larger Cu nanoparticles having an average diameter of 24.5nm in TiO2 was formed when their carbon shells were steam reformed at 673K. The Cu nanoparticles having a spherical shape are well dispersed in TiO2, which significantly enhance the photo-excited electron transfer for the DSSC. Notably, the Cu dispersed TiO2 photoanode has a greater efficiency than the pure TiO2 one by at least 23%. This work exemplifies a simple and novel alternative to enhance DSSC efficiencies.

Suggested Citation

  • Kang, H.Y. & Wang, H. Paul, 2012. "Cu@C dispersed TiO2 for dye-sensitized solar cell photoanodes," Applied Energy, Elsevier, vol. 100(C), pages 144-147.
    • Handle: RePEc:eee:appene:v:100:y:2012:i:c:p:144-147
    DOI: 10.1016/j.apenergy.2012.03.004
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    Cited by:

    1. Maddah, Hisham A. & Berry, Vikas & Behura, Sanjay K., 2020. "Biomolecular photosensitizers for dye-sensitized solar cells: Recent developments and critical insights," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    2. Santhosh Sivaraj & Rajasekar Rathanasamy & Gobinath Velu Kaliyannan & Hitesh Panchal & Ali Jawad Alrubaie & Mustafa Musa Jaber & Zafar Said & Saim Memon, 2022. "A Comprehensive Review on Current Performance, Challenges and Progress in Thin-Film Solar Cells," Energies, MDPI, vol. 15(22), pages 1-34, November.
    3. Su, Shanhe & Liu, Tie & Wang, Yuan & Chen, Xiaohang & Wang, Jintong & Chen, Jincan, 2014. "Performance optimization analyses and parametric design criteria of a dye-sensitized solar cell thermoelectric hybrid device," Applied Energy, Elsevier, vol. 120(C), pages 16-22.
    4. Duan, Huiling & Xuan, Yimin, 2014. "Enhanced optical absorption of the plasmonic nanoshell suspension based on the solar photocatalytic hydrogen production system," Applied Energy, Elsevier, vol. 114(C), pages 22-29.
    5. Wang, Xiaoyue & Li, Haibo & Liu, Yong & Zhao, Wenxia & Liang, Chaolun & Huang, Hong & Mo, Delin & Liu, Zhong & Yu, Xiao & Deng, Youjun & Shen, Hui, 2012. "Hydrothermal synthesis of well-aligned hierarchical TiO2 tubular macrochannel arrays with large surface area for high performance dye-sensitized solar cells," Applied Energy, Elsevier, vol. 99(C), pages 198-205.
    6. Hug, Hubert & Bader, Michael & Mair, Peter & Glatzel, Thilo, 2014. "Biophotovoltaics: Natural pigments in dye-sensitized solar cells," Applied Energy, Elsevier, vol. 115(C), pages 216-225.

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    Keywords

    Core-shell nanoparticles; Copper; DSSC; SAXS; TiO2;
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