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Production of greenhouse gas free hydrogen by thermocatalytic decomposition of methane – A review

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  • Ashik, U.P.M.
  • Wan Daud, W.M.A.
  • Abbas, Hazzim F.

Abstract

Thermocatalytic decomposition of methane (TCD) is a fully green single step technology for producing hydrogen and nano-carbon. This review studying all development in laboratory-scale research on TCD, especially the recent advances like co-feeding effect and catalyst regeneration for augmenting the productivity of the whole process. Although a great success on the laboratory-scale has been fulfilled, TCD for greenhouse gas (GHG) free hydrogen production is still in its infancy. The need for commercialization of TCD is greater than ever in the present situation of huge GHG emission. TCD usually examined over various kind of catalysts, such as monometallic, bimetallic, trimetallic, combination of metal–metal oxide, carbonaceous and/or metal doped carbon catalysts. Deactivation of catalysts is the prime drawback found in TCD process. Catalyst regeneration and co-feeding of methane with other hydrocarbon are the two solutions put forwarded in accordance to overcome deactivation hurdle. Higher amount of co-feed hydrocarbon in situ produce more amount of highly active carbonaceous deposits which assist further methane decomposition to produce additional hydrogen to a great extent. The methane conversion rate increases with increase in the temperature and decreases with the flow rate in the co-feeding process in a similar manner as observed in normal TCD. The presence of co-components in the post-reaction stream is a key challenge tackled in the co-feeding and regeneration. Hence, this review hypothesizing the integration of hydrogen separation membrane in to methane decomposition reactor for online hydrogen separation.

Suggested Citation

  • Ashik, U.P.M. & Wan Daud, W.M.A. & Abbas, Hazzim F., 2015. "Production of greenhouse gas free hydrogen by thermocatalytic decomposition of methane – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 221-256.
    • Handle: RePEc:eee:rensus:v:44:y:2015:i:c:p:221-256
    DOI: 10.1016/j.rser.2014.12.025
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    References listed on IDEAS

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    1. Nasir Uddin, Md. & Daud, W.M.A. Wan & Abbas, Hazim F., 2013. "Potential hydrogen and non-condensable gases production from biomass pyrolysis: Insights into the process variables," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 204-224.
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    1. Ashik, U.P.M. & Wan Daud, W.M.A. & Hayashi, Jun-ichiro, 2017. "A review on methane transformation to hydrogen and nanocarbon: Relevance of catalyst characteristics and experimental parameters on yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 743-767.
    2. Al -Fatesh, Ahmed Sadeq & Kasim, Samsudeen Olajide & Ibrahim, Ahmed Aidid & Al-Awadi, Abdulrhman S. & Abasaeed, Ahmed Elhag & Fakeeha, Anis H. & Awadallah, Ahmed E., 2020. "Catalytic methane decomposition over ZrO2 supported iron catalysts: Effect of WO3 and La2O3 addition on catalytic activity and stability," Renewable Energy, Elsevier, vol. 155(C), pages 969-978.
    3. Abuseada, Mostafa & Fisher, Timothy S., 2023. "Continuous solar-thermal methane pyrolysis for hydrogen and graphite production by roll-to-roll processing," Applied Energy, Elsevier, vol. 352(C).
    4. Munawar, Muhammad Assad & Khoja, Asif Hussain & Naqvi, Salman Raza & Mehran, Muhammad Taqi & Hassan, Muhammad & Liaquat, Rabia & Dawood, Usama Fida, 2021. "Challenges and opportunities in biomass ash management and its utilization in novel applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    5. Jikai Sun & Rui Tu & Yuchun Xu & Hongyan Yang & Tie Yu & Dong Zhai & Xiuqin Ci & Weiqiao Deng, 2024. "Machine learning aided design of single-atom alloy catalysts for methane cracking," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Hajji, Yassine & Bouteraa, Mourad & ELCafsi, Afif & Belghith, Ali & Bournot, Philippe & Kallel, Ftouh, 2015. "Natural ventilation of hydrogen during a leak in a residential garage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 810-818.
    7. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    8. Feng, Dongdong & Wang, Shizhang & Dong, Heming & Wang, Junjie & Wang, Fuhua & Shang, Qi & Zhao, Yijun & Sun, Shaozeng, 2024. "Mechanism on CMD reaction regulated by supports and promoters of Fe-based catalysts," Energy, Elsevier, vol. 298(C).
    9. Zhang, Xiang & Kätelhön, Arne & Sorda, Giovanni & Helmin, Marta & Rose, Marcus & Bardow, André & Madlener, Reinhard & Palkovits, Regina & Mitsos, Alexander, 2018. "CO2 mitigation costs of catalytic methane decomposition," Energy, Elsevier, vol. 151(C), pages 826-838.
    10. Raza, Jehangeer & Khoja, Asif Hussain & Anwar, Mustafa & Saleem, Faisal & Naqvi, Salman Raza & Liaquat, Rabia & Hassan, Muhammad & Javaid, Rahat & Qazi, Umair Yaqub & Lumbers, Brock, 2022. "Methane decomposition for hydrogen production: A comprehensive review on catalyst selection and reactor systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    11. Mirkarimi, S.M.R. & Bensaid, S. & Negro, V. & Chiaramonti, D., 2023. "Review of methane cracking over carbon-based catalyst for energy and fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    12. Rissman, Jeffrey & Bataille, Chris & Masanet, Eric & Aden, Nate & Morrow, William R. & Zhou, Nan & Elliott, Neal & Dell, Rebecca & Heeren, Niko & Huckestein, Brigitta & Cresko, Joe & Miller, Sabbie A., 2020. "Technologies and policies to decarbonize global industry: Review and assessment of mitigation drivers through 2070," Applied Energy, Elsevier, vol. 266(C).

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