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Solid superacid catalyzed fatty acid methyl esters production from acid oil

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  • Li, Yan
  • Zhang, Xiao-Dong
  • Sun, Li
  • Xu, Min
  • Zhou, Wen-Guang
  • Liang, Xiao-Hui

Abstract

A solid superacid catalyst was evaluated for the production of fatty acid methyl esters (FAMEs) from acid oil containing about 60 wt.% free fatty acids. It was demonstrated that /ZrO2-TiO2/La3+ was an effective catalyst for simultaneous transesterification and esterification. The optimization of reaction parameters was performed, showing that maximum yield of above 90% could be obtained under the conditions that molar ratio of alcohol/oil was 15:1, catalyst amount was 5 wt.%, temperature was 200 °C and duration was 2 h. The catalyst was finally recycled and utilized for five times repeatedly with little loss in activity. The final products purified by molecular distillation were detected by GC-MS. The content of FAMEs reached 96.24%.

Suggested Citation

  • Li, Yan & Zhang, Xiao-Dong & Sun, Li & Xu, Min & Zhou, Wen-Guang & Liang, Xiao-Hui, 2010. "Solid superacid catalyzed fatty acid methyl esters production from acid oil," Applied Energy, Elsevier, vol. 87(7), pages 2369-2373, July.
    • Handle: RePEc:eee:appene:v:87:y:2010:i:7:p:2369-2373
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    1. Li, Yan & Zhang, Xiao-Dong & Sun, Li & Zhang, Jie & Xu, Hai-Peng, 2010. "Fatty acid methyl ester synthesis catalyzed by solid superacid catalyst /ZrO2-TiO2/La3+," Applied Energy, Elsevier, vol. 87(1), pages 156-159, January.
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    1. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    2. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    3. Chattopadhyay, Soham & Sen, Ramkrishna, 2013. "Fuel properties, engine performance and environmental benefits of biodiesel produced by a green process," Applied Energy, Elsevier, vol. 105(C), pages 319-326.
    4. Gong, Shu-wen & Lu, Jing & Wang, Hong-hong & Liu, Li-jun & Zhang, Qian, 2014. "Biodiesel production via esterification of oleic acid catalyzed by picolinic acid modified 12-tungstophosphoric acid," Applied Energy, Elsevier, vol. 134(C), pages 283-289.
    5. Xie, Wenlei & Gao, Chunli & Li, Jiangbo, 2021. "Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites," Renewable Energy, Elsevier, vol. 168(C), pages 927-937.
    6. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
    7. Chattopadhyay, Soham & Karemore, Ankush & Das, Sancharini & Deysarkar, Asoke & Sen, Ramkrishna, 2011. "Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics," Applied Energy, Elsevier, vol. 88(4), pages 1251-1256, April.
    8. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
    9. Chattopadhyay, Soham & Das, Sancharini & Sen, Ramkrishna, 2011. "Rapid and precise estimation of biodiesel by high performance thin layer chromatography," Applied Energy, Elsevier, vol. 88(12), pages 5188-5192.
    10. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    11. Md Sufi Ullah Siddik Bhuyan & Abul Hasnat Md Ashraful Alam & Younghwan Chu & Yong Chan Seo, 2017. "Biodiesel Production Potential from Littered Edible Oil Fraction Using Directly Synthesized S-TiO 2 /MCM-41 Catalyst in Esterification Process via Non-Catalytic Subcritical Hydrolysis," Energies, MDPI, vol. 10(9), pages 1-17, August.
    12. Zhang, Qiaofei & Xie, Wenlei & Li, Jiangbo & Guo, Lihong, 2023. "Bimetallic Zrx-Aly-KIT-6 modified with sulfate as acidic catalyst for biodiesel production from low-grade acidic oils," Renewable Energy, Elsevier, vol. 217(C).
    13. Binhayeeding, Narisa & Klomklao, Sappasith & Prasertsan, Poonsuk & Sangkharak, Kanokphorn, 2020. "Improvement of biodiesel production using waste cooking oil and applying single and mixed immobilised lipases on polyhydroxyalkanoate," Renewable Energy, Elsevier, vol. 162(C), pages 1819-1827.

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