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Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics

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  • Chattopadhyay, Soham
  • Karemore, Ankush
  • Das, Sancharini
  • Deysarkar, Asoke
  • Sen, Ramkrishna

Abstract

The enzymatic production of biodiesel by transesterification of cottonseed oil was studied using low cost crude pancreatic lipase as catalyst in a batch system. The effects of the critical process parameters including water percentage, methanol:oil ratio, enzyme concentration, buffer pH and reaction temperature were determined. Maximum conversion of 75-80% was achieved after 4 h at 37 °C, pH 7.0 and with 1:15 M ratio of oil to methanol, 0.5% (wt of oil) enzyme and water concentration of 5% (wt of oil). Various organic solvents were tested among which a partially polar solvent (t-butanol) was found to be suitable for the reaction. The major fuel characteristics like specific gravity, kinematic viscosity, flash point and calorific value of the 20:80 blends (B20) of the fatty acid methyl esters with petroleum diesel conformed very closely to those of American Society for Testing Materials (ASTM) standards.

Suggested Citation

  • Chattopadhyay, Soham & Karemore, Ankush & Das, Sancharini & Deysarkar, Asoke & Sen, Ramkrishna, 2011. "Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics," Applied Energy, Elsevier, vol. 88(4), pages 1251-1256, April.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:4:p:1251-1256
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    1. Qi, D.H. & Chen, H. & Geng, L.M. & Bian, Y.ZH. & Ren, X.CH., 2010. "Performance and combustion characteristics of biodiesel-diesel-methanol blend fuelled engine," Applied Energy, Elsevier, vol. 87(5), pages 1679-1686, May.
    2. Balat, Mustafa & Balat, Havva, 2010. "Progress in biodiesel processing," Applied Energy, Elsevier, vol. 87(6), pages 1815-1835, June.
    3. Szczęsna Antczak, Mirosława & Kubiak, Aneta & Antczak, Tadeusz & Bielecki, Stanisław, 2009. "Enzymatic biodiesel synthesis – Key factors affecting efficiency of the process," Renewable Energy, Elsevier, vol. 34(5), pages 1185-1194.
    4. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    5. Li, Yan & Zhang, Xiao-Dong & Sun, Li & Xu, Min & Zhou, Wen-Guang & Liang, Xiao-Hui, 2010. "Solid superacid catalyzed fatty acid methyl esters production from acid oil," Applied Energy, Elsevier, vol. 87(7), pages 2369-2373, July.
    6. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
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    Cited by:

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    5. Chattopadhyay, Soham & Sen, Ramkrishna, 2013. "Fuel properties, engine performance and environmental benefits of biodiesel produced by a green process," Applied Energy, Elsevier, vol. 105(C), pages 319-326.
    6. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    7. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    8. Rial, Rafael Cardoso & de Freitas, Osmar Nunes & Nazário, Carlos Eduardo Domingues & Viana, Luíz Henrique, 2020. "Biodiesel from soybean oil using Porcine pancreas lipase immobilized on a new support: p-nitrobenzyl cellulose xanthate," Renewable Energy, Elsevier, vol. 149(C), pages 970-979.
    9. Maleki, Esmat & Aroua, Mohamed Kheireddine & Sulaiman, Nik Meriam Nik, 2013. "Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil," Applied Energy, Elsevier, vol. 104(C), pages 905-909.
    10. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
    11. Chattopadhyay, Soham & Das, Sancharini & Sen, Ramkrishna, 2011. "Rapid and precise estimation of biodiesel by high performance thin layer chromatography," Applied Energy, Elsevier, vol. 88(12), pages 5188-5192.
    12. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    13. Asokan, M.A. & Senthur prabu, S. & Kamesh, Shikhar & Khan, Wasiuddin, 2018. "Performance, combustion and emission characteristics of diesel engine fuelled with papaya and watermelon seed oil bio-diesel/diesel blends," Energy, Elsevier, vol. 145(C), pages 238-245.
    14. Liu, Yun & Li, Chong & Wang, Shihui & Chen, Weiyi, 2014. "Solid-supported microorganism of Burkholderia cenocepacia cultured via solid state fermentation for biodiesel production: Optimization and kinetics," Applied Energy, Elsevier, vol. 113(C), pages 713-721.
    15. Lian, Shuang & Li, Huijuan & Tang, Jinqiang & Tong, Dongmei & Hu, Changwei, 2012. "Integration of extraction and transesterification of lipid from jatropha seeds for the production of biodiesel," Applied Energy, Elsevier, vol. 98(C), pages 540-547.
    16. Lim, Steven & Lee, Keat Teong, 2014. "Investigation of impurity tolerance and thermal stability for biodiesel production from Jatropha curcas L. seeds using supercritical reactive extraction," Energy, Elsevier, vol. 68(C), pages 71-79.
    17. Tran, Dang-Thuan & Chen, Ching-Lung & Chang, Jo-Shu, 2016. "Continuous biodiesel conversion via enzymatic transesterification catalyzed by immobilized Burkholderia lipase in a packed-bed bioreactor," Applied Energy, Elsevier, vol. 168(C), pages 340-350.
    18. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.

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    More about this item

    Keywords

    Biodiesel Enzymatic transesterification Process parameters B20 Fuel characteristics;

    JEL classification:

    • B20 - Schools of Economic Thought and Methodology - - History of Economic Thought since 1925 - - - General

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