IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v88y2011i12p4590-4596.html
   My bibliography  Save this article

Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts

Author

Listed:
  • Peng, Lincai
  • Lin, Lu
  • Li, Hui
  • Yang, Qiulin

Abstract

The catalytic performances of common solid acids (ZSM-5(25), ZSM-5(36), NaY, H-mordenite, Zr3(PO4)4, SO42-/ZrO2, SO42-/TiO2, and TiO2) for the conversion of carbohydrates such as glucose to methyl levulinate in near-critical methanol were investigated to develop an environmentally benign catalyst with high activity. Among these catalysts employed, sulfated metal oxides (especially SO42-/TiO2) were found to be a type of potential catalysts for prospective utilization, which showed remarkably high selectivity and yield of methyl levulinate and had negligible undesired dimethyl ether formation from the dehydration of methanol. With SO42-/TiO2 as the catalyst, methyl levulinate in ca. 43, 33 and 59mol% yields could be obtained from sucrose, glucose and fructose, respectively, at 473K for 2h reaction time with a catalyst loading of 2.5wt.%. The heterogeneous catalyst (SO42-/TiO2) was easily recovered by filtration and exhibited good catalytic activities after calcination in five cycles of reusing. The surface structure and acidity variations of the fresh and recycled SO42-/TiO2 catalysts after calcination were characterized by XRD and NH3-TPD techniques. The results indicate that the catalyst crystallization structure was preserved after multiple cycles, the acid amount and acid strength of the catalyst reduced gradually as the increasing of recycling times.

Suggested Citation

  • Peng, Lincai & Lin, Lu & Li, Hui & Yang, Qiulin, 2011. "Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts," Applied Energy, Elsevier, vol. 88(12), pages 4590-4596.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:12:p:4590-4596
    DOI: 10.1016/j.apenergy.2011.05.049
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191100359X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2011.05.049?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Balat, Mustafa & Balat, Havva, 2010. "Progress in biodiesel processing," Applied Energy, Elsevier, vol. 87(6), pages 1815-1835, June.
    2. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
    3. Li, Yan & Zhang, Xiao-Dong & Sun, Li & Zhang, Jie & Xu, Hai-Peng, 2010. "Fatty acid methyl ester synthesis catalyzed by solid superacid catalyst /ZrO2-TiO2/La3+," Applied Energy, Elsevier, vol. 87(1), pages 156-159, January.
    4. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    5. Fatih Demirbas, M., 2009. "Biorefineries for biofuel upgrading: A critical review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 151-161, November.
    6. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    7. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Ronghua & Zhang, Wenhao & Jiang, Jianchun & Xu, Junming & Wang, Kui & Feng, Junfeng & Pan, Hui, 2024. "Catalytic valorization of biomass carbohydrates into levulinic acid/ester by using bifunctional catalysts," Renewable Energy, Elsevier, vol. 221(C).
    2. Oprescu, Elena-Emilia & Enascuta, Cristina-Emanuela & Doukeh, Rami & Calin, Catalina & Lavric, Vasile, 2021. "Characterizing and using a new bi-functional catalyst to sustainably synthesize methyl levulinate from biomass carbohydrates," Renewable Energy, Elsevier, vol. 176(C), pages 651-662.
    3. Kang, Shimin & Fu, Jinxia & Zhang, Gang, 2018. "From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 340-362.
    4. Hu, Lei & Lin, Lu & Wu, Zhen & Zhou, Shouyong & Liu, Shijie, 2017. "Recent advances in catalytic transformation of biomass-derived 5-hydroxymethylfurfural into the innovative fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 230-257.
    5. Feng, Junfeng & Jiang, Jianchun & Xu, Junming & Yang, Zhongzhi & Wang, Kui & Guan, Qian & Chen, Shuigen, 2015. "Preparation of methyl levulinate from fractionation of direct liquefied bamboo biomass," Applied Energy, Elsevier, vol. 154(C), pages 520-527.
    6. di Bitonto, Luigi & Locaputo, Vito & D'Ambrosio, Valeria & Pastore, Carlo, 2020. "Direct Lewis-Brønsted acid ethanolysis of sewage sludge for production of liquid fuels," Applied Energy, Elsevier, vol. 259(C).
    7. Dookheh, Maryam & Najafi Chermahini, Alireza, 2023. "Surface modified mesoporous KIT-5: A catalytic approach to obtain butyl levulinate from starch," Renewable Energy, Elsevier, vol. 211(C), pages 227-235.
    8. Li, Mengzhu & Wei, Junnan & Yan, Guihua & Liu, Huai & Tang, Xing & Sun, Yong & Zeng, Xianhai & Lei, Tingzhou & Lin, Lu, 2020. "Cascade conversion of furfural to fuel bioadditive ethyl levulinate over bifunctional zirconium-based catalysts," Renewable Energy, Elsevier, vol. 147(P1), pages 916-923.
    9. Tang, Xing & Zeng, Xianhai & Li, Zheng & Hu, Lei & Sun, Yong & Liu, Shijie & Lei, Tingzhou & Lin, Lu, 2014. "Production of γ-valerolactone from lignocellulosic biomass for sustainable fuels and chemicals supply," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 608-620.
    10. Zhao, Weijie & Li, Yingwen & Song, Changhua & Liu, Sijie & Li, Xuehui & Long, Jinxing, 2017. "Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification," Applied Energy, Elsevier, vol. 204(C), pages 1094-1100.
    11. Carlo Pastore & Valeria D’Ambrosio, 2021. "Intensification of Processes for the Production of Ethyl Levulinate Using AlCl 3 ·6H 2 O," Energies, MDPI, vol. 14(5), pages 1-11, February.
    12. Liu, Jie & Wang, Xue-Qian & Yang, Bei-Bei & Liu, Chun-Ling & Xu, Chun-Li & Dong, Wen-Sheng, 2018. "Highly efficient conversion of glucose into methyl levulinate catalyzed by tin-exchanged montmorillonite," Renewable Energy, Elsevier, vol. 120(C), pages 231-240.
    13. Yan, Kai & Jarvis, Cody & Gu, Jing & Yan, Yong, 2015. "Production and catalytic transformation of levulinic acid: A platform for speciality chemicals and fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 986-997.
    14. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    15. Chen, Han & Xu, Qiong & Zhang, Du & Liu, Wenzhu & Liu, Xianxiang & Yin, Dulin, 2021. "Highly efficient synthesis of γ-valerolactone by catalytic conversion of biomass-derived levulinate esters over support-free mesoporous Ni," Renewable Energy, Elsevier, vol. 163(C), pages 1023-1032.
    16. Pan, Hu & Liu, Xiaofang & Zhang, Heng & Yang, Kaili & Huang, Shan & Yang, Song, 2017. "Multi-SO3H functionalized mesoporous polymeric acid catalyst for biodiesel production and fructose-to-biodiesel additive conversion," Renewable Energy, Elsevier, vol. 107(C), pages 245-252.
    17. Yang, Yu & Abu-Omar, Mahdi M. & Hu, Changwei, 2012. "Heteropolyacid catalyzed conversion of fructose, sucrose, and inulin to 5-ethoxymethylfurfural, a liquid biofuel candidate," Applied Energy, Elsevier, vol. 99(C), pages 80-84.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    2. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    3. Feng, Junfeng & Jiang, Jianchun & Xu, Junming & Yang, Zhongzhi & Wang, Kui & Guan, Qian & Chen, Shuigen, 2015. "Preparation of methyl levulinate from fractionation of direct liquefied bamboo biomass," Applied Energy, Elsevier, vol. 154(C), pages 520-527.
    4. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    5. Kumar, Manish & Gayen, Kalyan, 2011. "Developments in biobutanol production: New insights," Applied Energy, Elsevier, vol. 88(6), pages 1999-2012, June.
    6. Demirbas, M. Fatih, 2011. "Biofuels from algae for sustainable development," Applied Energy, Elsevier, vol. 88(10), pages 3473-3480.
    7. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Hazrat, M.A., 2015. "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 331-351.
    8. Chattopadhyay, Soham & Karemore, Ankush & Das, Sancharini & Deysarkar, Asoke & Sen, Ramkrishna, 2011. "Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics," Applied Energy, Elsevier, vol. 88(4), pages 1251-1256, April.
    9. Akroum-Amrouche, Dahbia & Abdi, Nadia & Lounici, Hakim & Mameri, Nabil, 2011. "Effect of physico-chemical parameters on biohydrogen production and growth characteristics by batch culture of Rhodobacter sphaeroides CIP 60.6," Applied Energy, Elsevier, vol. 88(6), pages 2130-2135, June.
    10. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    11. Demirbas, Ayhan, 2011. "Biodiesel from oilgae, biofixation of carbon dioxide by microalgae: A solution to pollution problems," Applied Energy, Elsevier, vol. 88(10), pages 3541-3547.
    12. Chattopadhyay, Soham & Sen, Ramkrishna, 2013. "Fuel properties, engine performance and environmental benefits of biodiesel produced by a green process," Applied Energy, Elsevier, vol. 105(C), pages 319-326.
    13. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    14. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    15. No, Soo-Young, 2011. "Inedible vegetable oils and their derivatives for alternative diesel fuels in CI engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 131-149, January.
    16. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    17. Zhang, Yue & Wong, Wing-Tak & Yung, Ka-Fu, 2014. "Biodiesel production via esterification of oleic acid catalyzed by chlorosulfonic acid modified zirconia," Applied Energy, Elsevier, vol. 116(C), pages 191-198.
    18. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part I," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1427-1445.
    19. Boonyongmaneerat, Yuttanant & Sukjamsri, Chamaiporn & Sahapatsombut, Ukrit & Saenapitak, Sawalee & Sukkasi, Sittha, 2011. "Investigation of electrodeposited Ni-based coatings for biodiesel storage," Applied Energy, Elsevier, vol. 88(3), pages 909-913, March.
    20. Karavalakis, Georgios & Anastopoulos, Georgios & Stournas, Stamos, 2011. "Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils," Applied Energy, Elsevier, vol. 88(11), pages 3645-3650.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:88:y:2011:i:12:p:4590-4596. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.