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Experimental and thermodynamic study on the performance of water electrolysis by solid oxide electrolyzer cells with Nb-doped Co-based perovskite anode

Author

Listed:
  • Pan, Zehua
  • Liu, Qinglin
  • Zhang, Lan
  • Zhou, Juan
  • Zhang, Caizhi
  • Chan, Siew Hwa

Abstract

In this work, Solid Oxide Electrolyzer Cell (SOEC) based on Ba0.9Co0.7Fe0.2Nb0.1O3-δ (BCFN) air electrode and YSZ-GDC bilayer electrolyte was systematically investigated and the efficiency of high-temperature water electrolysis by such a cell was analyzed. Firstly, chemical compatibility test between BCFN and YSZ showed that BaZrO3 formed after heat treatment at 1000°C for 5h, which adversely influenced the performance of BCFN dramatically. A fully dense GDC interlayer was thus developed by co-sintering GDC layer, with addition of 0.5at.% Fe2O3, with YSZ electrolyte at only 1300°C. The as-prepared fuel electrode-supported eletrolyzer cell consisting of Ni-YSZ fuel electrode, YSZ-GDC bilayer electrolyte and BCFN air electrode was evaluated for water electrolysis. Specifically, at 800°C using a feedstock of 60% H2O-40% H2, the cell showed total area specific resistance of 0.195Ωcm2 and the cell voltage was 1.13V with an electrolysis current of 1Acm−2. After short-term stability test for 120h with 1Acm−2 electrolysis current at 800°C, the cell showed no microstructural changes as observed by scanning electron microscopy. At last, a high-temperature water electrolysis system based on the cell studied was proposed and the system analysis shows that the overall electricity to hydrogen efficiency can reach 73% based on lower heating value of hydrogen, with a hydrogen generation rate of 4180Lh−1m−2.

Suggested Citation

  • Pan, Zehua & Liu, Qinglin & Zhang, Lan & Zhou, Juan & Zhang, Caizhi & Chan, Siew Hwa, 2017. "Experimental and thermodynamic study on the performance of water electrolysis by solid oxide electrolyzer cells with Nb-doped Co-based perovskite anode," Applied Energy, Elsevier, vol. 191(C), pages 559-567.
    • Handle: RePEc:eee:appene:v:191:y:2017:i:c:p:559-567
    DOI: 10.1016/j.apenergy.2017.01.090
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    as
    1. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    2. Berg, R.W. & Nikiforov, A.V. & Petrushina, I.M. & Bjerrum, N.J., 2016. "Water vapor pressure over molten KH2PO4 and demonstration of water electrolysis at ∼300°C," Applied Energy, Elsevier, vol. 180(C), pages 269-275.
    3. Ehteshami, Seyyed Mohsen Mousavi & Chan, S.H., 2014. "The role of hydrogen and fuel cells to store renewable energy in the future energy network – potentials and challenges," Energy Policy, Elsevier, vol. 73(C), pages 103-109.
    4. Qu, Jifa & Wang, Wei & Chen, Yubo & Deng, Xiang & Shao, Zongping, 2016. "Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperatures," Applied Energy, Elsevier, vol. 164(C), pages 563-571.
    5. Mo, Jingke & Kang, Zhenye & Yang, Gaoqiang & Retterer, Scott T. & Cullen, David A. & Toops, Todd J. & Green, Johney B. & Zhang, Feng-Yuan, 2016. "Thin liquid/gas diffusion layers for high-efficiency hydrogen production from water splitting," Applied Energy, Elsevier, vol. 177(C), pages 817-822.
    6. Zhou, Juan & Liu, Qinglin & Zhang, Lan & Pan, Zehua & Chan, Siew Hwa, 2016. "Influence of pore former on electrochemical performance of fuel-electrode supported SOFCs manufactured by aqueous-based tape-casting," Energy, Elsevier, vol. 115(P1), pages 149-154.
    7. Ortiz-Vitoriano, N. & Bernuy-López, C. & Ruiz de Larramendi, I. & Knibbe, R. & Thydén, K. & Hauch, A. & Holtappels, P. & Rojo, T., 2013. "Optimizing solid oxide fuel cell cathode processing route for intermediate temperature operation," Applied Energy, Elsevier, vol. 104(C), pages 984-991.
    8. Buonomano, Annamaria & Calise, Francesco & d’Accadia, Massimo Dentice & Palombo, Adolfo & Vicidomini, Maria, 2015. "Hybrid solid oxide fuel cells–gas turbine systems for combined heat and power: A review," Applied Energy, Elsevier, vol. 156(C), pages 32-85.
    9. Stempien, Jan Pawel & Sun, Qiang & Chan, Siew Hwa, 2013. "Performance of power generation extension system based on solid-oxide electrolyzer cells under various design conditions," Energy, Elsevier, vol. 55(C), pages 647-657.
    10. McManus, M.C., 2012. "Environmental consequences of the use of batteries in low carbon systems: The impact of battery production," Applied Energy, Elsevier, vol. 93(C), pages 288-295.
    11. Lei, Libin & Wang, Yao & Fang, Shumin & Ren, Cong & Liu, Tong & Chen, Fanglin, 2016. "Efficient syngas generation for electricity storage through carbon gasification assisted solid oxide co-electrolysis," Applied Energy, Elsevier, vol. 173(C), pages 52-58.
    12. Zhang, Yanwei & Zhu, Qiaoqiao & Lin, Xiangdong & Xu, Zemin & Liu, Jianbo & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2013. "A novel thermochemical cycle for the dissociation of CO2 and H2O using sustainable energy sources," Applied Energy, Elsevier, vol. 108(C), pages 1-7.
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    2. Xing, Xuetao & Lin, Jin & Song, Yonghua & Hu, Qiang & Zhou, You & Mu, Shujun, 2018. "Optimization of hydrogen yield of a high-temperature electrolysis system with coordinated temperature and feed factors at various loading conditions: A model-based study," Applied Energy, Elsevier, vol. 232(C), pages 368-385.
    3. Lane, Blake & Kinnon, Michael Mac & Shaffer, Brendan & Samuelsen, Scott, 2022. "Deployment planning tool for environmentally sensitive heavy-duty vehicles and fueling infrastructure," Energy Policy, Elsevier, vol. 171(C).
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    5. Pan, Zehua & Shen, Jian & Wang, Jingyi & Xu, Xinhai & Chan, Wei Ping & Liu, Siyu & Zhou, Yexin & Yan, Zilin & Jiao, Zhenjun & Lim, Teik-Thye & Zhong, Zheng, 2022. "Thermodynamic analyses of a standalone diesel-fueled distributed power generation system based on solid oxide fuel cells," Applied Energy, Elsevier, vol. 308(C).
    6. Lane, Blake & Shaffer, Brendan & Samuelsen, Scott, 2020. "A comparison of alternative vehicle fueling infrastructure scenarios," Applied Energy, Elsevier, vol. 259(C).
    7. Yang, Gaoqiang & Mo, Jingke & Kang, Zhenye & Dohrmann, Yeshi & List, Frederick A. & Green, Johney B. & Babu, Sudarsanam S. & Zhang, Feng-Yuan, 2018. "Fully printed and integrated electrolyzer cells with additive manufacturing for high-efficiency water splitting," Applied Energy, Elsevier, vol. 215(C), pages 202-210.

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