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Efficiency and stability of hydrogen production from seawater using solid oxide electrolysis cells

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  • Liu, Zhao
  • Han, Beibei
  • Lu, Zhiyi
  • Guan, Wanbing
  • Li, Yuanyuan
  • Song, Changjiang
  • Chen, Liang
  • Singhal, Subhash C.

Abstract

Hydrogen production from seawater electrolysis provides a basis for clean and sustainable development of our energy system. However, in the existing seawater splitting techniques, it is difficult to overcome the damage to electrolyzers by the sea salt. In this work, solid oxide electrolysis was used to split untreated seawater, and its electrochemical performance and long-term stability were studied. The electrolysis was carried out at constant current density of 200 mA/cm−2 for 420 hrs with 183 mL/min hydrogen production and a degradation rate of 4.0%. Energy conversion efficiency of 72.47% was obtained even without reusing the high temperature exhaust gas. After 420 hrs of experiment, it was found that the structure and composition of the cell remained unchanged, showed that long-term operation had no obvious effect on the cell itself. This work shows that the performances of solid oxide electrolysis cell in seawater splitting are excellent, and provides a good choice for energy storage and hydrogen production from seawater.

Suggested Citation

  • Liu, Zhao & Han, Beibei & Lu, Zhiyi & Guan, Wanbing & Li, Yuanyuan & Song, Changjiang & Chen, Liang & Singhal, Subhash C., 2021. "Efficiency and stability of hydrogen production from seawater using solid oxide electrolysis cells," Applied Energy, Elsevier, vol. 300(C).
  • Handle: RePEc:eee:appene:v:300:y:2021:i:c:s0306261921008308
    DOI: 10.1016/j.apenergy.2021.117439
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    References listed on IDEAS

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    Cited by:

    1. Zhao, Kai & Lu, Jiaxin & Le, Long & Coyle, Chris & Marina, Olga A. & Huang, Kevin, 2024. "A high-performance intermediate temperature reversible solid oxide cell with a new barrier layer free oxygen electrode," Applied Energy, Elsevier, vol. 361(C).
    2. Li, Chaolei & Wu, Anqi & Xi, Chengqiao & Guan, Wanbing & Chen, Liang & Singhal, Subhash C., 2022. "High reversible cycling performance of carbon dioxide electrolysis by flat-tube solid oxide cell," Applied Energy, Elsevier, vol. 314(C).
    3. Jahangiri, Mehdi & Rezaei, Mostafa & Mostafaeipour, Ali & Goojani, Afsaneh Raiesi & Saghaei, Hamed & Hosseini Dehshiri, Seyyed Jalaladdin & Hosseini Dehshiri, Seyyed Shahabaddin, 2022. "Prioritization of solar electricity and hydrogen co-production stations considering PV losses and different types of solar trackers: A TOPSIS approach," Renewable Energy, Elsevier, vol. 186(C), pages 889-903.
    4. Nestor F. Guerrero-Rodríguez & Daniel A. De La Rosa-Leonardo & Ricardo Tapia-Marte & Francisco A. Ramírez-Rivera & Juan Faxas-Guzmán & Alexis B. Rey-Boué & Enrique Reyes-Archundia, 2024. "An Overview of the Efficiency and Long-Term Viability of Powered Hydrogen Production," Sustainability, MDPI, vol. 16(13), pages 1-29, June.
    5. Kang, Zhenye & Wang, Hao & Liu, Yanrong & Mo, Jingke & Wang, Min & Li, Jing & Tian, Xinlong, 2022. "Exploring and understanding the internal voltage losses through catalyst layers in proton exchange membrane water electrolysis devices," Applied Energy, Elsevier, vol. 317(C).
    6. Roy, Dibyendu & Samanta, Samiran, 2024. "A solar-assisted power-to-hydrogen system based on proton-conducting solid oxide electrolyzer cells," Renewable Energy, Elsevier, vol. 220(C).

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