IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v325y2022ics0306261922011035.html
   My bibliography  Save this article

Sponge-like form-stable phase change materials with embedded graphene oxide for enhancing the thermal storage efficiency and the temperature response in transport packaging applications

Author

Listed:
  • Wang, Ting
  • Qiu, Xiaolin
  • Chen, Xiaojing
  • Lu, Lixin
  • Zhou, Binglin

Abstract

Hydrated salt-based form-stable phase change materials (FPCMs) with appropriate phase transition temperatures display great potentials in the thermal management of transport packaging. In this study, a series of novel hydrated salt-containing sponge-like FPCMs supported by superporous hydrogel (SPH) was fabricated through a foam polymerization method. N,O-carboxymethyl chitosan (CMCS) and graphene oxide (GO) were chosen as modifiers. The surfaces and inter structures of the FPCMs were examined by scanning electron microscopy (SEM) and optical microscopy (OM). Differential scanning calorimetry (DSC) was used to measure the thermal storage efficiencies of the FPCMs. The temperature responses and the temperature-regulation properties of the FPCMs were tested by a thermal conductivity measurement apparatus, a temperature recorder and an infrared thermography. The mechanical properties of the FPCMs were obtained by a texture analyser. DSC analysis demonstrates that the sponge-like FPCMs with teeming ionic groups can make them load and grasp more PCMs to acquire high energy storage efficiencies. The FPCM with GO&CMCS-modified SPH achieved the highest effective enthalpy percentage (87.8 %) and melting enthalpy (169.0 J/g), which was 43 % higher than that of nonsuperporous hydrogels (NSPH)-supported FPCM without CMC and GO. Meanwhile, the interconnected channels and the enhanced thermal conductivity of the GO-embedded FPCM with SPH led to a 42 % decrease in time to charge when compared with FPCM with NSPH. Besides, the hardness of FPCMs with SPH was remarkable enhanced by over 140 % comparing to FPCMs with NSPH since the internal pores of the SPH could absorb the impact energy. Moreover, the mechanical properties of the FPCMs were further improved when CMCS and GO were incorporated into the matrix. Additionally, thermal images show that the SPH-supported FPCMs, especially modified by CMCS and GO, exhibit a temperature-regulation property, which is beneficial in transport packaging for extending the time to discharge. As a result, the sponge-like FPCMs with embedded GO was an excellent candidate used for energy storage and thermal regulation in transportation.

Suggested Citation

  • Wang, Ting & Qiu, Xiaolin & Chen, Xiaojing & Lu, Lixin & Zhou, Binglin, 2022. "Sponge-like form-stable phase change materials with embedded graphene oxide for enhancing the thermal storage efficiency and the temperature response in transport packaging applications," Applied Energy, Elsevier, vol. 325(C).
    • Handle: RePEc:eee:appene:v:325:y:2022:i:c:s0306261922011035
    DOI: 10.1016/j.apenergy.2022.119832
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261922011035
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2022.119832?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
    2. Kong, Xiangfei & Jiang, Lina & Yuan, Ye & Qiao, Xu, 2022. "Experimental study on the performance of an active novel vertical partition thermal storage wallboard based on composite phase change material with porous silica and microencapsulation," Energy, Elsevier, vol. 239(PE).
    3. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    4. Wang, Lu & Kong, Xiangfei & Ren, Jianlin & Fan, Man & Li, Han, 2022. "Novel hybrid composite phase change materials with high thermal performance based on aluminium nitride and nanocapsules," Energy, Elsevier, vol. 238(PB).
    5. Li, Min & Wu, Zhishen & Tan, Jinmiao, 2012. "Properties of form-stable paraffin/silicon dioxide/expanded graphite phase change composites prepared by sol–gel method," Applied Energy, Elsevier, vol. 92(C), pages 456-461.
    6. Rathod, Manish K. & Banerjee, Jyotirmay, 2013. "Thermal stability of phase change materials used in latent heat energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 246-258.
    7. Li, Gang & Hwang, Yunho & Radermacher, Reinhard & Chun, Ho-Hwan, 2013. "Review of cold storage materials for subzero applications," Energy, Elsevier, vol. 51(C), pages 1-17.
    8. Chen, Renjie & Huang, Xinyu & Deng, Weibin & Zheng, Ruizhi & Aftab, Waseem & Shi, Jinmin & Xie, Delong & Zou, Ruqiang & Mei, Yi, 2020. "Facile preparation of flexible eicosane/SWCNTs phase change films via colloid aggregation for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).
    9. Geng, Xiaoye & Li, Wei & Wang, Yu & Lu, Jiangwei & Wang, Jianping & Wang, Ning & Li, Jianjie & Zhang, Xingxiang, 2018. "Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing," Applied Energy, Elsevier, vol. 217(C), pages 281-294.
    10. Xiao, Qiangqiang & Fan, Jiaxin & Li, Li & Xu, Tao & Yuan, Wenhui, 2018. "Solar thermal energy storage based on sodium acetate trihydrate phase change hydrogels with excellent light-to-thermal conversion performance," Energy, Elsevier, vol. 165(PB), pages 1240-1247.
    11. Liu, Yushi & Yang, Yingzi, 2018. "Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide," Renewable Energy, Elsevier, vol. 115(C), pages 734-740.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Han, Pengju & Yu, Bo & Zhao, Xu & Liu, Changhui & nie, Gao Wei & Chen, Yanfei & Li, Xiang & Shao, Weili & Liu, Fan & He, Jianxin, 2024. "Excellent interfacial compatibility of phase change capsules/polyurethane foam with enhanced mechanical and thermal insulation properties for thermal energy storage," Energy, Elsevier, vol. 294(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yu, Kunyang & Liu, Yushi & Yang, Yingzi, 2021. "Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties," Applied Energy, Elsevier, vol. 292(C).
    2. Khan, Mohammed Mumtaz A. & Saidur, R. & Al-Sulaiman, Fahad A., 2017. "A review for phase change materials (PCMs) in solar absorption refrigeration systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 105-137.
    3. Du, Kun & Calautit, John & Eames, Philip & Wu, Yupeng, 2021. "A state-of-the-art review of the application of phase change materials (PCM) in Mobilized-Thermal Energy Storage (M-TES) for recovering low-temperature industrial waste heat (IWH) for distributed heat," Renewable Energy, Elsevier, vol. 168(C), pages 1040-1057.
    4. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
    5. Li, Yanchen & Wang, Beibei & Zhang, Weiye & Zhao, Junqi & Fang, Xiaoyang & Sun, Jingmeng & Xia, Rongqi & Guo, Hongwu & Liu, Yi, 2022. "Processing wood into a phase change material with high solar-thermal conversion efficiency by introducing stable polyethylene glycol-based energy storage polymer," Energy, Elsevier, vol. 254(PA).
    6. Fan, Man & Hu, Ming & Suo, Hanxiao & Kong, Xiangfei & Li, Han & Jia, Jie, 2024. "Preferred method and performance evaluation of heterogeneous composite phase change material (CPCM) wallboard in different seasons," Renewable Energy, Elsevier, vol. 220(C).
    7. Pitié, F. & Zhao, C.Y. & Baeyens, J. & Degrève, J. & Zhang, H.L., 2013. "Circulating fluidized bed heat recovery/storage and its potential to use coated phase-change-material (PCM) particles," Applied Energy, Elsevier, vol. 109(C), pages 505-513.
    8. Liu, Yushi & Yang, Yingzi, 2018. "Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide," Renewable Energy, Elsevier, vol. 115(C), pages 734-740.
    9. Lazaro, Ana & Peñalosa, Conchita & Solé, Aran & Diarce, Gonzalo & Haussmann, Thomas & Fois, Magali & Zalba, Belén & Gshwander, Stefan & Cabeza, Luisa F., 2013. "Intercomparative tests on phase change materials characterisation with differential scanning calorimeter," Applied Energy, Elsevier, vol. 109(C), pages 415-420.
    10. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    11. Xu, H.J. & Zhao, C.Y., 2016. "Thermal efficiency analysis of the cascaded latent heat/cold storage with multi-stage heat engine model," Renewable Energy, Elsevier, vol. 86(C), pages 228-237.
    12. Parameshwaran, R. & Deepak, K. & Saravanan, R. & Kalaiselvam, S., 2014. "Preparation, thermal and rheological properties of hybrid nanocomposite phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 115(C), pages 320-330.
    13. Chandrasekaran, P. & Cheralathan, M. & Velraj, R., 2015. "Influence of the size of spherical capsule on solidification characteristics of DI (deionized water) water for a cool thermal energy storage system – An experimental study," Energy, Elsevier, vol. 90(P1), pages 807-813.
    14. Su, Weiguang & Darkwa, Jo & Kokogiannakis, Georgios, 2015. "Review of solid–liquid phase change materials and their encapsulation technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 373-391.
    15. Gencel, Osman & Subasi, Serkan & Ustaoglu, Abid & Sarı, Ahmet & Marasli, Muhammed & Hekimoğlu, Gökhan & Kam, Erol, 2022. "Development, characterization and thermo-regulative performance of microencapsulated phase change material included-glass fiber reinforced foam concrete as novel thermal energy effective-building mate," Energy, Elsevier, vol. 257(C).
    16. Qian, Yong & Wei, Ping & Jiang, Pingkai & Li, Zhi & Yan, Yonggang & Liu, Jiping, 2013. "Preparation of a novel PEG composite with halogen-free flame retardant supporting matrix for thermal energy storage application," Applied Energy, Elsevier, vol. 106(C), pages 321-327.
    17. Xu, Huaqian & Zuo, Hongyang & Zeng, Kuo & Lu, Yongwen & Kong, Jiayue & Chi, Bowen & Gao, Junjie & Yang, Haiping & Chen, Hanping, 2023. "The heat transfer enhancement of the converging-diverging tube in the latent heat thermal energy storage unit: Melting performance and evaluation," Energy, Elsevier, vol. 282(C).
    18. M. Mofijur & Teuku Meurah Indra Mahlia & Arridina Susan Silitonga & Hwai Chyuan Ong & Mahyar Silakhori & Muhammad Heikal Hasan & Nandy Putra & S.M. Ashrafur Rahman, 2019. "Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview," Energies, MDPI, vol. 12(16), pages 1-20, August.
    19. Ahn, Jae Hwan & Kim, Hoon & Jeon, Yongseok & Kwon, Ki Hyun, 2022. "Performance characteristics of mobile cooling system utilizing ice thermal energy storage with direct contact discharging for a refrigerated truck," Applied Energy, Elsevier, vol. 308(C).
    20. Soares, N. & Bastos, J. & Pereira, L. Dias & Soares, A. & Amaral, A.R. & Asadi, E. & Rodrigues, E. & Lamas, F.B. & Monteiro, H. & Lopes, M.A.R. & Gaspar, A.R., 2017. "A review on current advances in the energy and environmental performance of buildings towards a more sustainable built environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 845-860.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:325:y:2022:i:c:s0306261922011035. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.