IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v217y2018icp281-294.html
   My bibliography  Save this article

Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing

Author

Listed:
  • Geng, Xiaoye
  • Li, Wei
  • Wang, Yu
  • Lu, Jiangwei
  • Wang, Jianping
  • Wang, Ning
  • Li, Jianjie
  • Zhang, Xingxiang

Abstract

In this study, a series of reversible thermochromic microencapsulated phase change materials (TC-MPCMs), exhibiting excellent latent heat storage-release performance, were designed and fabricated successfully. The characterization and microstructure regulation of TC-MPCMs were conducted systematically as well. The core of TC-MPCMs was comprised of crystal violet lactone employed as thermochromic colorant, bisphenol A employed as developer and 1-tetradecanol employed as co-solvent, respectively. These influencing factors of encapsulation process such as the amount of emulsifier, stirring rate, feeding weight of core/shell ratio, acid resistance and thermal cyclic durability were carried out to clarify the effect of various experimental conditions. The surface morphology, shell thickness and core–shell structure of TC-MPCMs were characterized via optical microscope (OM), thermal field emission scanning electronic microscope (TFE-SEM), transmission electron microscope (TEM), respectively. From different scanning calorimetry (DSC) analysis, the performance of temperature of fusion and crystallization and enthalpy of TC-MPCMs under various conditions were measured as well. The results of thermogravimetric (TG) analysis illustrated the influence on thermal stability of TC-MPCMs. In addition, Lab color space obtained by colorimeter is certainly intuitive to observe the colorimetric characteristics of TC-MPCMs as well. More importantly, the reversible thermochromic property associated with phase state of the 1-tetradecanol could also provide a visual evidence of energy storage or release performance of the TC-MPCMs. Furthermore, The TC-MPCMs exhibited excellent stability even after 100th thermal cycling test without any obvious performance degradation, including the morphology, phase change properties and thermal stability. In the end, the fire fighter protective clothing containing TC-MPCMs was designed and fabricated, which could provide adequate thermal protection in the various fire environments. Thus, TC-MPCMs developed in this work showed great potential applications in thermal protective clothing and other thermal regulation fields.

Suggested Citation

  • Geng, Xiaoye & Li, Wei & Wang, Yu & Lu, Jiangwei & Wang, Jianping & Wang, Ning & Li, Jianjie & Zhang, Xingxiang, 2018. "Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing," Applied Energy, Elsevier, vol. 217(C), pages 281-294.
    • Handle: RePEc:eee:appene:v:217:y:2018:i:c:p:281-294
    DOI: 10.1016/j.apenergy.2018.02.150
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918302800
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.02.150?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chai, Luxiao & Wang, Xiaodong & Wu, Dezhen, 2015. "Development of bifunctional microencapsulated phase change materials with crystalline titanium dioxide shell for latent-heat storage and photocatalytic effectiveness," Applied Energy, Elsevier, vol. 138(C), pages 661-674.
    2. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    3. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2014. "Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials," Applied Energy, Elsevier, vol. 134(C), pages 456-468.
    4. Lashgari, Somayeh & Arabi, Hassan & Mahdavian, Ali Reza & Ambrogi, Veronica, 2017. "Thermal and morphological studies on novel PCM microcapsules containing n-hexadecane as the core in a flexible shell," Applied Energy, Elsevier, vol. 190(C), pages 612-622.
    5. Li, Wei & Zhang, Xing-xiang & Wang, Xue-chen & Tang, Guo-yi & Shi, Hai-feng, 2012. "Fabrication and morphological characterization of microencapsulated phase change materials (MicroPCMs) and macrocapsules containing MicroPCMs for thermal energy storage," Energy, Elsevier, vol. 38(1), pages 249-254.
    6. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    7. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Synthesis, characterization and thermal properties of nanoencapsulated phase change materials via sol–gel method," Energy, Elsevier, vol. 61(C), pages 664-672.
    8. Nomura, Takahiro & Sheng, Nan & Zhu, Chunyu & Saito, Genki & Hanzaki, Daiki & Hiraki, Takehito & Akiyama, Tomohiro, 2017. "Microencapsulated phase change materials with high heat capacity and high cyclic durability for high-temperature thermal energy storage and transportation," Applied Energy, Elsevier, vol. 188(C), pages 9-18.
    9. Ma, Yanjie & Zong, Jiwen & Li, Wei & Chen, Long & Tang, Xiaofen & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2015. "Synthesis and characterization of thermal energy storage microencapsulated n-dodecanol with acrylic polymer shell," Energy, Elsevier, vol. 87(C), pages 86-94.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Ting & Qiu, Xiaolin & Chen, Xiaojing & Lu, Lixin & Zhou, Binglin, 2022. "Sponge-like form-stable phase change materials with embedded graphene oxide for enhancing the thermal storage efficiency and the temperature response in transport packaging applications," Applied Energy, Elsevier, vol. 325(C).
    2. Geng, Xiaoye & Huang, Rui & Zhang, Xingxiang & Li, Wei, 2021. "Research on long-chain alkanol etherified melamine-formaldehyde resin MicroPCMs for energy storage," Energy, Elsevier, vol. 214(C).
    3. Shang, Bofeng & Yang, Gui & Zhang, Bin, 2024. "Phase change nanocapsules incorporated with nanodiamonds for efficient photothermal energy conversion and storage," Applied Energy, Elsevier, vol. 360(C).
    4. Fabiani, C. & Pisello, A.L. & Bou-Zeid, E. & Yang, J. & Cotana, F., 2019. "Adaptive measures for mitigating urban heat islands: The potential of thermochromic materials to control roofing energy balance," Applied Energy, Elsevier, vol. 247(C), pages 155-170.
    5. Sun, Shaofeng & Gao, Yan & Han, Na & Zhang, XingXiang & Li, Wei, 2021. "Reversible photochromic energy storage polyurea microcapsules via in-situ polymerization," Energy, Elsevier, vol. 219(C).
    6. Chen, Renjie & Huang, Xinyu & Deng, Weibin & Zheng, Ruizhi & Aftab, Waseem & Shi, Jinmin & Xie, Delong & Zou, Ruqiang & Mei, Yi, 2020. "Facile preparation of flexible eicosane/SWCNTs phase change films via colloid aggregation for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).
    7. Lin, Yaxue & Zhu, Chuqiao & Alva, Guruprasad & Fang, Guiyin, 2018. "Microencapsulation and thermal properties of myristic acid with ethyl cellulose shell for thermal energy storage," Applied Energy, Elsevier, vol. 231(C), pages 494-501.
    8. Fabiani, C. & Castaldo, V.L. & Pisello, A.L., 2020. "Thermochromic materials for indoor thermal comfort improvement: Finite difference modeling and validation in a real case-study building," Applied Energy, Elsevier, vol. 262(C).
    9. Zhanjun Guo & Sen Liu & Jiali Wang & Yanping Xu & Zhangyang Kang & Jinsheng Zhang, 2024. "Numerical Study of an Energy Storage Container with a Flat Plate Phase Change Unit Characterized by an S-Shaped Flow Channel," Sustainability, MDPI, vol. 16(17), pages 1-15, August.
    10. Zhang, Ya & Liu, Huan & Niu, Jinfei & Wang, Xiaodong & Wu, Dezhen, 2020. "Development of reversible and durable thermochromic phase-change microcapsules for real-time indication of thermal energy storage and management," Applied Energy, Elsevier, vol. 264(C).
    11. Yang, Haiyue & Wang, Siyuan & Wang, Xin & Chao, Weixiang & Wang, Nan & Ding, Xiaolun & Liu, Feng & Yu, Qianqian & Yang, Tinghan & Yang, Zhaolin & Li, Jian & Wang, Chengyu & Li, Guoliang, 2020. "Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage," Applied Energy, Elsevier, vol. 261(C).
    12. Geng, Xiaoye & Li, Wei & Yin, Qing & Wang, Yu & Han, Na & Wang, Ning & Bian, Junmin & Wang, Jianping & Zhang, Xingxiang, 2018. "Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity," Energy, Elsevier, vol. 159(C), pages 857-869.
    13. Tao, Jialu & Luan, Jingde & Liu, Yue & Qu, Daoyu & Yan, Zheng & Ke, Xin, 2022. "Technology development and application prospects of organic-based phase change materials: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    14. Zhang, Long & Zhou, Kechao & Wei, Quiping & Ma, Li & Ye, Wentao & Li, Haichao & Zhou, Bo & Yu, Zhiming & Lin, Cheng-Te & Luo, Jingting & Gan, Xueping, 2019. "Thermal conductivity enhancement of phase change materials with 3D porous diamond foam for thermal energy storage," Applied Energy, Elsevier, vol. 233, pages 208-219.
    15. Li, Min & Zhou, Si, 2024. "Discoloration performance and mechanism research of a novel thermochromic energy storage material," Renewable Energy, Elsevier, vol. 225(C).
    16. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    17. Bashiri Rezaie, Ali & Montazer, Majid, 2020. "Shape-stable thermo-responsive nano Fe3O4/fatty acids/PET composite phase-change material for thermal energy management and saving applications," Applied Energy, Elsevier, vol. 262(C).
    18. Jiang, Liang & Lei, Yuan & Liu, Qinfeng & Lei, Jingxin, 2020. "Polyethylene glycol based self-luminous phase change materials for both thermal and light energy storage," Energy, Elsevier, vol. 193(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Tingyu & Wang, Shuangfeng & Geng, Lixia & Fang, Yutang, 2016. "Enhancement on thermal properties of paraffin/calcium carbonate phase change microcapsules with carbon network," Applied Energy, Elsevier, vol. 179(C), pages 601-608.
    2. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    3. Geng, Xiaoye & Li, Wei & Yin, Qing & Wang, Yu & Han, Na & Wang, Ning & Bian, Junmin & Wang, Jianping & Zhang, Xingxiang, 2018. "Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity," Energy, Elsevier, vol. 159(C), pages 857-869.
    4. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    5. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    6. Nassima Radouane, 2022. "A Comprehensive Review of Composite Phase Change Materials (cPCMs) for Thermal Management Applications, Including Manufacturing Processes, Performance, and Applications," Energies, MDPI, vol. 15(21), pages 1-28, November.
    7. Zhang, Ying & Wang, Xiaodong & Wu, Dezhen, 2016. "Microencapsulation of n-dodecane into zirconia shell doped with rare earth: Design and synthesis of bifunctional microcapsules for photoluminescence enhancement and thermal energy storage," Energy, Elsevier, vol. 97(C), pages 113-126.
    8. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2016. "Magnetic microencapsulated phase change materials with an organo-silica shell: Design, synthesis and application for electromagnetic shielding and thermal regulating polyimide films," Energy, Elsevier, vol. 98(C), pages 225-239.
    9. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.
    10. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Afifi, Amalina Binti Muhammad & Mahlia, Teuku Meurah Indra & Akhiani, Amir Reza & Metselaar, Hendrik Simon Cornelis, 2015. "Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol–gel method," Energy, Elsevier, vol. 85(C), pages 635-644.
    11. Rahimi, M. & Ardahaie, S. Saedi & Hosseini, M.J. & Gorzin, M., 2020. "Energy and exergy analysis of an experimentally examined latent heat thermal energy storage system," Renewable Energy, Elsevier, vol. 147(P1), pages 1845-1860.
    12. Wang, Tingyu & Jiang, Yan & Huang, Jin & Wang, Shuangfeng, 2018. "High thermal conductive paraffin/calcium carbonate phase change microcapsules based composites with different carbon network," Applied Energy, Elsevier, vol. 218(C), pages 184-191.
    13. Gulfam, Raza & Zhang, Peng & Meng, Zhaonan, 2019. "Advanced thermal systems driven by paraffin-based phase change materials – A review," Applied Energy, Elsevier, vol. 238(C), pages 582-611.
    14. Bashiri Rezaie, Ali & Montazer, Majid, 2019. "One-step preparation of magnetically responsive nano CuFe2O4/fatty acids/polyester composite for dynamic thermal energy management applications," Renewable Energy, Elsevier, vol. 143(C), pages 1839-1851.
    15. Yu, Qinghua & Tchuenbou-Magaia, Fideline & Al-Duri, Bushra & Zhang, Zhibing & Ding, Yulong & Li, Yongliang, 2018. "Thermo-mechanical analysis of microcapsules containing phase change materials for cold storage," Applied Energy, Elsevier, vol. 211(C), pages 1190-1202.
    16. Chinnasamy, Veerakumar & Heo, Jaehyeok & Jung, Sungyong & Lee, Hoseong & Cho, Honghyun, 2023. "Shape stabilized phase change materials based on different support structures for thermal energy storage applications–A review," Energy, Elsevier, vol. 262(PB).
    17. Jiang, Binbin & Wang, Xiaodong & Wu, Dezhen, 2017. "Fabrication of microencapsulated phase change materials with TiO2/Fe3O4 hybrid shell as thermoregulatory enzyme carriers: A novel design of applied energy microsystem for bioapplications," Applied Energy, Elsevier, vol. 201(C), pages 20-33.
    18. Chen, J. & Zhang, P., 2017. "Preparation and characterization of nano-sized phase change emulsions as thermal energy storage and transport media," Applied Energy, Elsevier, vol. 190(C), pages 868-879.
    19. Huanmei Yuan & Sitong Liu & Tonghe Li & Liyun Yang & Dehong Li & Hao Bai & Xiaodong Wang, 2024. "Review on Thermal Properties with Influence Factors of Solid–Liquid Organic Phase-Change Micro/Nanocapsules," Energies, MDPI, vol. 17(3), pages 1-51, January.
    20. Wu, Weixiong & Wu, Wei & Wang, Shuangfeng, 2019. "Form-stable and thermally induced flexible composite phase change material for thermal energy storage and thermal management applications," Applied Energy, Elsevier, vol. 236(C), pages 10-21.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:217:y:2018:i:c:p:281-294. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.