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Electrochemical analysis of high-performance protonic ceramic fuel cells based on a columnar-structured thin electrolyte

Author

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  • Choi, Sung Min
  • An, Hyegsoon
  • Yoon, Kyung Joong
  • Kim, Byung-Kook
  • Lee, Hae-Weon
  • Son, Ji-Won
  • Kim, Hyoungchul
  • Shin, Dongwook
  • Ji, Ho-Il
  • Lee, Jong-Ho

Abstract

High-performance and cost-effective fabrications should be simultaneously achieved for practical applications of fuel cells. Unfortunately, protonic ceramic fuel cells, which are considered next-generation solid oxide fuel cells operating at lower temperatures (≤600 °C), do not satisfy the requirements. While thin electrolyte and rapid reactions at electrode/electrolyte interfaces are crucial for cell performance, the thickness of the electrolyte via cost-effective ceramic processes is still not satisfactory (currently capable of >10 μm) and the electrode reaction(s) are yet to be clarified. Here we demonstrate the fabrication of a columnar-structured thin electrolyte (∼2.5 μm) of BaCe0.55Zr0.3Y0.15O3-δ, in which no perpendicular grain boundaries exist against the current direction, through a low-cost screen printing method. A high open-cell voltage of 1.10 V ensures that the thin electrolyte is sufficiently dense for gas-tightness, thereby achieving an extraordinary maximum power density of 350 mW/cm2 at 500 °C. The electrode reactions are investigated by distribution of relaxation time method based on electrochemical impedance spectroscopy as a function of oxygen partial pressure and hydrogen partial pressure at 500 °C, suggesting that the reaction step corresponding to the surface diffusion of an adsorbed oxygen to the triple phase boundaries at the cathode is most probably the main contributor to the overall polarization resistances.

Suggested Citation

  • Choi, Sung Min & An, Hyegsoon & Yoon, Kyung Joong & Kim, Byung-Kook & Lee, Hae-Weon & Son, Ji-Won & Kim, Hyoungchul & Shin, Dongwook & Ji, Ho-Il & Lee, Jong-Ho, 2019. "Electrochemical analysis of high-performance protonic ceramic fuel cells based on a columnar-structured thin electrolyte," Applied Energy, Elsevier, vol. 233, pages 29-36.
  • Handle: RePEc:eee:appene:v:233-234:y:2019:i::p:29-36
    DOI: 10.1016/j.apenergy.2018.10.043
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    References listed on IDEAS

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    1. Sihyuk Choi & Chris J. Kucharczyk & Yangang Liang & Xiaohang Zhang & Ichiro Takeuchi & Ho-Il Ji & Sossina M. Haile, 2018. "Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells," Nature Energy, Nature, vol. 3(3), pages 202-210, March.
    2. Chuancheng Duan & Robert J. Kee & Huayang Zhu & Canan Karakaya & Yachao Chen & Sandrine Ricote & Angelique Jarry & Ethan J. Crumlin & David Hook & Robert Braun & Neal P. Sullivan & Ryan O’Hayre, 2018. "Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells," Nature, Nature, vol. 557(7704), pages 217-222, May.
    3. Kiho Bae & Dong Young Jang & Hyung Jong Choi & Donghwan Kim & Jongsup Hong & Byung-Kook Kim & Jong-Ho Lee & Ji-Won Son & Joon Hyung Shim, 2017. "Demonstrating the potential of yttrium-doped barium zirconate electrolyte for high-performance fuel cells," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
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    Cited by:

    1. Chen, Yu & Lu, Minyi & Yang, Huazheng & Yao, Yingbang & Tao, Tao & Lu, Shengguo & Wang, Chao & Ramesh, Rajendran & Kendall, Michaela & Kendall, Kevin & Ouyang, Xiaoping & Liang, Bo, 2020. "80 Hours operation of a tubular solid oxide fuel cell using propane/air," Applied Energy, Elsevier, vol. 272(C).
    2. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    3. Danilov, Nikolay & Lyagaeva, Julia & Vdovin, Gennady & Medvedev, Dmitry, 2019. "Multifactor performance analysis of reversible solid oxide cells based on proton-conducting electrolytes," Applied Energy, Elsevier, vol. 237(C), pages 924-934.
    4. Shah, M.A.K. Yousaf & Lu, Yuzheng & Mushtaq, Naveed & Yousaf, Muhammad & Akbar, Nabeela & Xia, Chen & Yun, Sining & Zhu, Bin, 2023. "Semiconductor-membrane fuel cell (SMFC) for renewable energy technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).

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