IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v237y2019icp924-934.html
   My bibliography  Save this article

Multifactor performance analysis of reversible solid oxide cells based on proton-conducting electrolytes

Author

Listed:
  • Danilov, Nikolay
  • Lyagaeva, Julia
  • Vdovin, Gennady
  • Medvedev, Dmitry

Abstract

Reversible solid oxide cells (rSOCs) based on proton-conducting electrolytes represent a relatively new and cost-effective possibility for carrying out chemical-to-electrical energy conversion in direct and reverse directions with very high efficiency and low environmental impact. Here we report our findings regarding a modernised approach of rSOC testing, which differs from the traditional characterisation of electrochemical cells, consisting in volt-ampere measurements and impedance spectroscopy analysis under open circuit voltage (OCV) conditions. Expanding the bias range from 0.4 to 1.6 V, the designed rSOC was studied in different (fuel cell, OCV, electrolysis cell) modes and its performance was successfully correlated with ohmic and electrode electrochemical responses depending on the measurement temperature and water vapour partial pressure in oxidant gas. On the basis of this approach, the following new results can be formulated: (i) the ohmic resistance of the proton-conducting electrolytes is a variable parameter depending on the bias in contrast to the convenient oxygen-ionic conductors, for which it is assumed to be a constant; (ii) the electrolyte exhibits predominating proton transport with an activation energy of ∼0.3 eV over the whole bias range; (iii) the output parameters should be correlated with the ohmic and polarisation resistances determined at certain biases (a voltage corresponding to the maximal power density realisation or a thermoneutral voltage) instead of those measured under OCV mode. Concluding, this approach allows the main external factors affecting the rSOC’s performance to be disclosed along with proposed means for its future optimisation in the applied direction.

Suggested Citation

  • Danilov, Nikolay & Lyagaeva, Julia & Vdovin, Gennady & Medvedev, Dmitry, 2019. "Multifactor performance analysis of reversible solid oxide cells based on proton-conducting electrolytes," Applied Energy, Elsevier, vol. 237(C), pages 924-934.
  • Handle: RePEc:eee:appene:v:237:y:2019:i:c:p:924-934
    DOI: 10.1016/j.apenergy.2019.01.054
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191930056X
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2019.01.054?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hedayat, Nader & Du, Yanhai & Ilkhani, Hoda, 2017. "Review on fabrication techniques for porous electrodes of solid oxide fuel cells by sacrificial template methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1221-1239.
    2. Gradisher, Logan & Dutcher, Bryce & Fan, Maohong, 2015. "Catalytic hydrogen production from fossil fuels via the water gas shift reaction," Applied Energy, Elsevier, vol. 139(C), pages 335-349.
    3. Jiang, Jingjing & Ye, Bin & Liu, Junguo, 2019. "Research on the peak of CO2 emissions in the developing world: Current progress and future prospect," Applied Energy, Elsevier, vol. 235(C), pages 186-203.
    4. Scarlat, Nicolae & Dallemand, Jean-François & Fahl, Fernando, 2018. "Biogas: Developments and perspectives in Europe," Renewable Energy, Elsevier, vol. 129(PA), pages 457-472.
    5. Choi, Sung Min & An, Hyegsoon & Yoon, Kyung Joong & Kim, Byung-Kook & Lee, Hae-Weon & Son, Ji-Won & Kim, Hyoungchul & Shin, Dongwook & Ji, Ho-Il & Lee, Jong-Ho, 2019. "Electrochemical analysis of high-performance protonic ceramic fuel cells based on a columnar-structured thin electrolyte," Applied Energy, Elsevier, vol. 233, pages 29-36.
    6. Sihyuk Choi & Chris J. Kucharczyk & Yangang Liang & Xiaohang Zhang & Ichiro Takeuchi & Ho-Il Ji & Sossina M. Haile, 2018. "Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells," Nature Energy, Nature, vol. 3(3), pages 202-210, March.
    7. Mendiara, T. & García-Labiano, F. & Abad, A. & Gayán, P. & de Diego, L.F. & Izquierdo, M.T. & Adánez, J., 2018. "Negative CO2 emissions through the use of biofuels in chemical looping technology: A review," Applied Energy, Elsevier, vol. 232(C), pages 657-684.
    8. Bloess, Andreas & Schill, Wolf-Peter & Zerrahn, Alexander, 2018. "Power-to-heat for renewable energy integration: A review of technologies, modeling approaches, and flexibility potentials," Applied Energy, Elsevier, vol. 212(C), pages 1611-1626.
    9. Bloess, Andreas & Schill, Wolf-Peter & Zerrahn, Alexander, 2018. "Power-to-heat for renewable energy integration: A review of technologies, modeling approaches, and flexibility potentials," Applied Energy, Elsevier, vol. 212(C), pages 1611-1626.
    10. Stoynov, Zdravko & Vladikova, Daria & Burdin, Blagoy & Laurencin, Jerome & Montinaro, Dario & Raikova, Gergana & Schiller, Günter & Szabo, Patric, 2018. "Differential analysis of SOFC current-voltage characteristics," Applied Energy, Elsevier, vol. 228(C), pages 1584-1590.
    11. Hossain, Shahzad & Abdalla, Abdalla M. & Jamain, Siti Noorazean Binti & Zaini, Juliana Hj & Azad, Abul K., 2017. "A review on proton conducting electrolytes for clean energy and intermediate temperature-solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 750-764.
    12. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    13. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    14. Kiho Bae & Dong Young Jang & Hyung Jong Choi & Donghwan Kim & Jongsup Hong & Byung-Kook Kim & Jong-Ho Lee & Ji-Won Son & Joon Hyung Shim, 2017. "Demonstrating the potential of yttrium-doped barium zirconate electrolyte for high-performance fuel cells," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chang, Wanhyuk & Kang, Eun Heui & Jeong, Heon Jun & Choi, Wonjoon & Shim, Joon Hyung, 2023. "Inkjet printing of perovskite ceramics for high-performance proton ceramic fuel cells," Energy, Elsevier, vol. 268(C).
    2. de Guibert, Paul & Shirizadeh, Behrang & Quirion, Philippe, 2020. "Variable time-step: A method for improving computational tractability for energy system models with long-term storage," Energy, Elsevier, vol. 213(C).
    3. Stančin, H. & Mikulčić, H. & Wang, X. & Duić, N., 2020. "A review on alternative fuels in future energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    4. Østergaard, P.A. & Lund, H. & Thellufsen, J.Z. & Sorknæs, P. & Mathiesen, B.V., 2022. "Review and validation of EnergyPLAN," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    5. Gerbaulet, Clemens & von Hirschhausen, Christian & Kemfert, Claudia & Lorenz, Casimir & Oei, Pao-Yu, 2019. "European electricity sector decarbonization under different levels of foresight," EconStor Open Access Articles and Book Chapters, ZBW - Leibniz Information Centre for Economics, vol. 141, pages 973-987.
    6. Sihvonen, Ville & Ollila, Iisa & Jaanto, Jasmin & Grönman, Aki & Honkapuro, Samuli & Riikonen, Juhani & Price, Alisdair, 2024. "Role of power-to-heat and thermal energy storage in decarbonization of district heating," Energy, Elsevier, vol. 305(C).
    7. Guelpa, Elisa & Bischi, Aldo & Verda, Vittorio & Chertkov, Michael & Lund, Henrik, 2019. "Towards future infrastructures for sustainable multi-energy systems: A review," Energy, Elsevier, vol. 184(C), pages 2-21.
    8. Vassilis M. Charitopoulos & Mathilde Fajardy & Chi Kong Chyong & David M. Reiner, 2022. "The case of 100% electrification of domestic heat in Great Britain," Working Papers EPRG2206, Energy Policy Research Group, Cambridge Judge Business School, University of Cambridge.
    9. Shirizadeh, Behrang & Quirion, Philippe, 2022. "The importance of renewable gas in achieving carbon-neutrality: Insights from an energy system optimization model," Energy, Elsevier, vol. 255(C).
    10. Zhang, Menglin & Wu, Qiuwei & Wen, Jinyu & Pan, Bo & Qi, Shiqiang, 2020. "Two-stage stochastic optimal operation of integrated electricity and heat system considering reserve of flexible devices and spatial-temporal correlation of wind power," Applied Energy, Elsevier, vol. 275(C).
    11. Sara Bellocchi & Michele Manno & Michel Noussan & Michela Vellini, 2019. "Impact of Grid-Scale Electricity Storage and Electric Vehicles on Renewable Energy Penetration: A Case Study for Italy," Energies, MDPI, vol. 12(7), pages 1-32, April.
    12. Fridgen, Gilbert & Keller, Robert & Körner, Marc-Fabian & Schöpf, Michael, 2020. "A holistic view on sector coupling," Energy Policy, Elsevier, vol. 147(C).
    13. Zhao, Yongliang & Song, Jian & Liu, Ming & Zhao, Yao & Olympios, Andreas V. & Sapin, Paul & Yan, Junjie & Markides, Christos N., 2022. "Thermo-economic assessments of pumped-thermal electricity storage systems employing sensible heat storage materials," Renewable Energy, Elsevier, vol. 186(C), pages 431-456.
    14. Stefan Arens & Sunke Schlüters & Benedikt Hanke & Karsten von Maydell & Carsten Agert, 2020. "Sustainable Residential Energy Supply: A Literature Review-Based Morphological Analysis," Energies, MDPI, vol. 13(2), pages 1-28, January.
    15. Minjae Son & Minsoo Kim & Hongseok Kim, 2023. "Sector Coupling and Migration towards Carbon-Neutral Power Systems," Energies, MDPI, vol. 16(4), pages 1-12, February.
    16. Els van der Roest & Stijn Beernink & Niels Hartog & Jan Peter van der Hoek & Martin Bloemendal, 2021. "Towards Sustainable Heat Supply with Decentralized Multi-Energy Systems by Integration of Subsurface Seasonal Heat Storage," Energies, MDPI, vol. 14(23), pages 1-31, November.
    17. Odland, Severin & Rhodes, Ekaterina & Corbett, Meghan & Pardy, Aaron, 2023. "What policies do homeowners prefer for building decarbonization and why? An exploration of climate policy support in Canada," Energy Policy, Elsevier, vol. 173(C).
    18. Ruhnau, Oliver & Hirth, Lion & Praktiknjo, Aaron, 2020. "Heating with wind: Economics of heat pumps and variable renewables," Energy Economics, Elsevier, vol. 92(C).
    19. Vicente Gutiérrez González & Germán Ramos Ruiz & Carlos Fernández Bandera, 2021. "Impact of Actual Weather Datasets for Calibrating White-Box Building Energy Models Base on Monitored Data," Energies, MDPI, vol. 14(4), pages 1-16, February.
    20. Hou, Hui & Xu, Tao & Wu, Xixiu & Wang, Huan & Tang, Aihong & Chen, Yangyang, 2020. "Optimal capacity configuration of the wind-photovoltaic-storage hybrid power system based on gravity energy storage system," Applied Energy, Elsevier, vol. 271(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:237:y:2019:i:c:p:924-934. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.