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Surface restructuring of a perovskite-type air electrode for reversible protonic ceramic electrochemical cells

Author

Listed:
  • Kai Pei

    (South China University of Technology)

  • Yucun Zhou

    (Georgia Institute of Technology)

  • Kang Xu

    (South China University of Technology)

  • Hua Zhang

    (South China University of Technology)

  • Yong Ding

    (Georgia Institute of Technology)

  • Bote Zhao

    (South China University of Technology)

  • Wei Yuan

    (Georgia Institute of Technology
    South China University of Technology)

  • Kotaro Sasaki

    (Brookhaven National Laboratory)

  • YongMan Choi

    (National Yang Ming Chiao Tung University)

  • Yu Chen

    (South China University of Technology
    South China University of Technology, Guangzhou Higher Education Mega Centre)

  • Meilin Liu

    (Georgia Institute of Technology)

Abstract

Reversible protonic ceramic electrochemical cells (R-PCECs) are ideally suited for efficient energy storage and conversion; however, one of the limiting factors to high performance is the poor stability and insufficient electrocatalytic activity for oxygen reduction and evolution of the air electrode exposed to the high concentration of steam. Here we report our findings in enhancing the electrochemical activity and durability of a perovskite-type air electrode, Ba0.9Co0.7Fe0.2Nb0.1O3-δ (BCFN), via a water-promoted surface restructuring process. Under properly-controlled operating conditions, the BCFN electrode is naturally restructured to an Nb-rich BCFN electrode covered with Nb-deficient BCFN nanoparticles. When used as the air electrode for a fuel-electrode-supported R-PCEC, good performances are demonstrated at 650 °C, achieving a peak power density of 1.70 W cm−2 in the fuel cell mode and a current density of 2.8 A cm−2 at 1.3 V in the electrolysis mode while maintaining reasonable Faradaic efficiencies and promising durability.

Suggested Citation

  • Kai Pei & Yucun Zhou & Kang Xu & Hua Zhang & Yong Ding & Bote Zhao & Wei Yuan & Kotaro Sasaki & YongMan Choi & Yu Chen & Meilin Liu, 2022. "Surface restructuring of a perovskite-type air electrode for reversible protonic ceramic electrochemical cells," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29866-5
    DOI: 10.1038/s41467-022-29866-5
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    References listed on IDEAS

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    Cited by:

    1. Ze Liu & Yufei Song & Xiaolu Xiong & Yuxuan Zhang & Jingzeng Cui & Jianqiu Zhu & Lili Li & Jing Zhou & Chuan Zhou & Zhiwei Hu & Guntae Kim & Francesco Ciucci & Zongping Shao & Jian-Qiang Wang & Linjua, 2023. "Sintering-induced cation displacement in protonic ceramics and way for its suppression," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Lei, Libin & Mo, Yingyu & Huang, Yue & Qiu, Ruiming & Tian, Zhipeng & Wang, Junyao & Liu, Jianping & Chen, Ying & Zhang, Jihao & Tao, Zetian & Liang, Bo & Wang, Chao, 2023. "Revealing and quantifying the role of oxygen-ionic current in proton-conducting solid oxide fuel cells: A modeling study," Energy, Elsevier, vol. 276(C).
    3. Marshet Getaye Sendeku & Karim Harrath & Fekadu Tsegaye Dajan & Binglan Wu & Sabir Hussain & Ning Gao & Xueying Zhan & Ying Yang & Zhenxing Wang & Chen Chen & Weiqiang Liu & Fengmei Wang & Haohong Dua, 2024. "Deciphering in-situ surface reconstruction in two-dimensional CdPS3 nanosheets for efficient biomass hydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Zuoqing Liu & Yuesheng Bai & Hainan Sun & Daqin Guan & Wenhuai Li & Wei-Hsiang Huang & Chih-Wen Pao & Zhiwei Hu & Guangming Yang & Yinlong Zhu & Ran Ran & Wei Zhou & Zongping Shao, 2024. "Synergistic dual-phase air electrode enables high and durable performance of reversible proton ceramic electrochemical cells," Nature Communications, Nature, vol. 15(1), pages 1-15, December.

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