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Synergistic dual-phase air electrode enables high and durable performance of reversible proton ceramic electrochemical cells

Author

Listed:
  • Zuoqing Liu

    (Nanjing Tech University)

  • Yuesheng Bai

    (Nanjing Tech University)

  • Hainan Sun

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Daqin Guan

    (The Hong Kong Polytechnic University)

  • Wenhuai Li

    (Nanjing Tech University)

  • Wei-Hsiang Huang

    (National Synchrotron Radiation Research Center)

  • Chih-Wen Pao

    (National Synchrotron Radiation Research Center)

  • Zhiwei Hu

    (Max-Planck-Institute for Chemical Physics of Solids)

  • Guangming Yang

    (Nanjing Tech University)

  • Yinlong Zhu

    (Nanjing University of Aeronautics and Astronautics)

  • Ran Ran

    (Nanjing Tech University)

  • Wei Zhou

    (Nanjing Tech University)

  • Zongping Shao

    (Nanjing Tech University
    Curtin University)

Abstract

Reversible proton ceramic electrochemical cells are promising solid-state ion devices for efficient power generation and energy storage, but necessitate effective air electrodes to accelerate the commercial application. Here, we construct a triple-conducting hybrid electrode through a stoichiometry tuning strategy, composed of a cubic phase Ba0.5Sr0.5Co0.8Fe0.2O3−δ and a hexagonal phase Ba4Sr4(Co0.8Fe0.2)4O16−δ. Unlike the common method of creating self-assembled hybrids by breaking through material tolerance limits, the strategy of adjusting the stoichiometric ratio of the A-site/B-site not only achieves strong interactions between hybrid phases, but also can efficiently modifies the phase contents. When operate as an air electrode for reversible proton ceramic electrochemical cell, the hybrid electrode with unique dual-phase synergy shows excellent electrochemical performance with a current density of 3.73 A cm−2 @ 1.3 V in electrolysis mode and a peak power density of 1.99 W cm−2 in fuel cell mode at 650 °C.

Suggested Citation

  • Zuoqing Liu & Yuesheng Bai & Hainan Sun & Daqin Guan & Wenhuai Li & Wei-Hsiang Huang & Chih-Wen Pao & Zhiwei Hu & Guangming Yang & Yinlong Zhu & Ran Ran & Wei Zhou & Zongping Shao, 2024. "Synergistic dual-phase air electrode enables high and durable performance of reversible proton ceramic electrochemical cells," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44767-5
    DOI: 10.1038/s41467-024-44767-5
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    References listed on IDEAS

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    1. Zongping Shao & Sossina M. Haile, 2004. "A high-performance cathode for the next generation of solid-oxide fuel cells," Nature, Nature, vol. 431(7005), pages 170-173, September.
    2. Daqin Guan & Gihun Ryu & Zhiwei Hu & Jing Zhou & Chung-Li Dong & Yu-Cheng Huang & Kaifeng Zhang & Yijun Zhong & Alexander C. Komarek & Ming Zhu & Xinhao Wu & Chih-Wen Pao & Chung-Kai Chang & Hong-Ji L, 2020. "Utilizing ion leaching effects for achieving high oxygen-evolving performance on hybrid nanocomposite with self-optimized behaviors," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Houfu Lv & Le Lin & Xiaomin Zhang & Rongtan Li & Yuefeng Song & Hiroaki Matsumoto & Na Ta & Chaobin Zeng & Qiang Fu & Guoxiong Wang & Xinhe Bao, 2021. "Promoting exsolution of RuFe alloy nanoparticles on Sr2Fe1.4Ru0.1Mo0.5O6−δ via repeated redox manipulations for CO2 electrolysis," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Kai Pei & Yucun Zhou & Kang Xu & Hua Zhang & Yong Ding & Bote Zhao & Wei Yuan & Kotaro Sasaki & YongMan Choi & Yu Chen & Meilin Liu, 2022. "Surface restructuring of a perovskite-type air electrode for reversible protonic ceramic electrochemical cells," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Sihyuk Choi & Chris J. Kucharczyk & Yangang Liang & Xiaohang Zhang & Ichiro Takeuchi & Ho-Il Ji & Sossina M. Haile, 2018. "Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells," Nature Energy, Nature, vol. 3(3), pages 202-210, March.
    6. Chuancheng Duan & Robert Kee & Huayang Zhu & Neal Sullivan & Liangzhu Zhu & Liuzhen Bian & Dylan Jennings & Ryan O’Hayre, 2019. "Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production," Nature Energy, Nature, vol. 4(3), pages 230-240, March.
    7. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    8. Wenjuan Bian & Wei Wu & Baoming Wang & Wei Tang & Meng Zhou & Congrui Jin & Hanping Ding & Weiwei Fan & Yanhao Dong & Ju Li & Dong Ding, 2022. "Revitalizing interface in protonic ceramic cells by acid etch," Nature, Nature, vol. 604(7906), pages 479-485, April.
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