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A novel thermochemical cycle for the dissociation of CO2 and H2O using sustainable energy sources

Author

Listed:
  • Zhang, Yanwei
  • Zhu, Qiaoqiao
  • Lin, Xiangdong
  • Xu, Zemin
  • Liu, Jianbo
  • Wang, Zhihua
  • Zhou, Junhu
  • Cen, Kefa

Abstract

A novel thermochemical cycle, which uses alternative energy sources (such as solar, geothermal, and safe nuclear) to dissociate CO2 and H2O, is proposed. The cycle can effectively reduce CO2 emission from the combustion of fossil fuels. The products of the cycle include carbon monoxide, hydrogen and oxygen. Carbon monoxide and hydrogen can be used to synthesize hydrocarbons and liquid fuels. Oxygen can be used in oxy-fuel combustion. The proposed chemical reactions are performed to validate the cycle effectiveness and superiority. Experiments are conducted to investigate and characterize the reactive chemical systems. The maximum theoretical energy conversion efficiency of the cycle reaches 43.5%.

Suggested Citation

  • Zhang, Yanwei & Zhu, Qiaoqiao & Lin, Xiangdong & Xu, Zemin & Liu, Jianbo & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2013. "A novel thermochemical cycle for the dissociation of CO2 and H2O using sustainable energy sources," Applied Energy, Elsevier, vol. 108(C), pages 1-7.
    • Handle: RePEc:eee:appene:v:108:y:2013:i:c:p:1-7
    DOI: 10.1016/j.apenergy.2013.03.019
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    References listed on IDEAS

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    Citations

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    Cited by:

    1. Zhao, Chuanwen & Guo, Yafei & Li, Changhai & Lu, Shouxiang, 2014. "Removal of low concentration CO2 at ambient temperature using several potassium-based sorbents," Applied Energy, Elsevier, vol. 124(C), pages 241-247.
    2. Zhang, Yanwei & Xu, Chenyu & Chen, Jingche & Zhang, Xuhan & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "A novel photo-thermochemical cycle for the dissociation of CO2 using solar energy," Applied Energy, Elsevier, vol. 156(C), pages 223-229.
    3. Nguyen, Thanh D.B. & Gho, Yun-Ki & Cho, Won Chul & Kang, Kyoung Soo & Jeong, Seong Uk & Kim, Chang Hee & Park, Chu-Sik & Bae, Ki-Kwang, 2014. "Kinetics and modeling of hydrogen iodide decomposition for a bench-scale sulfur–iodine cycle," Applied Energy, Elsevier, vol. 115(C), pages 531-539.
    4. Marias, Foivos & Neveu, Pierre & Tanguy, Gwennyn & Papillon, Philippe, 2014. "Thermodynamic analysis and experimental study of solid/gas reactor operating in open mode," Energy, Elsevier, vol. 66(C), pages 757-765.
    5. Pan, Zehua & Liu, Qinglin & Zhang, Lan & Zhou, Juan & Zhang, Caizhi & Chan, Siew Hwa, 2017. "Experimental and thermodynamic study on the performance of water electrolysis by solid oxide electrolyzer cells with Nb-doped Co-based perovskite anode," Applied Energy, Elsevier, vol. 191(C), pages 559-567.
    6. Zhang, Yanwei & Yang, Hui & Zhou, Junhu & Wang, Zhihua & Liu, Jianzhong & Cen, Kefa, 2014. "Detailed kinetic modeling of homogeneous H2SO4 decomposition in the sulfur–iodine cycle for hydrogen production," Applied Energy, Elsevier, vol. 130(C), pages 396-402.

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