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CO2 abatement from the iron and steel industry using a combined Ca–Fe chemical loop

Author

Listed:
  • Tian, Sicong
  • Li, Kaimin
  • Jiang, Jianguo
  • Chen, Xuejing
  • Yan, Feng

Abstract

We report an integrated CO2 capture process to manufacture iron and steel with low CO2 emissions from steel-making plants over a CaO-based, Fe-functionalized CO2 sorbent. This new process relies on a combined Ca–Fe chemical loop, where the exothermic oxidation of FeO provides the heat (or fractions of it) required to drive the endothermic decomposition of CaCO3. A key advantage of coupling a FeO/Fe2O3 redox cycle and a CaO/CaCO3 CO2 capture cycle within the as-prepared materials is that the heat could be transferred from FeO to CaCO3 directly at a molecular level. All materials synthesized require an appreciably reduced net heat, i.e. a decrease of 26–43%, for CaCO3 decomposition during the combined Ca–Fe looping when compared with conventional calcium looping. Importantly, materials CaFe-CA1EG1-pH1, CaFe-CA1EG1-pH2, and CaFe-CA1EG1-pH3 exhibit a fairly stable cyclic CO2 uptake of ∼0.16gCO2gsorbent−1 throughout 10 realistic combined Ca–Fe looping cycles. The medium capacity but excellent stability for CO2 capture of the CO2 sorbents makes them a promising alternative of naturally-derived, CaO-based materials, especially for the combined Ca–Fe chemical loop proposed. Using steel slag as feedstock, the material developed is very promising for CO2 abatement from the iron and steel industry accompanied by the recycling of CaO and Fe2O3 components in spent sorbents and recovery of energy from process gases.

Suggested Citation

  • Tian, Sicong & Li, Kaimin & Jiang, Jianguo & Chen, Xuejing & Yan, Feng, 2016. "CO2 abatement from the iron and steel industry using a combined Ca–Fe chemical loop," Applied Energy, Elsevier, vol. 170(C), pages 345-352.
  • Handle: RePEc:eee:appene:v:170:y:2016:i:c:p:345-352
    DOI: 10.1016/j.apenergy.2016.02.120
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    References listed on IDEAS

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    1. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A., 2014. "Calcium-looping for post-combustion CO2 capture. On the adverse effect of sorbent regeneration under CO2," Applied Energy, Elsevier, vol. 126(C), pages 161-171.
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    5. Perejón, Antonio & Romeo, Luis M. & Lara, Yolanda & Lisbona, Pilar & Martínez, Ana & Valverde, Jose Manuel, 2016. "The Calcium-Looping technology for CO2 capture: On the important roles of energy integration and sorbent behavior," Applied Energy, Elsevier, vol. 162(C), pages 787-807.
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    7. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A., 2014. "Role of precalcination and regeneration conditions on postcombustion CO2 capture in the Ca-looping technology," Applied Energy, Elsevier, vol. 136(C), pages 347-356.
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    Citations

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    Cited by:

    1. An, Runying & Yu, Biying & Li, Ru & Wei, Yi-Ming, 2018. "Potential of energy savings and CO2 emission reduction in China’s iron and steel industry," Applied Energy, Elsevier, vol. 226(C), pages 862-880.
    2. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    3. Xu, Bin & Lin, Boqiang, 2017. "Assessing CO2 emissions in China's iron and steel industry: A nonparametric additive regression approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 325-337.
    4. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    5. Liu, Shuai & Xiang, Dong & Xu, Ying & Sun, Zhe & Cao, Yan, 2017. "Relationship between electronic properties of Fe3O4 substituted by Ca and Ba and their reactivity in chemical looping process: A first-principles study," Applied Energy, Elsevier, vol. 202(C), pages 550-557.
    6. Ma, Xiaotong & Li, Yingjie & Duan, Lunbo & Anthony, Edward & Liu, Hantao, 2018. "CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions," Applied Energy, Elsevier, vol. 225(C), pages 402-412.

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