IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v145y2015icp27-35.html
   My bibliography  Save this article

Experimental study on full-scale ZrCo and depleted uranium beds applied for fast recovery and delivery of hydrogen isotopes

Author

Listed:
  • Kou, Huaqin
  • Huang, Zhiyong
  • Luo, Wenhua
  • Sang, Ge
  • Meng, Daqiao
  • Luo, Deli
  • Zhang, Guanghui
  • Chen, Hao
  • Zhou, Ying
  • Hu, Changwen

Abstract

Metal hydride bed is an important component for the deuterium–tritium fusion energy under development in International Thermonuclear Experimental Reactor (ITER), in which the hydrogen recovery and delivery properties are influenced by the bed configuration, operation conditions and the hydrogen storage materials contained in the bed. In this work, a thin double-layered annulus bed configuration was adopted and full-scale beds loaded with ZrCo and depleted uranium (DU) for fast recovery and delivery of hydrogen isotopes were fabricated. The properties of hydrogen recovery/delivery together with the inner structure variation in the fabricated beds were systematically studied. The effects of operation conditions on the performances of the bed were also investigated. It was found that both of the fabricated ZrCo and DU beds were able to achieve the hydrogen storage target of 17.5mol with fast recovery rate. In addition, experimental results showed that operation of employing extra buffer vessel and scroll pump could not only promote the hydrogen delivery process but also reduce the possibility about disproportionation of ZrCo. Compared with ZrCo bed, DU bed exhibited superior hydrogen delivery performances in terms of fast delivery rate and high hydrogen delivery amount, which could deliver over 16.4mol H2 (93.7% of recovery amount) within 30min at the average delivery rate of 20Pam3/s. Good reversibility as high as 10 cycles without obvious degradation tendency in both of hydrogen delivery amount and delivery rate for DU bed was also achieved in our study. It was suggested that the fabricated thin double-layered annulus DU bed was a good candidate to rapidly deliver and recover massive hydrogen isotopes for fusion energy application.

Suggested Citation

  • Kou, Huaqin & Huang, Zhiyong & Luo, Wenhua & Sang, Ge & Meng, Daqiao & Luo, Deli & Zhang, Guanghui & Chen, Hao & Zhou, Ying & Hu, Changwen, 2015. "Experimental study on full-scale ZrCo and depleted uranium beds applied for fast recovery and delivery of hydrogen isotopes," Applied Energy, Elsevier, vol. 145(C), pages 27-35.
    • Handle: RePEc:eee:appene:v:145:y:2015:i:c:p:27-35
    DOI: 10.1016/j.apenergy.2015.02.010
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261915001804
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2015.02.010?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bao, Zewei & Yang, Fusheng & Wu, Zhen & Cao, Xinxin & Zhang, Zaoxiao, 2013. "Simulation studies on heat and mass transfer in high-temperature magnesium hydride reactors," Applied Energy, Elsevier, vol. 112(C), pages 1181-1189.
    2. Chung, C.A. & Yang, Su-Wen & Yang, Chien-Yuh & Hsu, Che-Weu & Chiu, Pai-Yuh, 2013. "Experimental study on the hydrogen charge and discharge rates of metal hydride tanks using heat pipes to enhance heat transfer," Applied Energy, Elsevier, vol. 103(C), pages 581-587.
    3. Zarrella, Angelo & Capozza, Antonio & De Carli, Michele, 2013. "Analysis of short helical and double U-tube borehole heat exchangers: A simulation-based comparison," Applied Energy, Elsevier, vol. 112(C), pages 358-370.
    4. Jiao, Kui & Li, Xianguo & Yin, Yan & Zhou, Yibo & Yu, Shuhai & Du, Qing, 2012. "Effects of various operating conditions on the hydrogen absorption processes in a metal hydride tank," Applied Energy, Elsevier, vol. 94(C), pages 257-269.
    5. Zarrella, Angelo & De Carli, Michele, 2013. "Heat transfer analysis of short helical borehole heat exchangers," Applied Energy, Elsevier, vol. 102(C), pages 1477-1491.
    6. Jayalakshmi, S. & Vasantha, V.S. & Fleury, E. & Gupta, M., 2012. "Characteristics of Ni–Nb-based metallic amorphous alloys for hydrogen-related energy applications," Applied Energy, Elsevier, vol. 90(1), pages 94-99.
    7. Wu, Zhen & Yang, Fusheng & Zhang, Zaoxiao & Bao, Zewei, 2014. "Magnesium based metal hydride reactor incorporating helical coil heat exchanger: Simulation study and optimal design," Applied Energy, Elsevier, vol. 130(C), pages 712-722.
    8. Hammond, Geoffrey P., 1996. "Nuclear energy into the twenty-first century," Applied Energy, Elsevier, vol. 54(4), pages 327-344, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhenyang Li & Shiyuan Liu & Yanhui Pu & Gang Huang & Yingbo Yuan & Ruiqi Zhu & Xufeng Li & Chunyan Chen & Gao Deng & Haihan Zou & Peng Yi & Ming Fang & Xin Sun & Junzhe He & He Cai & Jiaxiang Shang & , 2023. "Single-crystal ZrCo nanoparticle for advanced hydrogen and H-isotope storage," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.
    3. Lewis, Swaraj D. & Chippar, Purushothama, 2020. "Numerical investigation of hydrogen absorption in a metal hydride reactor with embedded embossed plate heat exchanger," Energy, Elsevier, vol. 194(C).
    4. Yao, Zhendong & Liang, Zhaoqing & Xiao, Xuezhang & Qi, Jiacheng & He, Jiahuan & Huang, Xu & Kou, Huaqin & Luo, Wenhua & Chen, Changan & Chen, Lixin, 2022. "Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction," Renewable Energy, Elsevier, vol. 187(C), pages 500-507.
    5. Jiacheng Qi & Xu Huang & Xuezhang Xiao & Xinyi Zhang & Panpan Zhou & Shuoqing Zhang & Ruhong Li & Huaqin Kou & Fei Jiang & Yong Yao & Jiangfeng Song & Xingwen Feng & Yan Shi & Wenhua Luo & Lixin Chen, 2024. "Isotope engineering achieved by local coordination design in Ti-Pd co-doped ZrCo-based alloys," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wu, Zhen & Yang, Fusheng & Zhang, Zaoxiao & Bao, Zewei, 2014. "Magnesium based metal hydride reactor incorporating helical coil heat exchanger: Simulation study and optimal design," Applied Energy, Elsevier, vol. 130(C), pages 712-722.
    2. Kim, Sung Han & Miesse, Craig M. & Lee, Hee Bum & Chang, Ik Whang & Hwang, Yong Sheen & Jang, Jae Hyuk & Cha, Suk Won, 2014. "Ultra compact direct hydrogen fuel cell prototype using a metal hydride hydrogen storage tank for a mobile phone," Applied Energy, Elsevier, vol. 134(C), pages 382-391.
    3. Lin, Xi & Zhu, Qi & Leng, Haiyan & Yang, Hongguang & Lyu, Tao & Li, Qian, 2019. "Numerical analysis of the effects of particle radius and porosity on hydrogen absorption performances in metal hydride tank," Applied Energy, Elsevier, vol. 250(C), pages 1065-1072.
    4. Ye, Yang & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2020. "Numerical simulation on the storage performance of a phase change materials based metal hydride hydrogen storage tank," Applied Energy, Elsevier, vol. 278(C).
    5. Ye, Yang & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials," Applied Energy, Elsevier, vol. 299(C).
    6. Ye, Yang & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2022. "Performance improvement of metal hydride hydrogen storage tanks by using phase change materials," Applied Energy, Elsevier, vol. 320(C).
    7. Kou, Huaqin & Luo, Wenhua & Huang, Zhiyong & Sang, Ge & Meng, Daqiao & Zhang, Guanghui & Chen, Changan & Luo, Deli & Hu, Changwen, 2015. "Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery," Energy, Elsevier, vol. 90(P1), pages 588-594.
    8. Wang, Qiuwang & Zeng, Min & Ma, Ting & Du, Xueping & Yang, Jianfeng, 2014. "Recent development and application of several high-efficiency surface heat exchangers for energy conversion and utilization," Applied Energy, Elsevier, vol. 135(C), pages 748-777.
    9. Aneta Sapińska-Sliwa & Marc A. Rosen & Andrzej Gonet & Joanna Kowalczyk & Tomasz Sliwa, 2019. "A New Method Based on Thermal Response Tests for Determining Effective Thermal Conductivity and Borehole Resistivity for Borehole Heat Exchangers," Energies, MDPI, vol. 12(6), pages 1-22, March.
    10. Shi, Yu & Song, Xianzhi & Wang, Gaosheng & McLennan, John & Forbes, Bryan & Li, Xiaojiang & Li, Jiacheng, 2019. "Study on wellbore fluid flow and heat transfer of a multilateral-well CO2 enhanced geothermal system," Applied Energy, Elsevier, vol. 249(C), pages 14-27.
    11. Somogyi, Viola & Sebestyén, Viktor & Nagy, Georgina, 2017. "Scientific achievements and regulation of shallow geothermal systems in six European countries – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P2), pages 934-952.
    12. Shah, Sheikh Khaleduzzaman & Aye, Lu & Rismanchi, Behzad, 2018. "Seasonal thermal energy storage system for cold climate zones: A review of recent developments," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 38-49.
    13. Wang, Di & Wang, Yuqi & Wang, Feng & Zheng, Shuaishuai & Guan, Sinan & Zheng, Lan & Wu, Le & Yang, Xin & Lv, Ming & Zhang, Zaoxiao, 2022. "Optimal design of disc mini-channel metal hydride reactor with high hydrogen storage efficiency," Applied Energy, Elsevier, vol. 308(C).
    14. Lewis, Swaraj D. & Chippar, Purushothama, 2020. "Numerical investigation of hydrogen absorption in a metal hydride reactor with embedded embossed plate heat exchanger," Energy, Elsevier, vol. 194(C).
    15. Liu, Yang & Wang, Hongxia & Ayub, Iqra & Yang, Fusheng & Wu, Zhen & Zhang, Zaoxiao, 2021. "A variable cross-section annular fins type metal hydride reactor for improving the phenomenon of inhomogeneous reaction in the thermal energy storage processes," Applied Energy, Elsevier, vol. 295(C).
    16. Xiao, Jinsheng & Tong, Liang & Bénard, Pierre & Chahine, Richard, 2020. "Thermodynamic analysis for hydriding-dehydriding cycle of metal hydride system," Energy, Elsevier, vol. 191(C).
    17. Wang, Di & Wang, Yuqi & Huang, Zhuonan & Yang, Fusheng & Wu, Zhen & Zheng, Lan & Wu, Le & Zhang, Zaoxiao, 2019. "Design optimization and sensitivity analysis of the radiation mini-channel metal hydride reactor," Energy, Elsevier, vol. 173(C), pages 443-456.
    18. Javadi, Hossein & Mousavi Ajarostaghi, Seyed Soheil & Rosen, Marc A. & Pourfallah, Mohsen, 2019. "Performance of ground heat exchangers: A comprehensive review of recent advances," Energy, Elsevier, vol. 178(C), pages 207-233.
    19. Pasquier, Philippe, 2018. "Interpretation of the first hours of a thermal response test using the time derivative of the temperature," Applied Energy, Elsevier, vol. 213(C), pages 56-75.
    20. Zhi, Chengqiang & Yang, Xiuqin & Zhou, Xiang & Tu, Shuyang & Zhang, Xu, 2022. "A revised sizing method for borehole heat exchangers in the Chinese national standard based on reliability and economy," Renewable Energy, Elsevier, vol. 191(C), pages 17-29.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:145:y:2015:i:c:p:27-35. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.