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Experimental study on full-scale ZrCo and depleted uranium beds applied for fast recovery and delivery of hydrogen isotopes

Author

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  • Kou, Huaqin
  • Huang, Zhiyong
  • Luo, Wenhua
  • Sang, Ge
  • Meng, Daqiao
  • Luo, Deli
  • Zhang, Guanghui
  • Chen, Hao
  • Zhou, Ying
  • Hu, Changwen

Abstract

Metal hydride bed is an important component for the deuterium–tritium fusion energy under development in International Thermonuclear Experimental Reactor (ITER), in which the hydrogen recovery and delivery properties are influenced by the bed configuration, operation conditions and the hydrogen storage materials contained in the bed. In this work, a thin double-layered annulus bed configuration was adopted and full-scale beds loaded with ZrCo and depleted uranium (DU) for fast recovery and delivery of hydrogen isotopes were fabricated. The properties of hydrogen recovery/delivery together with the inner structure variation in the fabricated beds were systematically studied. The effects of operation conditions on the performances of the bed were also investigated. It was found that both of the fabricated ZrCo and DU beds were able to achieve the hydrogen storage target of 17.5mol with fast recovery rate. In addition, experimental results showed that operation of employing extra buffer vessel and scroll pump could not only promote the hydrogen delivery process but also reduce the possibility about disproportionation of ZrCo. Compared with ZrCo bed, DU bed exhibited superior hydrogen delivery performances in terms of fast delivery rate and high hydrogen delivery amount, which could deliver over 16.4mol H2 (93.7% of recovery amount) within 30min at the average delivery rate of 20Pam3/s. Good reversibility as high as 10 cycles without obvious degradation tendency in both of hydrogen delivery amount and delivery rate for DU bed was also achieved in our study. It was suggested that the fabricated thin double-layered annulus DU bed was a good candidate to rapidly deliver and recover massive hydrogen isotopes for fusion energy application.

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  • Kou, Huaqin & Huang, Zhiyong & Luo, Wenhua & Sang, Ge & Meng, Daqiao & Luo, Deli & Zhang, Guanghui & Chen, Hao & Zhou, Ying & Hu, Changwen, 2015. "Experimental study on full-scale ZrCo and depleted uranium beds applied for fast recovery and delivery of hydrogen isotopes," Applied Energy, Elsevier, vol. 145(C), pages 27-35.
    • Handle: RePEc:eee:appene:v:145:y:2015:i:c:p:27-35
    DOI: 10.1016/j.apenergy.2015.02.010
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    References listed on IDEAS

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    1. Jiao, Kui & Li, Xianguo & Yin, Yan & Zhou, Yibo & Yu, Shuhai & Du, Qing, 2012. "Effects of various operating conditions on the hydrogen absorption processes in a metal hydride tank," Applied Energy, Elsevier, vol. 94(C), pages 257-269.
    2. Bao, Zewei & Yang, Fusheng & Wu, Zhen & Cao, Xinxin & Zhang, Zaoxiao, 2013. "Simulation studies on heat and mass transfer in high-temperature magnesium hydride reactors," Applied Energy, Elsevier, vol. 112(C), pages 1181-1189.
    3. Zarrella, Angelo & De Carli, Michele, 2013. "Heat transfer analysis of short helical borehole heat exchangers," Applied Energy, Elsevier, vol. 102(C), pages 1477-1491.
    4. Jayalakshmi, S. & Vasantha, V.S. & Fleury, E. & Gupta, M., 2012. "Characteristics of Ni–Nb-based metallic amorphous alloys for hydrogen-related energy applications," Applied Energy, Elsevier, vol. 90(1), pages 94-99.
    5. Wu, Zhen & Yang, Fusheng & Zhang, Zaoxiao & Bao, Zewei, 2014. "Magnesium based metal hydride reactor incorporating helical coil heat exchanger: Simulation study and optimal design," Applied Energy, Elsevier, vol. 130(C), pages 712-722.
    6. Hammond, Geoffrey P., 1996. "Nuclear energy into the twenty-first century," Applied Energy, Elsevier, vol. 54(4), pages 327-344, August.
    7. Chung, C.A. & Yang, Su-Wen & Yang, Chien-Yuh & Hsu, Che-Weu & Chiu, Pai-Yuh, 2013. "Experimental study on the hydrogen charge and discharge rates of metal hydride tanks using heat pipes to enhance heat transfer," Applied Energy, Elsevier, vol. 103(C), pages 581-587.
    8. Zarrella, Angelo & Capozza, Antonio & De Carli, Michele, 2013. "Analysis of short helical and double U-tube borehole heat exchangers: A simulation-based comparison," Applied Energy, Elsevier, vol. 112(C), pages 358-370.
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    Cited by:

    1. Zhenyang Li & Shiyuan Liu & Yanhui Pu & Gang Huang & Yingbo Yuan & Ruiqi Zhu & Xufeng Li & Chunyan Chen & Gao Deng & Haihan Zou & Peng Yi & Ming Fang & Xin Sun & Junzhe He & He Cai & Jiaxiang Shang & , 2023. "Single-crystal ZrCo nanoparticle for advanced hydrogen and H-isotope storage," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Yao, Zhendong & Liang, Zhaoqing & Xiao, Xuezhang & Qi, Jiacheng & He, Jiahuan & Huang, Xu & Kou, Huaqin & Luo, Wenhua & Chen, Changan & Chen, Lixin, 2022. "Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction," Renewable Energy, Elsevier, vol. 187(C), pages 500-507.
    3. Jiacheng Qi & Xu Huang & Xuezhang Xiao & Xinyi Zhang & Panpan Zhou & Shuoqing Zhang & Ruhong Li & Huaqin Kou & Fei Jiang & Yong Yao & Jiangfeng Song & Xingwen Feng & Yan Shi & Wenhua Luo & Lixin Chen, 2024. "Isotope engineering achieved by local coordination design in Ti-Pd co-doped ZrCo-based alloys," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.
    5. Lewis, Swaraj D. & Chippar, Purushothama, 2020. "Numerical investigation of hydrogen absorption in a metal hydride reactor with embedded embossed plate heat exchanger," Energy, Elsevier, vol. 194(C).

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