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Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction

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  • Yao, Zhendong
  • Liang, Zhaoqing
  • Xiao, Xuezhang
  • Qi, Jiacheng
  • He, Jiahuan
  • Huang, Xu
  • Kou, Huaqin
  • Luo, Wenhua
  • Chen, Changan
  • Chen, Lixin

Abstract

Hydrogen isotope (deuterium and tritium) as a special form of hydrogen energy, its storage in an efficient and safe way has been paid more and more attention by researchers in recent years. ZrCo alloy is regarding as the one and only promising material for large-scale storage of hydrogen isotope. However, poor cycle life and inferior capacity retention restrict its engineering application. Herein, we propose a co-substitution strategy of Nb (for Zr) and Ni (for Co) in ZrCo alloy to overcome the defects. Significantly, Zr0.8Nb0.2Co0.8Ni0.2 alloy exhibits ultralong cycle life (97.6% retention) and remarkable capacity (2.42 H (f. u.)) in 100 cycles, which far exceeds all existing hydrogen isotope storage alloys (Pd, U and other ZrCo-based alloys). These outstanding performances are entirely revealed from two aspects: stable homogeneous structural phase transformation process of parent structure (Zr0.8Nb0.2Co0.8Ni0.2H0.3-B33 ↔ Zr0.8Nb0.2Co0.8Ni0.2H2.8-B33″) and ordered migration mechanism of H atom (layered and linear de-/intercalation). Our attractive insights into the ultralong cycle life of ZrCo-based alloys through homogeneous structural phase transformation will serve as a pioneer on cycle optimization in the field of hydrogen storage materials.

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  • Yao, Zhendong & Liang, Zhaoqing & Xiao, Xuezhang & Qi, Jiacheng & He, Jiahuan & Huang, Xu & Kou, Huaqin & Luo, Wenhua & Chen, Changan & Chen, Lixin, 2022. "Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction," Renewable Energy, Elsevier, vol. 187(C), pages 500-507.
    • Handle: RePEc:eee:renene:v:187:y:2022:i:c:p:500-507
    DOI: 10.1016/j.renene.2022.01.086
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    1. Zhenyang Li & Shiyuan Liu & Yanhui Pu & Gang Huang & Yingbo Yuan & Ruiqi Zhu & Xufeng Li & Chunyan Chen & Gao Deng & Haihan Zou & Peng Yi & Ming Fang & Xin Sun & Junzhe He & He Cai & Jiaxiang Shang & , 2023. "Single-crystal ZrCo nanoparticle for advanced hydrogen and H-isotope storage," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Jiacheng Qi & Xu Huang & Xuezhang Xiao & Xinyi Zhang & Panpan Zhou & Shuoqing Zhang & Ruhong Li & Huaqin Kou & Fei Jiang & Yong Yao & Jiangfeng Song & Xingwen Feng & Yan Shi & Wenhua Luo & Lixin Chen, 2024. "Isotope engineering achieved by local coordination design in Ti-Pd co-doped ZrCo-based alloys," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Jiang, Wenbin & He, Changchun & Yang, Xiaobao & Xiao, Xuezhang & Ouyang, Liuzhang & Zhu, Min, 2022. "Influence of element substitution on structural stability and hydrogen storage performance: A theoretical and experimental study on TiCr2-xMnx alloy," Renewable Energy, Elsevier, vol. 197(C), pages 564-573.

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