IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-43828-5.html
   My bibliography  Save this article

Single-crystal ZrCo nanoparticle for advanced hydrogen and H-isotope storage

Author

Listed:
  • Zhenyang Li

    (Beihang University)

  • Shiyuan Liu

    (Beihang University)

  • Yanhui Pu

    (Beihang University)

  • Gang Huang

    (Beihang University)

  • Yingbo Yuan

    (Beihang University)

  • Ruiqi Zhu

    (Beihang University)

  • Xufeng Li

    (Beihang University)

  • Chunyan Chen

    (Beihang University)

  • Gao Deng

    (Beihang University)

  • Haihan Zou

    (Beihang University)

  • Peng Yi

    (Beihang University)

  • Ming Fang

    (Beihang University)

  • Xin Sun

    (National Key Laboratory of Scattering and Radiation)

  • Junzhe He

    (Beihang University
    National Key Laboratory of Scattering and Radiation)

  • He Cai

    (National Key Laboratory of Scattering and Radiation)

  • Jiaxiang Shang

    (Beihang University)

  • Xiaofang Liu

    (Beihang University)

  • Ronghai Yu

    (Beihang University)

  • Jianglan Shui

    (Beihang University
    Tianmushan Laboratory, Xixi Octagon City, Yuhang District)

Abstract

Hydrogen-isotope storage materials are essential for the controlled nuclear fusion. However, the currently used smelting-ZrCo alloy suffers from rapid degradation of performance due to severe disproportionation. Here, we reveal a defect-derived disproportionation mechanism and report a nano-single-crystal strategy to solve ZrCo’s problems. Single-crystal nano-ZrCo is synthesized by a wet-chemistry method and exhibits excellent comprehensive hydrogen-isotope storage performances, including ultrafast uptake/release kinetics, high anti-disproportionation ability, and stable cycling, far superior to conventional smelting-ZrCo. Especially, a further incorporation of Ti into nano-ZrCo can almost suppress the disproportionation reaction. Moreover, a mathematical relationship between dehydrogenation temperature and ZrCo particle size is established. Additionally, a microwave method capable of nondestructively detecting the hydrogen storage state of ZrCo is developed. The proposed disproportionation mechanism and anti-disproportionation strategy will be instructive for other materials with similar problems.

Suggested Citation

  • Zhenyang Li & Shiyuan Liu & Yanhui Pu & Gang Huang & Yingbo Yuan & Ruiqi Zhu & Xufeng Li & Chunyan Chen & Gao Deng & Haihan Zou & Peng Yi & Ming Fang & Xin Sun & Junzhe He & He Cai & Jiaxiang Shang & , 2023. "Single-crystal ZrCo nanoparticle for advanced hydrogen and H-isotope storage," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43828-5
    DOI: 10.1038/s41467-023-43828-5
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-43828-5
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-43828-5?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Elizabeth Gibney, 2022. "Nuclear-fusion reactor smashes energy record," Nature, Nature, vol. 602(7897), pages 371-371, February.
    2. Yao, Zhendong & Liang, Zhaoqing & Xiao, Xuezhang & Qi, Jiacheng & He, Jiahuan & Huang, Xu & Kou, Huaqin & Luo, Wenhua & Chen, Changan & Chen, Lixin, 2022. "Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction," Renewable Energy, Elsevier, vol. 187(C), pages 500-507.
    3. T. Ravensbergen & M. Berkel & A. Perek & C. Galperti & B. P. Duval & O. Février & R. J. R. Kampen & F. Felici & J. T. Lammers & C. Theiler & J. Schoukens & B. Linehan & M. Komm & S. Henderson & D. Bri, 2021. "Real-time feedback control of the impurity emission front in tokamak divertor plasmas," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    4. Kou, Huaqin & Huang, Zhiyong & Luo, Wenhua & Sang, Ge & Meng, Daqiao & Luo, Deli & Zhang, Guanghui & Chen, Hao & Zhou, Ying & Hu, Changwen, 2015. "Experimental study on full-scale ZrCo and depleted uranium beds applied for fast recovery and delivery of hydrogen isotopes," Applied Energy, Elsevier, vol. 145(C), pages 27-35.
    5. Huan Zhao & Poulami Chakraborty & Dirk Ponge & Tilmann Hickel & Binhan Sun & Chun-Hung Wu & Baptiste Gault & Dierk Raabe, 2022. "Hydrogen trapping and embrittlement in high-strength Al alloys," Nature, Nature, vol. 602(7897), pages 437-441, February.
    6. Jun Lu & Chun Zhan & Tianpin Wu & Jianguo Wen & Yu Lei & A. Jeremy Kropf & Huiming Wu & Dean J. Miller & Jeffrey W. Elam & Yang-Kook Sun & Xinping Qiu & Khalil Amine, 2014. "Effectively suppressing dissolution of manganese from spinel lithium manganate via a nanoscale surface-doping approach," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jiacheng Qi & Xu Huang & Xuezhang Xiao & Xinyi Zhang & Panpan Zhou & Shuoqing Zhang & Ruhong Li & Huaqin Kou & Fei Jiang & Yong Yao & Jiangfeng Song & Xingwen Feng & Yan Shi & Wenhua Luo & Lixin Chen, 2024. "Isotope engineering achieved by local coordination design in Ti-Pd co-doped ZrCo-based alloys," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Lewis, Swaraj D. & Chippar, Purushothama, 2020. "Numerical investigation of hydrogen absorption in a metal hydride reactor with embedded embossed plate heat exchanger," Energy, Elsevier, vol. 194(C).
    3. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.
    4. Yao, Zhendong & Liang, Zhaoqing & Xiao, Xuezhang & Qi, Jiacheng & He, Jiahuan & Huang, Xu & Kou, Huaqin & Luo, Wenhua & Chen, Changan & Chen, Lixin, 2022. "Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction," Renewable Energy, Elsevier, vol. 187(C), pages 500-507.
    5. Huan Zhao & Yue Yin & Yuxiang Wu & Siyuan Zhang & Andrea M. Mingers & Dirk Ponge & Baptiste Gault & Michael Rohwerder & Dierk Raabe, 2024. "How solute atoms control aqueous corrosion of Al-alloys," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Cheng, Guang & Wang, Xiaoli & Chen, Kaiyuan & Zhang, Yang & Venkatesh, T.A. & Wang, Xiaolin & Li, Zunzhao & Yang, Jing, 2023. "Probing the effects of hydrogen on the materials used for large-scale transport of hydrogen through multi-scale simulations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    7. Chengyi Yu & Kun Lin & Qinghua Zhang & Huihui Zhu & Ke An & Yan Chen & Dunji Yu & Tianyi Li & Xiaoqian Fu & Qian Yu & Li You & Xiaojun Kuang & Yili Cao & Qiang Li & Jinxia Deng & Xianran Xing, 2024. "An isotropic zero thermal expansion alloy with super-high toughness," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    8. Martí López Freixes & Xuyang Zhou & Huan Zhao & Hélène Godin & Lionel Peguet & Timothy Warner & Baptiste Gault, 2022. "Revisiting stress-corrosion cracking and hydrogen embrittlement in 7xxx-Al alloys at the near-atomic-scale," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    9. Jiang, Wenbin & He, Changchun & Yang, Xiaobao & Xiao, Xuezhang & Ouyang, Liuzhang & Zhu, Min, 2022. "Influence of element substitution on structural stability and hydrogen storage performance: A theoretical and experimental study on TiCr2-xMnx alloy," Renewable Energy, Elsevier, vol. 197(C), pages 564-573.
    10. Qingqing Yan & Jing Wang & Linda Zhang & Jiaqi Liu & Mohammad Wahiduzzaman & Nana Yan & Liang Yu & Romain Dupuis & Hao Wang & Guillaume Maurin & Michael Hirscher & Peng Guo & Sujing Wang & Jiangfeng D, 2023. "A squarate-pillared titanium oxide quantum sieve towards practical hydrogen isotope separation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    11. Pang-Yu Liu & Boning Zhang & Ranming Niu & Shao-Lun Lu & Chao Huang & Maoqiu Wang & Fuyang Tian & Yong Mao & Tong Li & Patrick A. Burr & Hongzhou Lu & Aimin Guo & Hung-Wei Yen & Julie M. Cairney & Hao, 2024. "Engineering metal-carbide hydrogen traps in steels," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43828-5. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.