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The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials

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  • Ye, Yang
  • Ding, Jing
  • Wang, Weilong
  • Yan, Jinyue

Abstract

The hydrogen storage of metal hydrides (MHs) is an exothermic process. The reaction enthalpy of magnesium hydride is 75 kJ/mol. Phase change materials (PCM) can be integrated with a MH hydrogen storage tank (MHST) to recycle the absorption heat as the heat source for desorption. To improve the heat transfer and hydrogen storage performance, this work comparatively studied the various configurations of the PCM based MHST. A numerical model is built to trace the transfer and storage process for two MHSTs with the PCM surrounded layout and sandwiched MH-PCM units. The results show that the configuration methods of PCM affects the hydrogen storage performance. The sandwiched MH-PCM units has faster heat transfer and reaction rate for the larger heat transfer area and smaller thermal resistance. The amount of PCM affects the reaction fraction due to the heat storage capacity. For the MHST with sandwiched MH-PCM units, when the amount of PCM is sufficient, the reduction of PCM will slightly decrease the average absorption rate and increase the average desorption rate by 21.8%. Considering the weight of PCM, the quantitative relationship is established among the mass ratio of PCM to MH, the maximum conversion rate of MgH2 and the actual gravimetric hydrogen storage capacity. When the amount of PCM is just sufficient, there is a maximum gravimetric hydrogen storage capacity of 0.733 wt%.

Suggested Citation

  • Ye, Yang & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials," Applied Energy, Elsevier, vol. 299(C).
  • Handle: RePEc:eee:appene:v:299:y:2021:i:c:s0306261921006759
    DOI: 10.1016/j.apenergy.2021.117255
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    References listed on IDEAS

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    2. Ye, Yang & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2022. "Performance improvement of metal hydride hydrogen storage tanks by using phase change materials," Applied Energy, Elsevier, vol. 320(C).
    3. Di Giorgio, Paolo & Di Ilio, Giovanni & Jannelli, Elio & Conte, Fiorentino Valerio, 2022. "Innovative battery thermal management system based on hydrogen storage in metal hydrides for fuel cell hybrid electric vehicles," Applied Energy, Elsevier, vol. 315(C).
    4. Qiu, Yibin & Li, Qi & Wang, Tianhong & Yin, Liangzhen & Chen, Weirong & Liu, Hong, 2022. "Optimal planning of Cross-regional hydrogen energy storage systems considering the uncertainty," Applied Energy, Elsevier, vol. 326(C).
    5. Pu, Yuchen & Li, Qi & Zou, Xueli & Li, Ruirui & Li, Luoyi & Chen, Weirong & Liu, Hong, 2021. "Optimal sizing for an integrated energy system considering degradation and seasonal hydrogen storage," Applied Energy, Elsevier, vol. 302(C).
    6. Ji Li & Lei Xu & Lihua Wang & Yang Kou & Yingli Huo & Weile Liang, 2024. "Operation Optimization of Regional Integrated Energy Systems with Hydrogen by Considering Demand Response and Green Certificate–Carbon Emission Trading Mechanisms," Energies, MDPI, vol. 17(13), pages 1-24, June.

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