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Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase

Author

Listed:
  • Wang, Tiejun
  • Li, Kai
  • Liu, Qiying
  • Zhang, Qing
  • Qiu, Songbai
  • Long, Jinxing
  • Chen, Lungang
  • Ma, Longlong
  • Zhang, Qi

Abstract

This paper presents a new route for biomass derived aviation fuel synthesis by catalytic conversion in aqueous phase. Furfural with the yield of 71% was produced by acid hydrolysis of raw corncob, and hydrogenated to 2-methylfuran with obtaining the yield of 89% over Raney Ni catalyst, both of which were implemented under mild reaction conditions. The hydroxyalkylation/alkylation condensation of 2-methylfuran and furfural to C15 intermediate was conducted by using organic and inorganic acid as the catalyst under the reaction condition of 328K and atmospheric pressure. The maximal 95% of the C15 intermediate was gained when using sulfuric acid as the catalyst. 83% of liquid alkanes (C8C15) yield and more than 90% of C14/C15 selectivity were produced by hydrodeoxygenation of the C15 intermediate over 10wt%Ni/ZrO2–SiO2 catalyst. During the hydrodeoxygenation process, the catalyst showed excellent stability depended on the 110h of time-on-stream test, due to its significantly decreased carbon deposition.

Suggested Citation

  • Wang, Tiejun & Li, Kai & Liu, Qiying & Zhang, Qing & Qiu, Songbai & Long, Jinxing & Chen, Lungang & Ma, Longlong & Zhang, Qi, 2014. "Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase," Applied Energy, Elsevier, vol. 136(C), pages 775-780.
    • Handle: RePEc:eee:appene:v:136:y:2014:i:c:p:775-780
    DOI: 10.1016/j.apenergy.2014.06.035
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    1. Wang, Tiejun & Yang, Yong & Ding, Mingyue & Liu, Qiying & Ma, Longlong, 2013. "Auto-thermal reforming of biomass raw fuel gas to syngas in a novel reformer: Promotion of hot-electron," Applied Energy, Elsevier, vol. 112(C), pages 448-453.
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    5. Yuriy Román-Leshkov & Christopher J. Barrett & Zhen Y. Liu & James A. Dumesic, 2007. "Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates," Nature, Nature, vol. 447(7147), pages 982-985, June.
    6. Shapouri, Hosein & Duffield, James A. & Wang, Michael Q., 2002. "The Energy Balance of Corn Ethanol: An Update," Agricultural Economic Reports 34075, United States Department of Agriculture, Economic Research Service.
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    1. Atsonios, Konstantinos & Kougioumtzis, Michael-Alexander & D. Panopoulos, Kyriakos & Kakaras, Emmanuel, 2015. "Alternative thermochemical routes for aviation biofuels via alcohols synthesis: Process modeling, techno-economic assessment and comparison," Applied Energy, Elsevier, vol. 138(C), pages 346-366.
    2. Zhufan Zou & Zhenjie Yu & Weixiang Guan & Yanfang Liu & Yumin Yao & Yang Han & Guangyi Li & Aiqin Wang & Yu Cong & Xinmiao Liang & Tao Zhang & Ning Li, 2024. "Selective production of methylindan and tetralin with xylose or hemicellulose," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Chen Zhang & Lei Luo & Wei Chen & Fei Yang & Gang Luo & Junming Xu, 2022. "Experimental Investigation on the Performance of an Aviation Piston Engine Fueled with Bio-Jet Fuel Prepared via Thermochemical Conversion of Triglyceride," Energies, MDPI, vol. 15(9), pages 1-13, April.
    4. Gutiérrez-Antonio, C. & Gómez-Castro, F.I. & de Lira-Flores, J.A. & Hernández, S., 2017. "A review on the production processes of renewable jet fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 709-729.
    5. Li, Yuping & Huang, Xiaoming & Zhang, Qian & Chen, Lungang & Zhang, Xinghua & Wang, Tiejun & Ma, Longlong, 2015. "Hydrogenation and hydrodeoxygenation of difurfurylidene acetone to liquid alkanes over Raney Ni and the supported Pt catalysts," Applied Energy, Elsevier, vol. 160(C), pages 990-998.
    6. Wang, Hongliang & Yang, Bin & Zhang, Qian & Zhu, Wanbin, 2020. "Catalytic routes for the conversion of lignocellulosic biomass to aviation fuel range hydrocarbons," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    7. Tuan Hoang, Anh & Viet Pham, Van, 2021. "2-Methylfuran (MF) as a potential biofuel: A thorough review on the production pathway from biomass, combustion progress, and application in engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    8. Rafał Łukajtis & Piotr Rybarczyk & Karolina Kucharska & Donata Konopacka-Łyskawa & Edyta Słupek & Katarzyna Wychodnik & Marian Kamiński, 2018. "Optimization of Saccharification Conditions of Lignocellulosic Biomass under Alkaline Pre-Treatment and Enzymatic Hydrolysis," Energies, MDPI, vol. 11(4), pages 1-27, April.
    9. Li Ji & Pengfei Li & Fuhou Lei & Xianliang Song & Jianxin Jiang & Kun Wang, 2020. "Coproduction of Furfural, Phenolated Lignin and Fermentable Sugars from Bamboo with One-Pot Fractionation Using Phenol-Acidic 1,4-Dioxane," Energies, MDPI, vol. 13(20), pages 1-17, October.
    10. Zhao, Weijie & Li, Yingwen & Song, Changhua & Liu, Sijie & Li, Xuehui & Long, Jinxing, 2017. "Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification," Applied Energy, Elsevier, vol. 204(C), pages 1094-1100.
    11. Li, Yuping & Zhao, Cong & Chen, Lungang & Zhang, Xinghua & Zhang, Qi & Wang, Tiejun & Qiu, Songbai & Tan, Jin & Li, Kai & Wang, Chenguang & Ma, Longlong, 2018. "Production of bio-jet fuel from corncob by hydrothermal decomposition and catalytic hydrogenation: Lab analysis of process and techno-economics of a pilot-scale facility," Applied Energy, Elsevier, vol. 227(C), pages 128-136.
    12. Thombal, Priyanka Raju & Thombal, Raju S. & Han, Sung Soo, 2021. "Comprehensive study on the catalytic methods for furyl alkane synthesis: A promising biodiesel precursor," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

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