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Coproduction of Furfural, Phenolated Lignin and Fermentable Sugars from Bamboo with One-Pot Fractionation Using Phenol-Acidic 1,4-Dioxane

Author

Listed:
  • Li Ji

    (Beijing Advanced Innovation Center for Tree Breeding by Molecular Design, Beijing Forestry University, Beijing 100083, China
    Department of Chemistry and Chemical Engineering, MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Forestry University, Beijing 100083, China)

  • Pengfei Li

    (Department of Chemistry and Chemical Engineering, MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Forestry University, Beijing 100083, China
    Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China)

  • Fuhou Lei

    (Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China)

  • Xianliang Song

    (Department of Chemistry and Chemical Engineering, MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Forestry University, Beijing 100083, China)

  • Jianxin Jiang

    (Beijing Advanced Innovation Center for Tree Breeding by Molecular Design, Beijing Forestry University, Beijing 100083, China
    Department of Chemistry and Chemical Engineering, MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Forestry University, Beijing 100083, China)

  • Kun Wang

    (Department of Chemistry and Chemical Engineering, MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Forestry University, Beijing 100083, China)

Abstract

A one-pot fractionation method of Moso bamboo into hemicellulose, lignin, and cellulose streams was used to produce furfural, phenolated lignin, and fermentable sugars in the acidic 1,4-dioxane system. Xylan was depolymerized to furfural at a yield of 93.81% of the theoretical value; however, the prolonged processing time (5 h) led to a high removal ratio of glucan (37.21%) in the absence of phenol. The optimum moderate condition (80 °C for 2 h with 2.5% phenol) was determined through the high fractionation efficiency. Consequently, 77.28% of xylan and 84.83% of lignin were removed and presented in the hydrolysate, while 91.08% of glucan was reserved in the solid portion. The formation of furfural from xylan remained high, with a yield of 92.92%. The extracted lignin was phenolated with an increasing content of phenolic hydroxyl. The fractionated lignin yield was 51.88%, which suggested this could be a low-cost raw material to product the activated carbon fiber precursor. The delignified pulp was subjected to enzymatic hydrolysis and the glucose yield reached up to 99.03% of the theoretical.

Suggested Citation

  • Li Ji & Pengfei Li & Fuhou Lei & Xianliang Song & Jianxin Jiang & Kun Wang, 2020. "Coproduction of Furfural, Phenolated Lignin and Fermentable Sugars from Bamboo with One-Pot Fractionation Using Phenol-Acidic 1,4-Dioxane," Energies, MDPI, vol. 13(20), pages 1-17, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:20:p:5294-:d:426551
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    References listed on IDEAS

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    2. Xuejun Shi & Yulong Wu & Huaifeng Yi & Guo Rui & Panpan Li & Mingde Yang & Gehua Wang, 2011. "Selective Preparation of Furfural from Xylose over Sulfonic Acid Functionalized Mesoporous Sba-15 Materials," Energies, MDPI, vol. 4(4), pages 1-16, April.
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