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Direct cleavage of C=O double bond in CO2 by the subnano MoOx surface on Mo2N

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  • Hao-Xin Liu

    (Shandong University)

  • Wei-Wei Wang

    (Shandong University)

  • Xin-Pu Fu

    (Shandong University)

  • Jin-Cheng Liu

    (Nankai University)

  • Chun-Jiang Jia

    (Shandong University)

Abstract

Compared to H2-assisted activation mode, the direct dissociation of CO2 into carbonyl (*CO) with a simplified reaction route is advantageous for CO2-related synthetic processes and catalyst upgrading, while the stable C = O double bond makes it very challenging. Herein, we construct a subnano MoO3 layer on the surface of Mo2N, which provides a dynamically changing surface of MoO3↔MoOx (x

Suggested Citation

  • Hao-Xin Liu & Wei-Wei Wang & Xin-Pu Fu & Jin-Cheng Liu & Chun-Jiang Jia, 2024. "Direct cleavage of C=O double bond in CO2 by the subnano MoOx surface on Mo2N," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-53484-y
    DOI: 10.1038/s41467-024-53484-y
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    References listed on IDEAS

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