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Ptn–Ov synergistic sites on MoOx/γ-Mo2N heterostructure for low-temperature reverse water–gas shift reaction

Author

Listed:
  • Hao-Xin Liu

    (Shandong University)

  • Jin-Ying Li

    (Shandong University)

  • Xuetao Qin

    (Peking University)

  • Chao Ma

    (Hunan University)

  • Wei-Wei Wang

    (Shandong University)

  • Kai Xu

    (Shandong University)

  • Han Yan

    (Shandong University)

  • Dequan Xiao

    (University of New Haven)

  • Chun-Jiang Jia

    (Shandong University)

  • Qiang Fu

    (University of Science and Technology of China)

  • Ding Ma

    (Peking University)

Abstract

In heterogeneous catalysis, the interface between active metal and support plays a key role in catalyzing various reactions. Specially, the synergistic effect between active metals and oxygen vacancies on support can greatly promote catalytic efficiency. However, the construction of high-density metal-vacancy synergistic sites on catalyst surface is very challenging. In this work, isolated Pt atoms are first deposited onto a very thin-layer of MoO3 surface stabilized on γ-Mo2N. Subsequently, the Pt–MoOx/γ-Mo2N catalyst, containing abundant Pt cluster-oxygen vacancy (Ptn–Ov) sites, is in situ constructed. This catalyst exhibits an unmatched activity and excellent stability in the reverse water-gas shift (RWGS) reaction at low temperature (300 °C). Systematic in situ characterizations illustrate that the MoO3 structure on the γ-Mo2N surface can be easily reduced into MoOx (2

Suggested Citation

  • Hao-Xin Liu & Jin-Ying Li & Xuetao Qin & Chao Ma & Wei-Wei Wang & Kai Xu & Han Yan & Dequan Xiao & Chun-Jiang Jia & Qiang Fu & Ding Ma, 2022. "Ptn–Ov synergistic sites on MoOx/γ-Mo2N heterostructure for low-temperature reverse water–gas shift reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33308-7
    DOI: 10.1038/s41467-022-33308-7
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    1. Yuanyuan Li & Matthew Kottwitz & Joshua L. Vincent & Michael J. Enright & Zongyuan Liu & Lihua Zhang & Jiahao Huang & Sanjaya D. Senanayake & Wei-Chang D. Yang & Peter A. Crozier & Ralph G. Nuzzo & An, 2021. "Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    2. Lili Lin & Jinjia Liu & Xi Liu & Zirui Gao & Ning Rui & Siyu Yao & Feng Zhang & Maolin Wang & Chang Liu & Lili Han & Feng Yang & Sen Zhang & Xiao-dong Wen & Sanjaya D. Senanayake & Yichao Wu & Xiaonia, 2021. "Reversing sintering effect of Ni particles on γ-Mo2N via strong metal support interaction," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Jiafeng Yu & Xingtao Sun & Xin Tong & Jixin Zhang & Jie Li & Shiyan Li & Yuefeng Liu & Noritatsu Tsubaki & Takayuki Abe & Jian Sun, 2021. "Ultra-high thermal stability of sputtering reconstructed Cu-based catalysts," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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    1. Xiao-Long Zhang & Peng-Cheng Yu & Shu-Ping Sun & Lei Shi & Peng-Peng Yang & Zhi-Zheng Wu & Li-Ping Chi & Ya-Rong Zheng & Min-Rui Gao, 2024. "In situ ammonium formation mediates efficient hydrogen production from natural seawater splitting," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Hui Xin & Rongtan Li & Le Lin & Rentao Mu & Mingrun Li & Dan Li & Qiang Fu & Xinhe Bao, 2024. "Reverse water gas-shift reaction product driven dynamic activation of molybdenum nitride catalyst surface," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Haiyan Wang & Shuang Wang & Shida Liu & Yiling Dai & Zhenghao Jia & Xuejing Li & Shuhe Liu & Feixiong Dang & Kevin J. Smith & Xiaowa Nie & Shuandi Hou & Xinwen Guo, 2024. "Redox-induced controllable engineering of MnO2-MnxCo3-xO4 interface to boost catalytic oxidation of ethane," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    4. Hao-Xin Liu & Wei-Wei Wang & Xin-Pu Fu & Jin-Cheng Liu & Chun-Jiang Jia, 2024. "Direct cleavage of C=O double bond in CO2 by the subnano MoOx surface on Mo2N," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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