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Tandem utilization of CO2 photoreduction products for the carbonylation of aryl iodides

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  • Yuan-Sheng Xia

    (Nanjing Normal University)

  • Meizhong Tang

    (Nanjing Normal University)

  • Lei Zhang

    (South China Normal University)

  • Jiang Liu

    (Nanjing Normal University
    South China Normal University)

  • Cheng Jiang

    (Nanjing Normal University)

  • Guang-Kuo Gao

    (Nanjing Normal University)

  • Long-Zhang Dong

    (Nanjing Normal University)

  • Lan-Gui Xie

    (Nanjing Normal University)

  • Ya-Qian Lan

    (Nanjing Normal University
    South China Normal University)

Abstract

Photocatalytic CO2 reduction reaction has been developed as an effective strategy to convert CO2 into reusable chemicals. However, the reduction products of this reaction are often of low utilization value. Herein, we effectively connect photocatalytic CO2 reduction and amino carbonylation reactions in series to reconvert inexpensive photoreduction product CO into value-added and easily isolated fine chemicals. In this tandem transformation system, we synthesize an efficient photocatalyst, NNU-55-Ni, which is transformed into nanosheets (NNU-55-Ni-NS) in situ to improve the photocatalytic CO2-to-CO activity significantly. After that, CO serving as reactant is further reconverted into organic molecules through the coupled carbonylation reactions. Especially in the carbonylation reaction of diethyltoluamide synthesis, CO conversion reaches up to 85%. Meanwhile, this tandem transformation also provides a simple and low-cost method for the 13C isotopically labeled organic molecules. This work represents an important and feasible pathway for the subsequent separation and application of CO2 photoreduction product.

Suggested Citation

  • Yuan-Sheng Xia & Meizhong Tang & Lei Zhang & Jiang Liu & Cheng Jiang & Guang-Kuo Gao & Long-Zhang Dong & Lan-Gui Xie & Ya-Qian Lan, 2022. "Tandem utilization of CO2 photoreduction products for the carbonylation of aryl iodides," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30676-y
    DOI: 10.1038/s41467-022-30676-y
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    1. Xianyu Deng & Jianjun Zhang & Kezhen Qi & Guijie Liang & Feiyan Xu & Jiaguo Yu, 2024. "Ultrafast electron transfer at the In2O3/Nb2O5 S-scheme interface for CO2 photoreduction," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Serena Monticelli & Alex Talbot & Philipp Gotico & Fabien Caillé & Olivier Loreau & Antonio Vecchio & Augustin Malandain & Antoine Sallustrau & Winfried Leibl & Ally Aukauloo & Frédéric Taran & Zakari, 2023. "Unlocking full and fast conversion in photocatalytic carbon dioxide reduction for applications in radio-carbonylation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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