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Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons

Author

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  • Guangxin Yang

    (Shantou University)

  • Subin Hao

    (Shantou University)

  • Xin Deng

    (Shantou University)

  • Xinluo Song

    (Shantou University)

  • Bo Sun

    (Wenzhou University)

  • Woo Jin Hyun

    (Guangdong Technion-Israel Institute of Technology)

  • Ming-De Li

    (Shantou University
    Chemistry and Chemical Engineering Guangdong Laboratory)

  • Li Dang

    (Shantou University)

Abstract

Polymer-based pure organic room-temperature phosphorescent materials have tremendous advantages in applications owing to their low cost, vast resources, and easy processability. However, designing polymer-based room-temperature phosphorescent materials with large Stokes shifts as key requirements in biocompatibility and environmental-friendly performance is still challenging. By generating charge transfer states as the gangplank from singlet excited states to triplet states in doped organic molecules, we find a host molecule (pyrrolidone) that affords charge transfer with doped guest molecules, and excellent polymer-based organic room-temperature phosphorescent materials can be easily fabricated when polymerizing the host molecule. By adding polyaromatic hydrocarbon molecules as electron-donor in polyvinylpyrrolidone, efficient intersystem crossing and tunable phosphorescent from green to near-infrared can be achieved, with maximum phosphorescence wavelength and lifetime up to 757 nm and 3850 ms, respectively. These doped polyvinylpyrrolidone materials have good photoactivation properties, recyclability, advanced data encryption, and anti-counterfeiting. This reported design strategy paves the way for the design of polyvinylpyrrolidone-based room-temperature phosphorescent materials.

Suggested Citation

  • Guangxin Yang & Subin Hao & Xin Deng & Xinluo Song & Bo Sun & Woo Jin Hyun & Ming-De Li & Li Dang, 2024. "Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48913-x
    DOI: 10.1038/s41467-024-48913-x
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    References listed on IDEAS

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