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Turing structuring with multiple nanotwins to engineer efficient and stable catalysts for hydrogen evolution reaction

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  • Jialun Gu

    (City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science
    City University of Hong Kong
    CityU-Shenzhen Futian Research Institute
    City University of Hong Kong)

  • Lanxi Li

    (City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science
    City University of Hong Kong
    City University of Hong Kong)

  • Youneng Xie

    (City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science
    City University of Hong Kong
    City University of Hong Kong)

  • Bo Chen

    (City University of Hong Kong)

  • Fubo Tian

    (Jilin University)

  • Yanju Wang

    (City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science
    City University of Hong Kong
    City University of Hong Kong)

  • Jing Zhong

    (City University of Hong Kong)

  • Junda Shen

    (City University of Hong Kong
    City University of Hong Kong)

  • Jian Lu

    (City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science
    City University of Hong Kong
    City University of Hong Kong
    CityU-Shenzhen Futian Research Institute)

Abstract

Low-dimensional nanocrystals with controllable defects or strain modifications are newly emerging active electrocatalysts for hydrogen-energy conversion and utilization; however, a crucial challenge remains in insufficient stability due to spontaneous structural degradation and strain relaxation. Here we report a Turing structuring strategy to activate and stabilize superthin metal nanosheets by incorporating high-density nanotwins. Turing configuration, realized by constrained orientation attachment of nanograins, yields intrinsically stable nanotwin network and straining effects, which synergistically reduce the energy barrier of water dissociation and optimize the hydrogen adsorption free energy for hydrogen evolution reaction. Turing PtNiNb nanocatalyst achieves 23.5 and 3.1 times increase in mass activity and stability index, respectively, compared against commercial 20% Pt/C. The Turing PtNiNb-based anion-exchange-membrane water electrolyser with a low Pt mass loading of 0.05 mg cm−2 demonstrates at least 500 h stability at 1000 mA cm−2, disclosing the stable catalysis. Besides, this new paradigm can be extended to Ir/Pd/Ag-based nanocatalysts, illustrating the universality of Turing-type catalysts.

Suggested Citation

  • Jialun Gu & Lanxi Li & Youneng Xie & Bo Chen & Fubo Tian & Yanju Wang & Jing Zhong & Junda Shen & Jian Lu, 2023. "Turing structuring with multiple nanotwins to engineer efficient and stable catalysts for hydrogen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40972-w
    DOI: 10.1038/s41467-023-40972-w
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    1. Ge Wu & Sida Liu & Qing Wang & Jing Rao & Wenzhen Xia & Yong-Qiang Yan & Jürgen Eckert & Chang Liu & En Ma & Zhi-Wei Shan, 2023. "Substantially enhanced homogeneous plastic flow in hierarchically nanodomained amorphous alloys," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Yuanming Zhang & Ningsi Zhang & Yong Liu & Yong Chen & Huiting Huang & Wenjing Wang & Xiaoming Xu & Yang Li & Fengtao Fan & Jinhua Ye & Zhaosheng Li & Zhigang Zou, 2022. "Homogeneous solution assembled Turing structures with near zero strain semi-coherence interface," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    3. Xu Li & Xavier Isidro Pereira-Hernández & Yizhen Chen & Jia Xu & Jiankang Zhao & Chih-Wen Pao & Chia-Yu Fang & Jie Zeng & Yong Wang & Bruce C. Gates & Jingyue Liu, 2022. "Functional CeOx nanoglues for robust atomically dispersed catalysts," Nature, Nature, vol. 611(7935), pages 284-288, November.
    4. Jakob Kibsgaard & Ib Chorkendorff, 2019. "Considerations for the scaling-up of water splitting catalysts," Nature Energy, Nature, vol. 4(6), pages 430-433, June.
    5. Xinzhe Li & Yiyun Fang & Jun Wang & Hanyan Fang & Shibo Xi & Xiaoxu Zhao & Danyun Xu & Haomin Xu & Wei Yu & Xiao Hai & Cheng Chen & Chuanhao Yao & Hua Bing Tao & Alexander G. R. Howe & Stephen J. Penn, 2021. "Ordered clustering of single atomic Te vacancies in atomically thin PtTe2 promotes hydrogen evolution catalysis," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    6. Tianou He & Weicong Wang & Fenglei Shi & Xiaolong Yang & Xiang Li & Jianbo Wu & Yadong Yin & Mingshang Jin, 2021. "Mastering the surface strain of platinum catalysts for efficient electrocatalysis," Nature, Nature, vol. 598(7879), pages 76-81, October.
    7. Xuesi Wang & Chaochen Xu & Mietek Jaroniec & Yao Zheng & Shi-Zhang Qiao, 2019. "Anomalous hydrogen evolution behavior in high-pH environment induced by locally generated hydronium ions," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
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    2. Yaoda Liu & Lei Li & Li Wang & Na Li & Xiaoxu Zhao & Ya Chen & Thangavel Sakthivel & Zhengfei Dai, 2024. "Janus electronic state of supported iridium nanoclusters for sustainable alkaline water electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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