IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-40825-6.html
   My bibliography  Save this article

Proton-controlled molecular ionic ferroelectrics

Author

Listed:
  • Yulong Huang

    (University at Buffalo, The State University of New York)

  • Jennifer L. Gottfried

    (Weapons Sciences, US Army Combat Capabilities Development Command-Army Research Laboratory, Aberdeen Proving Ground)

  • Arpita Sarkar

    (University at Buffalo, The State University of New York)

  • Gengyi Zhang

    (University at Buffalo, The State University of New York)

  • Haiqing Lin

    (University at Buffalo, The State University of New York)

  • Shenqiang Ren

    (University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York
    Research and Education in Energy, Environment and Water (RENEW) Institute, University at Buffalo, The State University of New York
    University of Maryland)

Abstract

Molecular ferroelectric materials consist of organic and inorganic ions held together by hydrogen bonds, electrostatic forces, and van der Waals interactions. However, ionically tailored multifunctionality in molecular ferroelectrics has been a missing component despite of their peculiar stimuli-responsive structure and building blocks. Here we report molecular ionic ferroelectrics exhibiting the coexistence of room-temperature ionic conductivity (6.1 × 10−5 S/cm) and ferroelectricity, which triggers the ionic-coupled ferroelectric properties. Such ionic ferroelectrics with the absorbed water molecules further present the controlled tunability in polarization from 0.68 to 1.39 μC/cm2, thermal conductivity by 13% and electrical resistivity by 86% due to the proton transfer in an ionic lattice under external stimuli. These findings enlighten the development of molecular ionic ferroelectrics towards multifunctionality.

Suggested Citation

  • Yulong Huang & Jennifer L. Gottfried & Arpita Sarkar & Gengyi Zhang & Haiqing Lin & Shenqiang Ren, 2023. "Proton-controlled molecular ionic ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40825-6
    DOI: 10.1038/s41467-023-40825-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-40825-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-40825-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Sachio Horiuchi & Kensuke Kobayashi & Reiji Kumai & Shoji Ishibashi, 2017. "Proton tautomerism for strong polarization switching," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    2. Yong Hu & Scott Broderick & Zipeng Guo & Alpha T. N’Diaye & Jaspal S. Bola & Hans Malissa & Cheng Li & Qiang Zhang & Yulong Huang & Quanxi Jia & Christoph Boehme & Z. Valy Vardeny & Chi Zhou & Shenqia, 2021. "Proton switching molecular magnetoelectricity," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Jiawei Zhou & Hyun D. Shin & Ke Chen & Bai Song & Ryan A. Duncan & Qian Xu & Alexei A. Maznev & Keith A. Nelson & Gang Chen, 2020. "Direct observation of large electron–phonon interaction effect on phonon heat transport," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    4. Michael Hoffmann & Franz P. G. Fengler & Melanie Herzig & Terence Mittmann & Benjamin Max & Uwe Schroeder & Raluca Negrea & Pintilie Lucian & Stefan Slesazeck & Thomas Mikolajick, 2019. "Unveiling the double-well energy landscape in a ferroelectric layer," Nature, Nature, vol. 565(7740), pages 464-467, January.
    5. Xianyong Wu & Jessica J. Hong & Woochul Shin & Lu Ma & Tongchao Liu & Xuanxuan Bi & Yifei Yuan & Yitong Qi & T. Wesley Surta & Wenxi Huang & Joerg Neuefeind & Tianpin Wu & P. Alex Greaney & Jun Lu & X, 2019. "Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries," Nature Energy, Nature, vol. 4(2), pages 123-130, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Congqin Zheng & Xin Li & Wei Li & Tiantian Chen & Fu Lv & Yuhui Huang & Qian Li & Yongjun Wu & Zijian Hong, 2024. "A molecular ferroelectric thin film of imidazolium perchlorate on silicon," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ben Niu & Wenxuan Jiang & Bo Jiang & Mengqi Lv & Sa Wang & Wei Wang, 2022. "Determining the depth of surface charging layer of single Prussian blue nanoparticles with pseudocapacitive behaviors," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Haiming Lv & Zhiquan Wei & Cuiping Han & Xiaolong Yang & Zijie Tang & Yantu Zhang & Chunyi Zhi & Hongfei Li, 2023. "Cross-linked polyaniline for production of long lifespan aqueous iron||organic batteries with electrochromic properties," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Yongjiu Lei & Wenli Zhao & Jun Yin & Yinchang Ma & Zhiming Zhao & Jian Yin & Yusuf Khan & Mohamed Nejib Hedhili & Long Chen & Qingxiao Wang & Youyou Yuan & Xixiang Zhang & Osman M. Bakr & Omar F. Moha, 2023. "Discovery of a three-proton insertion mechanism in α-molybdenum trioxide leading to enhanced charge storage capacity," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Yong Hu & Jennifer L. Gottfried & Rose Pesce-Rodriguez & Chi-Chin Wu & Scott D. Walck & Zhiyu Liu & Sangeeth Balakrishnan & Scott Broderick & Zipeng Guo & Qiang Zhang & Lu An & Revant Adlakha & Mostaf, 2022. "Releasing chemical energy in spatially programmed ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Nattapol Ma & Ryo Ohtani & Hung M. Le & Søren S. Sørensen & Ryuta Ishikawa & Satoshi Kawata & Sareeya Bureekaew & Soracha Kosasang & Yoshiyuki Kawazoe & Koji Ohara & Morten M. Smedskjaer & Satoshi Hor, 2022. "Exploration of glassy state in Prussian blue analogues," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    6. Zhenyu Sun & Yueqi Su & Aomiao Zhi & Zhicheng Gao & Xu Han & Kang Wu & Lihong Bao & Yuan Huang & Youguo Shi & Xuedong Bai & Peng Cheng & Lan Chen & Kehui Wu & Xuezeng Tian & Changzheng Wu & Baojie Fen, 2024. "Evidence for multiferroicity in single-layer CuCrSe2," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    7. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Wei Liu & Jiage Yu & Tianshui Li & Shihang Li & Boyu Ding & Xinlong Guo & Aiqing Cao & Qihao Sha & Daojin Zhou & Yun Kuang & Xiaoming Sun, 2024. "Self-protecting CoFeAl-layered double hydroxides enable stable and efficient brine oxidation at 2 A cm−2," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    9. Jiadong Tang & Yun Wang & Hongyang Yang & Qianqian Zhang & Ce Wang & Leyuan Li & Zilong Zheng & Yuhong Jin & Hao Wang & Yifan Gu & Tieyong Zuo, 2024. "All-natural 2D nanofluidics as highly-efficient osmotic energy generators," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Michael Hoffmann & Zheng Wang & Nujhat Tasneem & Ahmad Zubair & Prasanna Venkatesan Ravindran & Mengkun Tian & Anthony Arthur Gaskell & Dina Triyoso & Steven Consiglio & Kandabara Tapily & Robert Clar, 2022. "Antiferroelectric negative capacitance from a structural phase transition in zirconia," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    11. Yan Sun & Shuting Xu & Zheqi Xu & Jiamin Tian & Mengmeng Bai & Zhiying Qi & Yue Niu & Hein Htet Aung & Xiaolu Xiong & Junfeng Han & Cuicui Lu & Jianbo Yin & Sheng Wang & Qing Chen & Reshef Tenne & All, 2022. "Mesoscopic sliding ferroelectricity enabled photovoltaic random access memory for material-level artificial vision system," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    12. Benbing Shi & Xiao Pang & Shunning Li & Hong Wu & Jianliang Shen & Xiaoyao Wang & Chunyang Fan & Li Cao & Tianhao Zhu & Ming Qiu & Zhuoyu Yin & Yan Kong & Yiqin Liu & Mingzheng Zhang & Yawei Liu & Fen, 2022. "Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Simas, Fabiano C. & Nobrega, K.Z. & Bazeia, D., 2022. "Bifurcation and chaos in one dimensional chains of small particles," Chaos, Solitons & Fractals, Elsevier, vol. 161(C).
    14. Mochou Liao & Xiao Ji & Yongjie Cao & Jie Xu & Xuan Qiu & Yihua Xie & Fei Wang & Chunsheng Wang & Yongyao Xia, 2022. "Solvent-free protic liquid enabling batteries operation at an ultra-wide temperature range," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    15. Tiezhu Xu & Zhenming Xu & Tengyu Yao & Miaoran Zhang & Duo Chen & Xiaogang Zhang & Laifa Shen, 2023. "Discovery of fast and stable proton storage in bulk hexagonal molybdenum oxide," Nature Communications, Nature, vol. 14(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40825-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.