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Proton-controlled molecular ionic ferroelectrics

Author

Listed:
  • Yulong Huang

    (University at Buffalo, The State University of New York)

  • Jennifer L. Gottfried

    (Weapons Sciences, US Army Combat Capabilities Development Command-Army Research Laboratory, Aberdeen Proving Ground)

  • Arpita Sarkar

    (University at Buffalo, The State University of New York)

  • Gengyi Zhang

    (University at Buffalo, The State University of New York)

  • Haiqing Lin

    (University at Buffalo, The State University of New York)

  • Shenqiang Ren

    (University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York
    Research and Education in Energy, Environment and Water (RENEW) Institute, University at Buffalo, The State University of New York
    University of Maryland)

Abstract

Molecular ferroelectric materials consist of organic and inorganic ions held together by hydrogen bonds, electrostatic forces, and van der Waals interactions. However, ionically tailored multifunctionality in molecular ferroelectrics has been a missing component despite of their peculiar stimuli-responsive structure and building blocks. Here we report molecular ionic ferroelectrics exhibiting the coexistence of room-temperature ionic conductivity (6.1 × 10−5 S/cm) and ferroelectricity, which triggers the ionic-coupled ferroelectric properties. Such ionic ferroelectrics with the absorbed water molecules further present the controlled tunability in polarization from 0.68 to 1.39 μC/cm2, thermal conductivity by 13% and electrical resistivity by 86% due to the proton transfer in an ionic lattice under external stimuli. These findings enlighten the development of molecular ionic ferroelectrics towards multifunctionality.

Suggested Citation

  • Yulong Huang & Jennifer L. Gottfried & Arpita Sarkar & Gengyi Zhang & Haiqing Lin & Shenqiang Ren, 2023. "Proton-controlled molecular ionic ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40825-6
    DOI: 10.1038/s41467-023-40825-6
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    References listed on IDEAS

    as
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    3. Sachio Horiuchi & Kensuke Kobayashi & Reiji Kumai & Shoji Ishibashi, 2017. "Proton tautomerism for strong polarization switching," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
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