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Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity

Author

Listed:
  • Benbing Shi

    (Tianjin University)

  • Xiao Pang

    (Tianjin University)

  • Shunning Li

    (Peking University Shenzhen Graduate School)

  • Hong Wu

    (Tianjin University
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Jianliang Shen

    (Tianjin University)

  • Xiaoyao Wang

    (Tianjin University)

  • Chunyang Fan

    (Tianjin University)

  • Li Cao

    (Tianjin University)

  • Tianhao Zhu

    (Tianjin University)

  • Ming Qiu

    (Tianjin University)

  • Zhuoyu Yin

    (Tianjin University)

  • Yan Kong

    (Tianjin University)

  • Yiqin Liu

    (Tianjin University)

  • Mingzheng Zhang

    (Peking University Shenzhen Graduate School)

  • Yawei Liu

    (Chinese Academy of Sciences)

  • Feng Pan

    (Peking University Shenzhen Graduate School)

  • Zhongyi Jiang

    (Tianjin University
    Haihe Laboratory of Sustainable Chemical Transformations
    International Campus of Tianjin University, Binhai New City
    Zhejiang Institute of Tianjin University)

Abstract

The idea of spatial confinement has gained widespread interest in myriad applications. Especially, the confined short hydrogen-bond (SHB) network could afford an attractive opportunity to enable proton transfer in a nearly barrierless manner, but its practical implementation has been challenging. Herein, we report a SHB network confined on the surface of ionic covalent organic framework (COF) membranes decorated by densely and uniformly distributed hydrophilic ligands. Combined experimental and theoretical evidences have pointed to the confinement of water molecules allocated to each ligand, achieving the local enrichment of hydronium ions and the concomitant formation of SHBs in water-hydronium domains. These overlapped water-hydronium domains create an interconnected SHB network, which yields an unprecedented ultrahigh proton conductivity of 1389 mS cm−1 at 90 °C, 100% relative humidity.

Suggested Citation

  • Benbing Shi & Xiao Pang & Shunning Li & Hong Wu & Jianliang Shen & Xiaoyao Wang & Chunyang Fan & Li Cao & Tianhao Zhu & Ming Qiu & Zhuoyu Yin & Yan Kong & Yiqin Liu & Mingzheng Zhang & Yawei Liu & Fen, 2022. "Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33868-8
    DOI: 10.1038/s41467-022-33868-8
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    Cited by:

    1. Zhangcai Zhang & Lixin Liang & Jianze Feng & Guangjin Hou & Wencai Ren, 2024. "Significant enhancement of proton conductivity in solid acid at the monolayer limit," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Tianhao Zhu & Yan Kong & Bohui Lyu & Li Cao & Benbing Shi & Xiaoyao Wang & Xiao Pang & Chunyang Fan & Chao Yang & Hong Wu & Zhongyi Jiang, 2023. "3D covalent organic framework membrane with fast and selective ion transport," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Xue-Xin Li & Cai-Hong Li & Ming-Jun Hou & Bo Zhu & Wei-Chao Chen & Chun-Yi Sun & Ye Yuan & Wei Guan & Chao Qin & Kui-Zhan Shao & Xin-Long Wang & Zhong-Min Su, 2023. "Ce-mediated molecular tailoring on gigantic polyoxometalate {Mo132} into half-closed {Ce11Mo96} for high proton conduction," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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