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Releasing chemical energy in spatially programmed ferroelectrics

Author

Listed:
  • Yong Hu

    (University at Buffalo, The State University of New York)

  • Jennifer L. Gottfried

    (Weapons and Materials Research Directorate, US Army Combat Capabilities Development-Army Research Laboratory, Aberdeen Proving Ground)

  • Rose Pesce-Rodriguez

    (Weapons and Materials Research Directorate, US Army Combat Capabilities Development-Army Research Laboratory, Aberdeen Proving Ground)

  • Chi-Chin Wu

    (Weapons and Materials Research Directorate, US Army Combat Capabilities Development-Army Research Laboratory, Aberdeen Proving Ground)

  • Scott D. Walck

    (Survice Engineering Co.)

  • Zhiyu Liu

    (University of Maryland)

  • Sangeeth Balakrishnan

    (University of Maryland)

  • Scott Broderick

    (University at Buffalo, The State University of New York)

  • Zipeng Guo

    (University at Buffalo, The State University of New York)

  • Qiang Zhang

    (Oak Ridge National Laboratory)

  • Lu An

    (University at Buffalo, The State University of New York)

  • Revant Adlakha

    (University at Buffalo, The State University of New York)

  • Mostafa Nouh

    (University at Buffalo, The State University of New York)

  • Chi Zhou

    (University at Buffalo, The State University of New York)

  • Peter W. Chung

    (University of Maryland)

  • Shenqiang Ren

    (University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York)

Abstract

Chemical energy ferroelectrics are generally solid macromolecules showing spontaneous polarization and chemical bonding energy. These materials still suffer drawbacks, including the limited control of energy release rate, and thermal decomposition energy well below total chemical energy. To overcome these drawbacks, we report the integrated molecular ferroelectric and energetic material from machine learning-directed additive manufacturing coupled with the ice-templating assembly. The resultant aligned porous architecture shows a low density of 0.35 g cm−3, polarization-controlled energy release, and an anisotropic thermal conductivity ratio of 15. Thermal analysis suggests that the chlorine radicals react with macromolecules enabling a large exothermic enthalpy of reaction (6180 kJ kg−1). In addition, the estimated detonation velocity of molecular ferroelectrics can be tuned from 6.69 ± 0.21 to 7.79 ± 0.25 km s−1 by switching the polarization state. These results provide a pathway toward spatially programmed energetic ferroelectrics for controlled energy release rates.

Suggested Citation

  • Yong Hu & Jennifer L. Gottfried & Rose Pesce-Rodriguez & Chi-Chin Wu & Scott D. Walck & Zhiyu Liu & Sangeeth Balakrishnan & Scott Broderick & Zipeng Guo & Qiang Zhang & Lu An & Revant Adlakha & Mostaf, 2022. "Releasing chemical energy in spatially programmed ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34819-z
    DOI: 10.1038/s41467-022-34819-z
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    References listed on IDEAS

    as
    1. Mutian Hua & Shuwang Wu & Yanfei Ma & Yusen Zhao & Zilin Chen & Imri Frenkel & Joseph Strzalka & Hua Zhou & Xinyuan Zhu & Ximin He, 2021. "Strong tough hydrogels via the synergy of freeze-casting and salting out," Nature, Nature, vol. 590(7847), pages 594-599, February.
    2. Yong Hu & Scott Broderick & Zipeng Guo & Alpha T. N’Diaye & Jaspal S. Bola & Hans Malissa & Cheng Li & Qiang Zhang & Yulong Huang & Quanxi Jia & Christoph Boehme & Z. Valy Vardeny & Chi Zhou & Shenqia, 2021. "Proton switching molecular magnetoelectricity," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Yong Hu & Zhiyu Liu & Chi-Chin Wu & Jennifer L. Gottfried & Rose Pesce-Rodriguez & Scott D. Walck & Peter W. Chung & Shenqiang Ren, 2021. "Chemically driven energetic molecular ferroelectrics," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
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