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Antiferroelectric negative capacitance from a structural phase transition in zirconia

Author

Listed:
  • Michael Hoffmann

    (NaMLab gGmbH
    University of California)

  • Zheng Wang

    (Georgia Institute of Technology)

  • Nujhat Tasneem

    (Georgia Institute of Technology)

  • Ahmad Zubair

    (Massachusetts Institute of Technology)

  • Prasanna Venkatesan Ravindran

    (Georgia Institute of Technology)

  • Mengkun Tian

    (Georgia Institute of Technology)

  • Anthony Arthur Gaskell

    (Georgia Institute of Technology)

  • Dina Triyoso

    (TEL Technology Center, America, LLC)

  • Steven Consiglio

    (TEL Technology Center, America, LLC)

  • Kandabara Tapily

    (TEL Technology Center, America, LLC)

  • Robert Clark

    (TEL Technology Center, America, LLC)

  • Jae Hur

    (Georgia Institute of Technology)

  • Sai Surya Kiran Pentapati

    (Georgia Institute of Technology)

  • Sung Kyu Lim

    (Georgia Institute of Technology)

  • Milan Dopita

    (Charles University)

  • Shimeng Yu

    (Georgia Institute of Technology)

  • Winston Chern

    (Massachusetts Institute of Technology
    Izentis LLC)

  • Josh Kacher

    (Georgia Institute of Technology)

  • Sebastian E. Reyes-Lillo

    (Universidad Andres Bello)

  • Dimitri Antoniadis

    (Massachusetts Institute of Technology)

  • Jayakanth Ravichandran

    (University of Southern California)

  • Stefan Slesazeck

    (NaMLab gGmbH)

  • Thomas Mikolajick

    (NaMLab gGmbH
    TU Dresden)

  • Asif Islam Khan

    (Georgia Institute of Technology
    Georgia Institute of Technology)

Abstract

Crystalline materials with broken inversion symmetry can exhibit a spontaneous electric polarization, which originates from a microscopic electric dipole moment. Long-range polar or anti-polar order of such permanent dipoles gives rise to ferroelectricity or antiferroelectricity, respectively. However, the recently discovered antiferroelectrics of fluorite structure (HfO2 and ZrO2) are different: A non-polar phase transforms into a polar phase by spontaneous inversion symmetry breaking upon the application of an electric field. Here, we show that this structural transition in antiferroelectric ZrO2 gives rise to a negative capacitance, which is promising for overcoming the fundamental limits of energy efficiency in electronics. Our findings provide insight into the thermodynamically forbidden region of the antiferroelectric transition in ZrO2 and extend the concept of negative capacitance beyond ferroelectricity. This shows that negative capacitance is a more general phenomenon than previously thought and can be expected in a much broader range of materials exhibiting structural phase transitions.

Suggested Citation

  • Michael Hoffmann & Zheng Wang & Nujhat Tasneem & Ahmad Zubair & Prasanna Venkatesan Ravindran & Mengkun Tian & Anthony Arthur Gaskell & Dina Triyoso & Steven Consiglio & Kandabara Tapily & Robert Clar, 2022. "Antiferroelectric negative capacitance from a structural phase transition in zirconia," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28860-1
    DOI: 10.1038/s41467-022-28860-1
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    References listed on IDEAS

    as
    1. Ajay K. Yadav & Kayla X. Nguyen & Zijian Hong & Pablo García-Fernández & Pablo Aguado-Puente & Christopher T. Nelson & Sujit Das & Bhagwati Prasad & Daewoong Kwon & Suraj Cheema & Asif I. Khan & Chenm, 2019. "Spatially resolved steady-state negative capacitance," Nature, Nature, vol. 565(7740), pages 468-471, January.
    2. Michael Hoffmann & Franz P. G. Fengler & Melanie Herzig & Terence Mittmann & Benjamin Max & Uwe Schroeder & Raluca Negrea & Pintilie Lucian & Stefan Slesazeck & Thomas Mikolajick, 2019. "Unveiling the double-well energy landscape in a ferroelectric layer," Nature, Nature, vol. 565(7740), pages 464-467, January.
    3. Bin Xu & Jorge Íñiguez & L. Bellaiche, 2017. "Designing lead-free antiferroelectrics for energy storage," Nature Communications, Nature, vol. 8(1), pages 1-8, August.
    4. Pavlo Zubko & Jacek C. Wojdeł & Marios Hadjimichael & Stéphanie Fernandez-Pena & Anaïs Sené & Igor Luk’yanchuk & Jean-Marc Triscone & Jorge Íñiguez, 2016. "Negative capacitance in multidomain ferroelectric superlattices," Nature, Nature, vol. 534(7608), pages 524-528, June.
    5. A. K. Tagantsev & K. Vaideeswaran & S. B. Vakhrushev & A. V. Filimonov & R. G. Burkovsky & A. Shaganov & D. Andronikova & A. I. Rudskoy & A. Q. R. Baron & H. Uchiyama & D. Chernyshov & A. Bosak & Z. U, 2013. "The origin of antiferroelectricity in PbZrO3," Nature Communications, Nature, vol. 4(1), pages 1-8, October.
    6. Ajay K. Yadav & Kayla X. Nguyen & Zijian Hong & Pablo García-Fernández & Pablo Aguado-Puente & Christopher T. Nelson & Sujit Das & Bhagwati Prasad & Daewoong Kwon & Suraj Cheema & Asif I. Khan & Chenm, 2019. "Author Correction: Spatially resolved steady-state negative capacitance," Nature, Nature, vol. 568(7753), pages 13-13, April.
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