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Cross-linked polyaniline for production of long lifespan aqueous iron||organic batteries with electrochromic properties

Author

Listed:
  • Haiming Lv

    (Songshan Lake Materials Laboratory, Dongguan
    Yan’an University)

  • Zhiquan Wei

    (City University of Hong Kong)

  • Cuiping Han

    (Faculty of Materials Science and Engineering, Low Dimensional Energy Materials Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences)

  • Xiaolong Yang

    (Songshan Lake Materials Laboratory, Dongguan)

  • Zijie Tang

    (Songshan Lake Materials Laboratory, Dongguan)

  • Yantu Zhang

    (Yan’an University)

  • Chunyi Zhi

    (Songshan Lake Materials Laboratory, Dongguan
    City University of Hong Kong)

  • Hongfei Li

    (Songshan Lake Materials Laboratory, Dongguan
    Southern University of Science and Technology, Shenzhen)

Abstract

Aqueous iron batteries are appealing candidates for large-scale energy storage due to their safety and low-cost aspects. However, the development of aqueous Fe batteries is hindered by their inadequate long-term cycling stability. Here, we propose the synthesis and application as positive electrode active material of cross-linked polyaniline (C-PANI). We use melamine as the crosslinker to improve the electronical conductivity and electrochemical stability of the C-PANI. Indeed, when the C-PANI is tested in combination with a Fe metal negative electrode and 1 M iron trifluoromethanesulfonate (Fe(TOF)2) electrolyte solution, the coin cell can deliver a specific capacity of about 110 mAh g−1 and an average discharge voltage of 0.55 V after 39,000 cycles at 25 A g−1 with a test temperature of 28 °C ± 1 °C. Furthermore, mechanistic studies suggest that Fe2+ ions are bonded to TOF− anions to form positively charged complexes Fe(TOF)+, which are stored with protons in the C-PANI electrode structures. Finally, we also demonstrate the use of C-PANI in combination with a polymeric hydrogel electrolyte to produce a flexible reflective electrochromic lab-scale iron battery prototype.

Suggested Citation

  • Haiming Lv & Zhiquan Wei & Cuiping Han & Xiaolong Yang & Zijie Tang & Yantu Zhang & Chunyi Zhi & Hongfei Li, 2023. "Cross-linked polyaniline for production of long lifespan aqueous iron||organic batteries with electrochromic properties," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38890-y
    DOI: 10.1038/s41467-023-38890-y
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    References listed on IDEAS

    as
    1. Cuiping Han & Hongfei Li & Yu Li & Jiaxiong Zhu & Chunyi Zhi, 2021. "Proton-assisted calcium-ion storage in aromatic organic molecular crystal with coplanar stacked structure," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Xianyong Wu & Jessica J. Hong & Woochul Shin & Lu Ma & Tongchao Liu & Xuanxuan Bi & Yifei Yuan & Yitong Qi & T. Wesley Surta & Wenxi Huang & Joerg Neuefeind & Tianpin Wu & P. Alex Greaney & Jun Lu & X, 2019. "Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries," Nature Energy, Nature, vol. 4(2), pages 123-130, February.
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