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Square ice in graphene nanocapillaries

Author

Listed:
  • G. Algara-Siller

    (Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, University of Ulm, 89081 Ulm, Germany)

  • O. Lehtinen

    (Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, University of Ulm, 89081 Ulm, Germany)

  • F. C. Wang

    (Chinese Academy of Sciences Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China)

  • R. R. Nair

    (School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK)

  • U. Kaiser

    (Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, University of Ulm, 89081 Ulm, Germany)

  • H. A. Wu

    (Chinese Academy of Sciences Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China)

  • A. K. Geim

    (School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK)

  • I. V. Grigorieva

    (School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK)

Abstract

The structure of the low-dimensional water confined in hydrophobic pores is shown, using electron microscopy and supported by molecular dynamics simulations, to be ‘square ice’, which does not have the conventional tetrahedral hydrogen bonding.

Suggested Citation

  • G. Algara-Siller & O. Lehtinen & F. C. Wang & R. R. Nair & U. Kaiser & H. A. Wu & A. K. Geim & I. V. Grigorieva, 2015. "Square ice in graphene nanocapillaries," Nature, Nature, vol. 519(7544), pages 443-445, March.
    • Handle: RePEc:nat:nature:v:519:y:2015:i:7544:d:10.1038_nature14295
    DOI: 10.1038/nature14295
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    Cited by:

    1. Bo Lin & Jian Jiang & Xiao Cheng Zeng & Lei Li, 2023. "Temperature-pressure phase diagram of confined monolayer water/ice at first-principles accuracy with a machine-learning force field," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Xin Yu & Wencai Ren, 2023. "2D CdPS3-based versatile superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    3. Ng, Ving Onn & Hong, XiangYu & Yu, Hao & Wu, HengAn & Hung, Yew Mun, 2022. "Anomalously enhanced thermal performance of micro heat pipes coated with heterogeneous superwettable graphene nanostructures," Applied Energy, Elsevier, vol. 326(C).
    4. Kuichang Zuo & Xiang Zhang & Xiaochuan Huang & Eliezer F. Oliveira & Hua Guo & Tianshu Zhai & Weipeng Wang & Pedro J. J. Alvarez & Menachem Elimelech & Pulickel M. Ajayan & Jun Lou & Qilin Li, 2022. "Ultrahigh resistance of hexagonal boron nitride to mineral scale formation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Mailis Lounasvuori & Yangyunli Sun & Tyler S. Mathis & Ljiljana Puskar & Ulrich Schade & De-En Jiang & Yury Gogotsi & Tristan Petit, 2023. "Vibrational signature of hydrated protons confined in MXene interlayers," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Ruijian Zhu & Yanting Wang, 2024. "A critical edge number revealed for phase stabilities of two-dimensional ball-stick polygons," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Pavan Ravindra & Xavier R. Advincula & Christoph Schran & Angelos Michaelides & Venkat Kapil, 2024. "Quasi-one-dimensional hydrogen bonding in nanoconfined ice," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    8. Tomohito Sudare & Takuro Yamaguchi & Mizuki Ueda & Hiromasa Shiiba & Hideki Tanaka & Mongkol Tipplook & Fumitaka Hayashi & Katsuya Teshima, 2022. "Critical role of water structure around interlayer ions for ion storage in layered double hydroxides," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    9. Felix Kohler & Olivier Pierre-Louis & Dag Kristian Dysthe, 2022. "Crystal growth in confinement," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    10. Tong, Xuan & Li, Nianqi & Zeng, Min & Wang, Qiuwang, 2019. "Organic phase change materials confined in carbon-based materials for thermal properties enhancement: Recent advancement and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 398-422.
    11. Nawapong Unsuree & Sorasak Phanphak & Pongthep Prajongtat & Aritsa Bunpheng & Kulpavee Jitapunkul & Pornpis Kongputhon & Pannaree Srinoi & Pawin Iamprasertkun & Wisit Hirunpinyopas, 2021. "A Review: Ion Transport of Two-Dimensional Materials in Novel Technologies from Macro to Nanoscopic Perspectives," Energies, MDPI, vol. 14(18), pages 1-38, September.
    12. Hao-Ting Chin & Jiri Klimes & I-Fan Hu & Ding-Rui Chen & Hai-Thai Nguyen & Ting-Wei Chen & Shao-Wei Ma & Mario Hofmann & Chi-Te Liang & Ya-Ping Hsieh, 2021. "Ferroelectric 2D ice under graphene confinement," Nature Communications, Nature, vol. 12(1), pages 1-7, December.

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