IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-33456-w.html
   My bibliography  Save this article

Understanding water transport through graphene-based nanochannels via experimental control of slip length

Author

Listed:
  • Xinyue Wen

    (University of New South Wales)

  • Tobias Foller

    (University of New South Wales)

  • Xiaoheng Jin

    (University of New South Wales)

  • Tiziana Musso

    (University of New South Wales)

  • Priyank Kumar

    (University of New South Wales)

  • Rakesh Joshi

    (University of New South Wales)

Abstract

The water transport along graphene-based nanochannels has gained significant interest. However, experimental access to the influence of defects and impurities on transport poses a critical knowledge gap. Here, we investigate the water transport of cation intercalated graphene oxide membranes. The cations act as water-attracting impurities on the channel walls. Via water transport experiments, we show that the slip length of the nanochannels decay exponentially with the hydrated diameter of the intercalated cations, confirming that water transport is governed by the interaction between water molecules and the impurities on the channel wall. The exponential decay of slip length approximates non-slip conditions. This offers experimental support for the use of the Hagen-Poiseuille equation in graphene-based nanochannels, which was previously only confirmed by simulations. Our study gives valuable feedback to theoretical predictions of the water transport along graphene-based channels with water-attracting impurities.

Suggested Citation

  • Xinyue Wen & Tobias Foller & Xiaoheng Jin & Tiziana Musso & Priyank Kumar & Rakesh Joshi, 2022. "Understanding water transport through graphene-based nanochannels via experimental control of slip length," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33456-w
    DOI: 10.1038/s41467-022-33456-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-33456-w
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-33456-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. A. Keerthi & A. K. Geim & A. Janardanan & A. P. Rooney & A. Esfandiar & S. Hu & S. A. Dar & I. V. Grigorieva & S. J. Haigh & F. C. Wang & B. Radha, 2018. "Ballistic molecular transport through two-dimensional channels," Nature, Nature, vol. 558(7710), pages 420-424, June.
    2. B. Radha & A. Esfandiar & F. C. Wang & A. P. Rooney & K. Gopinadhan & A. Keerthi & A. Mishchenko & A. Janardanan & P. Blake & L. Fumagalli & M. Lozada-Hidalgo & S. Garaj & S. J. Haigh & I. V. Grigorie, 2016. "Molecular transport through capillaries made with atomic-scale precision," Nature, Nature, vol. 538(7624), pages 222-225, October.
    3. Nikita Kavokine & Marie-Laure Bocquet & Lydéric Bocquet, 2022. "Fluctuation-induced quantum friction in nanoscale water flows," Nature, Nature, vol. 602(7895), pages 84-90, February.
    4. Félix Mouhat & François-Xavier Coudert & Marie-Laure Bocquet, 2020. "Structure and chemistry of graphene oxide in liquid water from first principles," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    5. Liang Chen & Guosheng Shi & Jie Shen & Bingquan Peng & Bowu Zhang & Yuzhu Wang & Fenggang Bian & Jiajun Wang & Deyuan Li & Zhe Qian & Gang Xu & Gongping Liu & Jianrong Zeng & Lijuan Zhang & Yizhou Yan, 2017. "Ion sieving in graphene oxide membranes via cationic control of interlayer spacing," Nature, Nature, vol. 550(7676), pages 380-383, October.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhipeng Wang & Liqin Huang & Xue Dong & Tong Wu & Qi Qing & Jing Chen & Yuexiang Lu & Chao Xu, 2023. "Ion sieving in graphene oxide membrane enables efficient actinides/lanthanides separation," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Qian Zhang & Bo Gao & Ling Zhang & Xiaopeng Liu & Jixiang Cui & Yijun Cao & Hongbo Zeng & Qun Xu & Xinwei Cui & Lei Jiang, 2023. "Anomalous water molecular gating from atomic-scale graphene capillaries for precise and ultrafast molecular sieving," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Nawapong Unsuree & Sorasak Phanphak & Pongthep Prajongtat & Aritsa Bunpheng & Kulpavee Jitapunkul & Pornpis Kongputhon & Pannaree Srinoi & Pawin Iamprasertkun & Wisit Hirunpinyopas, 2021. "A Review: Ion Transport of Two-Dimensional Materials in Novel Technologies from Macro to Nanoscopic Perspectives," Energies, MDPI, vol. 14(18), pages 1-38, September.
    4. Weiming Wang & Qingguo Liu & Yingnan Liu & Rigong Zhang & Tian Cheng & Youguo Yan & Qianze Hu & Tingting Li, 2023. "Research Status, Existing Problems, and the Prospect of New Methods of Determining the Lower Limit of the Physical Properties of Tight Sandstone Reservoirs," Energies, MDPI, vol. 16(15), pages 1-19, July.
    5. Cheng Chi & Gongze Liu & Meng An & Yufeng Zhang & Dongxing Song & Xin Qi & Chunyu Zhao & Zequn Wang & Yanzheng Du & Zizhen Lin & Yang Lu & He Huang & Yang Li & Chongjia Lin & Weigang Ma & Baoling Huan, 2023. "Reversible bipolar thermopower of ionic thermoelectric polymer composite for cyclic energy generation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Quan Peng & Ruoyu Wang & Zilin Zhao & Shihong Lin & Ying Liu & Dianyu Dong & Zheng Wang & Yiman He & Yuzhang Zhu & Jian Jin & Lei Jiang, 2024. "Extreme Li-Mg selectivity via precise ion size differentiation of polyamide membrane," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Bo Lin & Jian Jiang & Xiao Cheng Zeng & Lei Li, 2023. "Temperature-pressure phase diagram of confined monolayer water/ice at first-principles accuracy with a machine-learning force field," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Kuichang Zuo & Xiang Zhang & Xiaochuan Huang & Eliezer F. Oliveira & Hua Guo & Tianshu Zhai & Weipeng Wang & Pedro J. J. Alvarez & Menachem Elimelech & Pulickel M. Ajayan & Jun Lou & Qilin Li, 2022. "Ultrahigh resistance of hexagonal boron nitride to mineral scale formation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Andrzej Olejniczak & Ruslan A. Rymzhanov, 2023. "From nanohole to ultralong straight nanochannel fabrication in graphene oxide with swift heavy ions," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    10. Hongjian Wang & Yeming Zhai & Yang Li & Yu Cao & Benbing Shi & Runlai Li & Zingting Zhu & Haifei Jiang & Zheyuan Guo & Meidi Wang & Long Chen & Yawei Liu & Kai-Ge Zhou & Fusheng Pan & Zhongyi Jiang, 2022. "Covalent organic framework membranes for efficient separation of monovalent cations," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    11. Yuanxi Yu & Chenxing Yang & Matteo Baggioli & Anthony E. Phillips & Alessio Zaccone & Lei Zhang & Ryoichi Kajimoto & Mitsutaka Nakamura & Dehong Yu & Liang Hong, 2022. "The ω3 scaling of the vibrational density of states in quasi-2D nanoconfined solids," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    12. Ryusuke Futamura & Taku Iiyama & Takahiro Ueda & Patrick A. Bonnaud & François-Xavier Coudert & Ayumi Furuse & Hideki Tanaka & Roland J. -M. Pellenq & Katsumi Kaneko, 2024. "Staggered structural dynamic-mediated selective adsorption of H2O/D2O on flexible graphene oxide nanosheets," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    13. JianHao Qian & HengAn Wu & FengChao Wang, 2023. "A generalized Knudsen theory for gas transport with specular and diffuse reflections," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    14. Nathan Ronceray & Massimo Spina & Vanessa Hui Yin Chou & Chwee Teck Lim & Andre K. Geim & Slaven Garaj, 2024. "Elastocapillarity-driven 2D nano-switches enable zeptoliter-scale liquid encapsulation," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    15. Shuangqiao Han & Junyong Zhu & Adam A. Uliana & Dongyang Li & Yatao Zhang & Lin Zhang & Yong Wang & Tao He & Menachem Elimelech, 2022. "Microporous organic nanotube assisted design of high performance nanofiltration membranes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    16. Peifu Cheng & Francesco Fornasiero & Melinda L. Jue & Wonhee Ko & An-Ping Li & Juan Carlos Idrobo & Michael S. H. Boutilier & Piran R. Kidambi, 2022. "Differences in water and vapor transport through angstrom-scale pores in atomically thin membranes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    17. Jincheng Tong & Nathan Bruyn & Adriana Alieva & Elizabeth. J. Legge & Matthew Boyes & Xiuju Song & Alvin J. Walisinghe & Andrew J. Pollard & Michael W. Anderson & Thomas Vetter & Manuel Melle-Franco &, 2024. "Crystallization of molecular layers produced under confinement onto a surface," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    18. Haiguang Zhang & Jiajian Xing & Gaoliang Wei & Xu Wang & Shuo Chen & Xie Quan, 2024. "Electrostatic-induced ion-confined partitioning in graphene nanolaminate membrane for breaking anion–cation co-transport to enhance desalination," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    19. Yuan Hou & Jingzhuo Zhou & Zezhou He & Juzheng Chen & Mengya Zhu & HengAn Wu & Yang Lu, 2024. "Tuning instability in suspended monolayer 2D materials," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Zhen Zhang & Preeti Bhauriyal & Hafeesudeen Sahabudeen & Zhiyong Wang & Xiaohui Liu & Mike Hambsch & Stefan C. B. Mannsfeld & Renhao Dong & Thomas Heine & Xinliang Feng, 2022. "Cation-selective two-dimensional polyimine membranes for high-performance osmotic energy conversion," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33456-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.