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Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries

Author

Listed:
  • Hyeokjin Kwon

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Hyun-Ji Choi

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Jung-kyu Jang

    (Korea Research Institute of Chemical Technology (KRICT))

  • Jinhong Lee

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Jinkwan Jung

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Wonjun Lee

    (Ulsan National Institute of Science and Technology (UNIST))

  • Youngil Roh

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Jaewon Baek

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Dong Jae Shin

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Ju-Hyuk Lee

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Nam-Soon Choi

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Ying Shirley Meng

    (University of California at San Diego
    University of Chicago)

  • Hee-Tak Kim

    (Korea Advanced Institute of Science and Technology (KAIST)
    Korea Advanced Institute of Science and Technology (KAIST))

Abstract

The pulverization of lithium metal electrodes during cycling recently has been suppressed through various techniques, but the issue of irreversible consumption of the electrolyte remains a critical challenge, hindering the progress of energy-dense lithium metal batteries. Here, we design a single-ion-conductor-based composite layer on the lithium metal electrode, which significantly reduces the liquid electrolyte loss via adjusting the solvation environment of moving Li+ in the layer. A Li||Ni0.5Mn0.3Co0.2O2 pouch cell with a thin lithium metal (N/P of 2.15), high loading cathode (21.5 mg cm−2), and carbonate electrolyte achieves 400 cycles at the electrolyte to capacity ratio of 2.15 g Ah−1 (2.44 g Ah−1 including mass of composite layer) or 100 cycles at 1.28 g Ah−1 (1.57 g Ah−1 including mass of composite layer) under a stack pressure of 280 kPa (0.2 C charge with a constant voltage charge at 4.3 V to 0.05 C and 1.0 C discharge within a voltage window of 4.3 V to 3.0 V). The rational design of the single-ion-conductor-based composite layer demonstrated in this work provides a way forward for constructing energy-dense rechargeable lithium metal batteries with minimal electrolyte content.

Suggested Citation

  • Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39673-1
    DOI: 10.1038/s41467-023-39673-1
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    as
    1. A. J. Louli & A. Eldesoky & Rochelle Weber & M. Genovese & Matt Coon & Jack deGooyer & Zhe Deng & R. T. White & Jaehan Lee & Thomas Rodgers & R. Petibon & S. Hy & Shawn J. H. Cheng & J. R. Dahn, 2020. "Diagnosing and correcting anode-free cell failure via electrolyte and morphological analysis," Nature Energy, Nature, vol. 5(9), pages 693-702, September.
    2. Zhiao Yu & Hansen Wang & Xian Kong & William Huang & Yuchi Tsao & David G. Mackanic & Kecheng Wang & Xinchang Wang & Wenxiao Huang & Snehashis Choudhury & Yu Zheng & Chibueze V. Amanchukwu & Samantha , 2020. "Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries," Nature Energy, Nature, vol. 5(7), pages 526-533, July.
    3. Jun Liu & Zhenan Bao & Yi Cui & Eric J. Dufek & John B. Goodenough & Peter Khalifah & Qiuyan Li & Bor Yann Liaw & Ping Liu & Arumugam Manthiram & Y. Shirley Meng & Venkat R. Subramanian & Michael F. T, 2019. "Pathways for practical high-energy long-cycling lithium metal batteries," Nature Energy, Nature, vol. 4(3), pages 180-186, March.
    4. Jürgen Janek & Wolfgang G. Zeier, 2016. "A solid future for battery development," Nature Energy, Nature, vol. 1(9), pages 1-4, September.
    5. Paul Albertus & Susan Babinec & Scott Litzelman & Aron Newman, 2018. "Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries," Nature Energy, Nature, vol. 3(1), pages 16-21, January.
    6. Qidi Wang & Zhenpeng Yao & Chenglong Zhao & Tomas Verhallen & Daniel P. Tabor & Ming Liu & Frans Ooms & Feiyu Kang & Alán Aspuru-Guzik & Yong-Sheng Hu & Marnix Wagemaker & Baohua Li, 2020. "Interface chemistry of an amide electrolyte for highly reversible lithium metal batteries," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    7. Yong-Gun Lee & Satoshi Fujiki & Changhoon Jung & Naoki Suzuki & Nobuyoshi Yashiro & Ryo Omoda & Dong-Su Ko & Tomoyuki Shiratsuchi & Toshinori Sugimoto & Saebom Ryu & Jun Hwan Ku & Taku Watanabe & Youn, 2020. "High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes," Nature Energy, Nature, vol. 5(4), pages 299-308, April.
    8. Jianhui Wang & Yuki Yamada & Keitaro Sodeyama & Ching Hua Chiang & Yoshitaka Tateyama & Atsuo Yamada, 2016. "Superconcentrated electrolytes for a high-voltage lithium-ion battery," Nature Communications, Nature, vol. 7(1), pages 1-9, November.
    9. Chengcheng Fang & Jinxing Li & Minghao Zhang & Yihui Zhang & Fan Yang & Jungwoo Z. Lee & Min-Han Lee & Judith Alvarado & Marshall A. Schroeder & Yangyuchen Yang & Bingyu Lu & Nicholas Williams & Migue, 2019. "Quantifying inactive lithium in lithium metal batteries," Nature, Nature, vol. 572(7770), pages 511-515, August.
    10. Chaojiang Niu & Dianying Liu & Joshua A. Lochala & Cassidy S. Anderson & Xia Cao & Mark E. Gross & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2021. "Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries," Nature Energy, Nature, vol. 6(7), pages 723-732, July.
    11. Jiangfeng Qian & Wesley A. Henderson & Wu Xu & Priyanka Bhattacharya & Mark Engelhard & Oleg Borodin & Ji-Guang Zhang, 2015. "High rate and stable cycling of lithium metal anode," Nature Communications, Nature, vol. 6(1), pages 1-9, May.
    12. Chaojiang Niu & Hongkyung Lee & Shuru Chen & Qiuyan Li & Jason Du & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2019. "High-energy lithium metal pouch cells with limited anode swelling and long stable cycles," Nature Energy, Nature, vol. 4(7), pages 551-559, July.
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