IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-48889-8.html
   My bibliography  Save this article

Synergetic regulation of SEI mechanics and crystallographic orientation for stable lithium metal pouch cells

Author

Listed:
  • Yanhua Zhang

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Rui Qiao

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Qiaona Nie

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Peiyu Zhao

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Yong Li

    (Shanghai Institute of Space Power-Sources)

  • Yunfei Hong

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Shengjie Chen

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Chao Li

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University
    Xi’an Jiaotong University)

  • Baoyu Sun

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Hao Fan

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Junkai Deng

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Jingying Xie

    (Shanghai Institute of Space Power-Sources)

  • Feng Liu

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

  • Jiangxuan Song

    (Shaanxi International Research Center for Soft Matter, Xi’an Jiaotong University)

Abstract

The advancement of Li-metal batteries is significantly impeded by the presence of unstable solid electrolyte interphase and Li dendrites upon cycling. Herein, we present an innovative approach to address these issues through the synergetic regulation of solid electrolyte interphase mechanics and Li crystallography using yttrium fluoride/polymethyl methacrylate composite layer. Specifically, we demonstrate the in-situ generation of Y-doped lithium metal through the reaction of composite layer with Li metal, which reduces the surface energy of the (200) plane, and tunes the preferential crystallographic orientation to (200) plane from conventional (110) plane during Li plating. These changes effectively passivate Li metal, thereby significantly reducing undesired side reactions between Li and electrolytes by 4 times. Meanwhile, the composite layer with suitable modulus (~1.02 GPa) can enhance mechanical stability and maintain structural stability of SEI. Consequently, a 4.2 Ah pouch cell with high energy density of 468 Wh kg−1 and remarkable capacity stability of 0.08% decay/cycle is demonstrated under harsh condition, such as high-areal-capacity cathode (6 mAh cm−2), lean electrolyte (1.98 g Ah−1), and high current density (3 mA cm−2). Our findings highlight the potential of reactive composite layer as a promising strategy for the development of stable Li-metal batteries.

Suggested Citation

  • Yanhua Zhang & Rui Qiao & Qiaona Nie & Peiyu Zhao & Yong Li & Yunfei Hong & Shengjie Chen & Chao Li & Baoyu Sun & Hao Fan & Junkai Deng & Jingying Xie & Feng Liu & Jiangxuan Song, 2024. "Synergetic regulation of SEI mechanics and crystallographic orientation for stable lithium metal pouch cells," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48889-8
    DOI: 10.1038/s41467-024-48889-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-48889-8
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-48889-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhiao Yu & Paul E. Rudnicki & Zewen Zhang & Zhuojun Huang & Hasan Celik & Solomon T. Oyakhire & Yuelang Chen & Xian Kong & Sang Cheol Kim & Xin Xiao & Hansen Wang & Yu Zheng & Gaurav A. Kamat & Mun Se, 2022. "Rational solvent molecule tuning for high-performance lithium metal battery electrolytes," Nature Energy, Nature, vol. 7(1), pages 94-106, January.
    2. Jun Liu & Zhenan Bao & Yi Cui & Eric J. Dufek & John B. Goodenough & Peter Khalifah & Qiuyan Li & Bor Yann Liaw & Ping Liu & Arumugam Manthiram & Y. Shirley Meng & Venkat R. Subramanian & Michael F. T, 2019. "Pathways for practical high-energy long-cycling lithium metal batteries," Nature Energy, Nature, vol. 4(3), pages 180-186, March.
    3. Sang Cheol Kim & Jingyang Wang & Rong Xu & Pu Zhang & Yuelang Chen & Zhuojun Huang & Yufei Yang & Zhiao Yu & Solomon T. Oyakhire & Wenbo Zhang & Louisa C. Greenburg & Mun Sek Kim & David T. Boyle & Ph, 2023. "High-entropy electrolytes for practical lithium metal batteries," Nature Energy, Nature, vol. 8(8), pages 814-826, August.
    4. Chaojiang Niu & Dianying Liu & Joshua A. Lochala & Cassidy S. Anderson & Xia Cao & Mark E. Gross & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2021. "Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries," Nature Energy, Nature, vol. 6(7), pages 723-732, July.
    5. Qian-Kui Zhang & Xue-Qiang Zhang & Jing Wan & Nan Yao & Ting-Lu Song & Jin Xie & Li-Peng Hou & Ming-Yue Zhou & Xiang Chen & Bo-Quan Li & Rui Wen & Hong-Jie Peng & Qiang Zhang & Jia-Qi Huang, 2023. "Homogeneous and mechanically stable solid–electrolyte interphase enabled by trioxane-modulated electrolytes for lithium metal batteries," Nature Energy, Nature, vol. 8(7), pages 725-735, July.
    6. Chaojiang Niu & Hongkyung Lee & Shuru Chen & Qiuyan Li & Jason Du & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2019. "High-energy lithium metal pouch cells with limited anode swelling and long stable cycles," Nature Energy, Nature, vol. 4(7), pages 551-559, July.
    7. Xintong Yuan & Bo Liu & Matthew Mecklenburg & Yuzhang Li, 2023. "Ultrafast deposition of faceted lithium polyhedra by outpacing SEI formation," Nature, Nature, vol. 620(7972), pages 86-91, August.
    8. Yuliang Gao & Fahong Qiao & Jingyuan You & Zengying Ren & Nan Li & Kun Zhang & Chao Shen & Ting Jin & Keyu Xie, 2022. "Effect of the supergravity on the formation and cycle life of non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Chengcheng Fang & Bingyu Lu & Gorakh Pawar & Minghao Zhang & Diyi Cheng & Shuru Chen & Miguel Ceja & Jean-Marie Doux & Henry Musrock & Mei Cai & Boryann Liaw & Ying Shirley Meng, 2021. "Pressure-tailored lithium deposition and dissolution in lithium metal batteries," Nature Energy, Nature, vol. 6(10), pages 987-994, October.
    10. Yuxiang Xie & Yixin Huang & Yinggan Zhang & Tairui Wu & Shishi Liu & Miaolan Sun & Bruce Lee & Zhen Lin & Hui Chen & Peng Dai & Zheng Huang & Jian Yang & Chenguang Shi & Deyin Wu & Ling Huang & Yingji, 2023. "Surface modification using heptafluorobutyric acid to produce highly stable Li metal anodes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    11. Zhiao Yu & Hansen Wang & Xian Kong & William Huang & Yuchi Tsao & David G. Mackanic & Kecheng Wang & Xinchang Wang & Wenxiao Huang & Snehashis Choudhury & Yu Zheng & Chibueze V. Amanchukwu & Samantha , 2020. "Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries," Nature Energy, Nature, vol. 5(7), pages 526-533, July.
    12. Minglei Mao & Xiao Ji & Qiyu Wang & Zejing Lin & Meiying Li & Tao Liu & Chengliang Wang & Yong-Sheng Hu & Hong Li & Xuejie Huang & Liquan Chen & Liumin Suo, 2023. "Anion-enrichment interface enables high-voltage anode-free lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    13. Yawei Chen & Menghao Li & Yue Liu & Yulin Jie & Wanxia Li & Fanyang Huang & Xinpeng Li & Zixu He & Xiaodi Ren & Yunhua Chen & Xianhui Meng & Tao Cheng & Meng Gu & Shuhong Jiao & Ruiguo Cao, 2023. "Origin of dendrite-free lithium deposition in concentrated electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    14. Qing Zhao & Yue Deng & Nyalaliska W. Utomo & Jingxu Zheng & Prayag Biswal & Jiefu Yin & Lynden A. Archer, 2021. "On the crystallography and reversibility of lithium electrodeposits at ultrahigh capacity," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    15. Chengbin Jin & Tiefeng Liu & Ouwei Sheng & Matthew Li & Tongchao Liu & Yifei Yuan & Jianwei Nai & Zhijin Ju & Wenkui Zhang & Yujing Liu & Yao Wang & Zhan Lin & Jun Lu & Xinyong Tao, 2021. "Rejuvenating dead lithium supply in lithium metal anodes by iodine redox," Nature Energy, Nature, vol. 6(4), pages 378-387, April.
    16. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    17. Zhaohui Wu & Chunyang Wang & Zeyu Hui & Haodong Liu & Shen Wang & Sicen Yu & Xing Xing & John Holoubek & Qiushi Miao & Huolin L. Xin & Ping Liu, 2023. "Growing single-crystalline seeds on lithiophobic substrates to enable fast-charging lithium-metal batteries," Nature Energy, Nature, vol. 8(4), pages 340-350, April.
    18. Zhuojun Huang & Jian-Cheng Lai & Sheng-Lun Liao & Zhiao Yu & Yuelang Chen & Weilai Yu & Huaxin Gong & Xin Gao & Yufei Yang & Jian Qin & Yi Cui & Zhenan Bao, 2023. "A salt-philic, solvent-phobic interfacial coating design for lithium metal electrodes," Nature Energy, Nature, vol. 8(6), pages 577-585, June.
    19. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hyeokjin Kwon & Hongsin Kim & Jaemin Hwang & Wonsik Oh & Youngil Roh & Dongseok Shin & Hee-Tak Kim, 2024. "Borate–pyran lean electrolyte-based Li-metal batteries with minimal Li corrosion," Nature Energy, Nature, vol. 9(1), pages 57-69, January.
    2. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Jiawei Chen & Daoming Zhang & Lei Zhu & Mingzhu Liu & Tianle Zheng & Jie Xu & Jun Li & Fei Wang & Yonggang Wang & Xiaoli Dong & Yongyao Xia, 2024. "Hybridizing carbonate and ether at molecular scales for high-energy and high-safety lithium metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Jiaqi Cao & Yuansheng Shi & Aosong Gao & Guangyuan Du & Muhtar Dilxat & Yongfei Zhang & Mohang Cai & Guoyu Qian & Xueyi Lu & Fangyan Xie & Yang Sun & Xia Lu, 2024. "Hierarchical Li electrochemistry using alloy-type anode for high-energy-density Li metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    6. Yan Zhao & Tianhong Zhou & Timur Ashirov & Mario El Kazzi & Claudia Cancellieri & Lars P. H. Jeurgens & Jang Wook Choi & Ali Coskun, 2022. "Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Minglei Mao & Xiao Ji & Qiyu Wang & Zejing Lin & Meiying Li & Tao Liu & Chengliang Wang & Yong-Sheng Hu & Hong Li & Xuejie Huang & Liquan Chen & Liumin Suo, 2023. "Anion-enrichment interface enables high-voltage anode-free lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    8. Junyeob Moon & Dong Ok Kim & Lieven Bekaert & Munsoo Song & Jinkyu Chung & Danwon Lee & Annick Hubin & Jongwoo Lim, 2022. "Non-fluorinated non-solvating cosolvent enabling superior performance of lithium metal negative electrode battery," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    9. Junbo Zhang & Haikuo Zhang & Suting Weng & Ruhong Li & Di Lu & Tao Deng & Shuoqing Zhang & Ling Lv & Jiacheng Qi & Xuezhang Xiao & Liwu Fan & Shujiang Geng & Fuhui Wang & Lixin Chen & Malachi Noked & , 2023. "Multifunctional solvent molecule design enables high-voltage Li-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    10. Guangzhao Zhang & Jian Chang & Liguang Wang & Jiawei Li & Chaoyang Wang & Ruo Wang & Guoli Shi & Kai Yu & Wei Huang & Honghe Zheng & Tianpin Wu & Yonghong Deng & Jun Lu, 2023. "A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    11. Muhammad Mominur Rahman & Sha Tan & Yang Yang & Hui Zhong & Sanjit Ghose & Iradwikanari Waluyo & Adrian Hunt & Lu Ma & Xiao-Qing Yang & Enyuan Hu, 2023. "An inorganic-rich but LiF-free interphase for fast charging and long cycle life lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    13. Chutao Wang & Zongqiang Sun & Yaqing Liu & Lin Liu & Xiaoting Yin & Qing Hou & Jingmin Fan & Jiawei Yan & Ruming Yuan & Mingsen Zheng & Quanfeng Dong, 2024. "A weakly coordinating-intervention strategy for modulating Na+ solvation sheathes and constructing robust interphase in sodium-metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    14. Qian Wu & Mandi Fang & Shizhe Jiao & Siyuan Li & Shichao Zhang & Zeyu Shen & Shulan Mao & Jiale Mao & Jiahui Zhang & Yuanzhong Tan & Kang Shen & Jiaxing Lv & Wei Hu & Yi He & Yingying Lu, 2023. "Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    15. Zheng Li & Harsha Rao & Rasha Atwi & Bhuvaneswari M. Sivakumar & Bharat Gwalani & Scott Gray & Kee Sung Han & Thomas A. Everett & Tanvi A. Ajantiwalay & Vijayakumar Murugesan & Nav Nidhi Rajput & Vila, 2023. "Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    16. Feifei Wang & Jipeng Zhang & Haotian Lu & Hanbing Zhu & Zihui Chen & Lu Wang & Jinyang Yu & Conghui You & Wenhao Li & Jianwei Song & Zhe Weng & Chunpeng Yang & Quan-Hong Yang, 2023. "Production of gas-releasing electrolyte-replenishing Ah-scale zinc metal pouch cells with aqueous gel electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    17. Shuoqing Zhang & Ruhong Li & Nan Hu & Tao Deng & Suting Weng & Zunchun Wu & Di Lu & Haikuo Zhang & Junbo Zhang & Xuefeng Wang & Lixin Chen & Liwu Fan & Xiulin Fan, 2022. "Tackling realistic Li+ flux for high-energy lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    18. James T. Frith & Matthew J. Lacey & Ulderico Ulissi, 2023. "A non-academic perspective on the future of lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-17, December.
    19. Yangyang Feng & Yong Li & Jing Lin & Huyue Wu & Lei Zhu & Xiang Zhang & Linlin Zhang & Chuan-Fu Sun & Maoxiang Wu & Yaobing Wang, 2023. "Production of high-energy 6-Ah-level Li | |LiNi0.83Co0.11Mn0.06O2 multi-layer pouch cells via negative electrode protective layer coating strategy," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    20. Burak Aktekin & Luise M. Riegger & Svenja-K. Otto & Till Fuchs & Anja Henss & Jürgen Janek, 2023. "SEI growth on Lithium metal anodes in solid-state batteries quantified with coulometric titration time analysis," Nature Communications, Nature, vol. 14(1), pages 1-14, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48889-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.