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Observation of solid-state bidirectional thermal conductivity switching in antiferroelectric lead zirconate (PbZrO3)

Author

Listed:
  • Kiumars Aryana

    (University of Virginia)

  • John A. Tomko

    (University of Virginia)

  • Ran Gao

    (University of California, Berkeley)

  • Eric R. Hoglund

    (University of Virginia)

  • Takanori Mimura

    (University of Virginia)

  • Sara Makarem

    (University of Virginia)

  • Alejandro Salanova

    (University of Virginia)

  • Md Shafkat Bin Hoque

    (University of Virginia)

  • Thomas W. Pfeifer

    (University of Virginia)

  • David H. Olson

    (University of Virginia)

  • Jeffrey L. Braun

    (University of Virginia)

  • Joyeeta Nag

    (Western Digital Corporation)

  • John C. Read

    (Western Digital Corporation)

  • James M. Howe

    (University of Virginia)

  • Elizabeth J. Opila

    (University of Virginia
    University of Virginia)

  • Lane W. Martin

    (University of California, Berkeley
    Lawrence Berkeley National Laboratory)

  • Jon F. Ihlefeld

    (University of Virginia
    University of Virginia)

  • Patrick E. Hopkins

    (University of Virginia
    University of Virginia
    University of Virginia)

Abstract

Materials with tunable thermal properties enable on-demand control of temperature and heat flow, which is an integral component in the development of solid-state refrigeration, energy scavenging, and thermal circuits. Although gap-based and liquid-based thermal switches that work on the basis of mechanical movements have been an effective approach to control the flow of heat in the devices, their complex mechanisms impose considerable costs in latency, expense, and power consumption. As a consequence, materials that have multiple solid-state phases with distinct thermal properties are appealing for thermal management due to their simplicity, fast switching, and compactness. Thus, an ideal thermal switch should operate near or above room temperature, have a simple trigger mechanism, and offer a quick and large on/off switching ratio. In this study, we experimentally demonstrate that manipulating phonon scattering rates can switch the thermal conductivity of antiferroelectric PbZrO3 bidirectionally by −10% and +25% upon applying electrical and thermal excitation, respectively. Our approach takes advantage of two separate phase transformations in PbZrO3 that alter the phonon scattering rate in different manners. In this study, we demonstrate that PbZrO3 can serve as a fast (

Suggested Citation

  • Kiumars Aryana & John A. Tomko & Ran Gao & Eric R. Hoglund & Takanori Mimura & Sara Makarem & Alejandro Salanova & Md Shafkat Bin Hoque & Thomas W. Pfeifer & David H. Olson & Jeffrey L. Braun & Joyeet, 2022. "Observation of solid-state bidirectional thermal conductivity switching in antiferroelectric lead zirconate (PbZrO3)," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29023-y
    DOI: 10.1038/s41467-022-29023-y
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    References listed on IDEAS

    as
    1. Gou, Xiaolong & Ping, Huifeng & Ou, Qiang & Xiao, Heng & Qing, Shaowei, 2015. "A novel thermoelectric generation system with thermal switch," Applied Energy, Elsevier, vol. 160(C), pages 843-852.
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    Cited by:

    1. Subham Ranjan & Avulu Vinod Kumar & Rajadurai Chandrasekar & Satoshi Takamizawa, 2024. "Spatially controllable and mechanically switchable isomorphous organoferroeleastic crystal optical waveguides and networks," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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