IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37469-x.html
   My bibliography  Save this article

Well-defined double hysteresis loop in NaNbO3 antiferroelectrics

Author

Listed:
  • Nengneng Luo

    (Environment and Materials; Guangxi University)

  • Li Ma

    (Environment and Materials; Guangxi University
    Guangxi University)

  • Gengguang Luo

    (Environment and Materials; Guangxi University)

  • Chao Xu

    (The Hong Kong Polytechnic University)

  • Lixiang Rao

    (Beijing Institute of Technology)

  • Zhengu Chen

    (Environment and Materials; Guangxi University
    Guangxi University)

  • Zhenyong Cen

    (Environment and Materials; Guangxi University)

  • Qin Feng

    (Environment and Materials; Guangxi University)

  • Xiyong Chen

    (Environment and Materials; Guangxi University)

  • Fujita Toyohisa

    (Environment and Materials; Guangxi University)

  • Ye Zhu

    (The Hong Kong Polytechnic University)

  • Jiawang Hong

    (Beijing Institute of Technology)

  • Jing-Feng Li

    (Tsinghua University)

  • Shujun Zhang

    (University of Wollongong)

Abstract

Antiferroelectrics (AFEs) are promising candidates in energy-storage capacitors, electrocaloric solid-cooling, and displacement transducers. As an actively studied lead-free antiferroelectric (AFE) material, NaNbO3 has long suffered from its ferroelectric (FE)-like polarization-electric field (P-E) hysteresis loops with high remnant polarization and large hysteresis. Guided by theoretical calculations, a new strategy of reducing the oxygen octahedral tilting angle is proposed to stabilize the AFE P phase (Space group Pbma) of NaNbO3. To validate this, we judiciously introduced CaHfO3 with a low Goldschmidt tolerance factor and AgNbO3 with a low electronegativity difference into NaNbO3, the decreased cation displacements and [BO6] octahedral tilting angles were confirmed by Synchrotron X-ray powder diffraction and aberration-corrected scanning transmission electron microscopy. Of particular importance is that the 0.75NaNbO3−0.20AgNbO3−0.05CaHfO3 ceramic exhibits highly reversible phase transition between the AFE and FE states, showing well-defined double P-E loops and sprout-shaped strain-electric field curves with reduced hysteresis, low remnant polarization, high AFE-FE phase transition field, and zero negative strain. Our work provides a new strategy for designing NaNbO3-based AFE material with well-defined double P-E loops, which can also be extended to discover a variety of new lead-free AFEs.

Suggested Citation

  • Nengneng Luo & Li Ma & Gengguang Luo & Chao Xu & Lixiang Rao & Zhengu Chen & Zhenyong Cen & Qin Feng & Xiyong Chen & Fujita Toyohisa & Ye Zhu & Jiawang Hong & Jing-Feng Li & Shujun Zhang, 2023. "Well-defined double hysteresis loop in NaNbO3 antiferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37469-x
    DOI: 10.1038/s41467-023-37469-x
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37469-x
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-37469-x?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhengqian Fu & Xuefeng Chen & Zhenqin Li & Tengfei Hu & Linlin Zhang & Ping Lu & Shujun Zhang & Genshui Wang & Xianlin Dong & Fangfang Xu, 2020. "Unveiling the ferrielectric nature of PbZrO3-based antiferroelectric materials," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Nengneng Luo & Kai Han & Matthew J. Cabral & Xiaozhou Liao & Shujun Zhang & Changzhong Liao & Guangzu Zhang & Xiyong Chen & Qin Feng & Jing-Feng Li & Yuezhou Wei, 2020. "Constructing phase boundary in AgNbO3 antiferroelectrics: pathway simultaneously achieving high energy density and efficiency," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Benjamin H. Savitzky & Ismail El Baggari & Alemayehu S. Admasu & Jaewook Kim & Sang-Wook Cheong & Robert Hovden & Lena F. Kourkoutis, 2017. "Bending and breaking of stripes in a charge ordered manganite," Nature Communications, Nature, vol. 8(1), pages 1-6, December.
    4. John D. Budai & Jiawang Hong & Michael E. Manley & Eliot D. Specht & Chen W. Li & Jonathan Z. Tischler & Douglas L. Abernathy & Ayman H. Said & Bogdan M. Leu & Lynn A. Boatner & Robert J. McQueeney & , 2014. "Metallization of vanadium dioxide driven by large phonon entropy," Nature, Nature, vol. 515(7528), pages 535-539, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mao-Hua Zhang & Hui Ding & Sonja Egert & Changhao Zhao & Lorenzo Villa & Lovro Fulanović & Pedro B. Groszewicz & Gerd Buntkowsky & Hans-Joachim Kleebe & Karsten Albe & Andreas Klein & Jurij Koruza, 2023. "Tailoring high-energy storage NaNbO3-based materials from antiferroelectric to relaxor states," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Suk Hyun Sung & Yin Min Goh & Hyobin Yoo & Rebecca Engelke & Hongchao Xie & Kuan Zhang & Zidong Li & Andrew Ye & Parag B. Deotare & Ellad B. Tadmor & Andrew J. Mannix & Jiwoong Park & Liuyan Zhao & Ph, 2022. "Torsional periodic lattice distortions and diffraction of twisted 2D materials," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Suk Hyun Sung & Nishkarsh Agarwal & Ismail El Baggari & Patrick Kezer & Yin Min Goh & Noah Schnitzer & Jeremy M. Shen & Tony Chiang & Yu Liu & Wenjian Lu & Yuping Sun & Lena F. Kourkoutis & John T. He, 2024. "Endotaxial stabilization of 2D charge density waves with long-range order," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    4. Weichen Zhao & Diming Xu & Da Li & Max Avdeev & Hongmei Jing & Mengkang Xu & Yan Guo & Dier Shi & Tao Zhou & Wenfeng Liu & Dong Wang & Di Zhou, 2023. "Broad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Li-Feng Zhu & Shiqing Deng & Lei Zhao & Gen Li & Qi Wang & Linhai Li & Yongke Yan & He Qi & Bo-Ping Zhang & Jun Chen & Jing-Feng Li, 2023. "Heterovalent-doping-enabled atom-displacement fluctuation leads to ultrahigh energy-storage density in AgNbO3-based multilayer capacitors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Jianhong Duan & Kun Wei & Qianbiao Du & Linzhao Ma & Huifen Yu & He Qi & Yangchun Tan & Gaokuo Zhong & Hao Li, 2024. "High-entropy superparaelectrics with locally diverse ferroic distortion for high-capacitive energy storage," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    7. Mahmoud Darwish & Péter Neumann & János Mizsei & László Pohl, 2020. "Electro-Thermal Simulation of Vertical VO 2 Thermal-Electronic Circuit Elements," Energies, MDPI, vol. 13(13), pages 1-15, July.
    8. Liang Chen & Shiqing Deng & Hui Liu & Jie Wu & He Qi & Jun Chen, 2022. "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Yunting Guo & Bin Peng & Guangming Lu & Guohua Dong & Guannan Yang & Bohan Chen & Ruibin Qiu & Haixia Liu & Butong Zhang & Yufei Yao & Yanan Zhao & Suzhi Li & Xiangdong Ding & Jun Sun & Ming Liu, 2024. "Remarkable flexibility in freestanding single-crystalline antiferroelectric PbZrO3 membranes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Kiumars Aryana & John A. Tomko & Ran Gao & Eric R. Hoglund & Takanori Mimura & Sara Makarem & Alejandro Salanova & Md Shafkat Bin Hoque & Thomas W. Pfeifer & David H. Olson & Jeffrey L. Braun & Joyeet, 2022. "Observation of solid-state bidirectional thermal conductivity switching in antiferroelectric lead zirconate (PbZrO3)," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37469-x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.