IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-022-35569-8.html
   My bibliography  Save this article

Scalable high yield exfoliation for monolayer nanosheets

Author

Listed:
  • Zhuyuan Wang

    (Monash University)

  • Xue Yan

    (The University of Melbourne)

  • Qinfu Hou

    (Monash University)

  • Yue Liu

    (Monash University)

  • Xiangkang Zeng

    (The University of Queensland)

  • Yuan Kang

    (Monash University)

  • Wang Zhao

    (Monash University)

  • Xuefeng Li

    (Monash University)

  • Shi Yuan

    (Monash University)

  • Ruosang Qiu

    (Monash University)

  • Md Hemayet Uddin

    (Melbourne Centre for Nanofabrication)

  • Ruoxin Wang

    (Monash University)

  • Yun Xia

    (Monash University)

  • Meipeng Jian

    (Monash University)

  • Yan Kang

    (Vontron Membrane Technology Co. Ltd.)

  • Li Gao

    (South East Water Corporation)

  • Songmiao Liang

    (Vontron Membrane Technology Co. Ltd.)

  • Jefferson Zhe Liu

    (The University of Melbourne)

  • Huanting Wang

    (Monash University)

  • Xiwang Zhang

    (Monash University
    The University of Queensland)

Abstract

Although two-dimensional (2D) materials have grown into an extended family that accommodates hundreds of members and have demonstrated promising advantages in many fields, their practical applications are still hindered by the lack of scalable high-yield production of monolayer products. Here, we show that scalable production of monolayer nanosheets can be achieved by a facile ball-milling exfoliation method with the assistance of viscous polyethyleneimine (PEI) liquid. As a demonstration, graphite is effectively exfoliated into graphene nanosheets, achieving a high monolayer percentage of 97.9% at a yield of 78.3%. The universality of this technique is also proven by successfully exfoliating other types of representative layered materials with different structures, such as carbon nitride, covalent organic framework, zeolitic imidazolate framework and hexagonal boron nitride. This scalable exfoliation technique for monolayer nanosheets could catalyze the synthesis and industrialization of 2D nanosheet materials.

Suggested Citation

  • Zhuyuan Wang & Xue Yan & Qinfu Hou & Yue Liu & Xiangkang Zeng & Yuan Kang & Wang Zhao & Xuefeng Li & Shi Yuan & Ruosang Qiu & Md Hemayet Uddin & Ruoxin Wang & Yun Xia & Meipeng Jian & Yan Kang & Li Ga, 2023. "Scalable high yield exfoliation for monolayer nanosheets," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35569-8
    DOI: 10.1038/s41467-022-35569-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-35569-8
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-35569-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Weiwei Lei & Vadym N. Mochalin & Dan Liu & Si Qin & Yury Gogotsi & Ying Chen, 2015. "Boron nitride colloidal solutions, ultralight aerogels and freestanding membranes through one-step exfoliation and functionalization," Nature Communications, Nature, vol. 6(1), pages 1-8, December.
    2. Aleksey Falin & Qiran Cai & Elton J.G. Santos & Declan Scullion & Dong Qian & Rui Zhang & Zhi Yang & Shaoming Huang & Kenji Watanabe & Takashi Taniguchi & Matthew R. Barnett & Ying Chen & Rodney S. Ru, 2017. "Mechanical properties of atomically thin boron nitride and the role of interlayer interactions," Nature Communications, Nature, vol. 8(1), pages 1-9, August.
    3. Yuan Huang & Yu-Hao Pan & Rong Yang & Li-Hong Bao & Lei Meng & Hai-Lan Luo & Yong-Qing Cai & Guo-Dong Liu & Wen-Juan Zhao & Zhang Zhou & Liang-Mei Wu & Zhi-Li Zhu & Ming Huang & Li-Wei Liu & Lei Liu &, 2020. "Universal mechanical exfoliation of large-area 2D crystals," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhuyuan Wang & Ting Hu & Mike Tebyetekerwa & Xiangkang Zeng & Fan Du & Yuan Kang & Xuefeng Li & Hao Zhang & Huanting Wang & Xiwang Zhang, 2024. "Electricity generation from carbon dioxide adsorption by spatially nanoconfined ion separation," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhuyuan Wang & Ting Hu & Mike Tebyetekerwa & Xiangkang Zeng & Fan Du & Yuan Kang & Xuefeng Li & Hao Zhang & Huanting Wang & Xiwang Zhang, 2024. "Electricity generation from carbon dioxide adsorption by spatially nanoconfined ion separation," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Hongjun Xu & Ke Jia & Yuan Huang & Fanqi Meng & Qinghua Zhang & Yu Zhang & Chen Cheng & Guibin Lan & Jing Dong & Jinwu Wei & Jiafeng Feng & Congli He & Zhe Yuan & Mingliang Zhu & Wenqing He & Caihua W, 2023. "Electrical detection of spin pumping in van der Waals ferromagnetic Cr2Ge2Te6 with low magnetic damping," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Heng Wang & Yuying Zhu & Zhonghua Bai & Zechao Wang & Shuxu Hu & Hong-Yi Xie & Xiaopeng Hu & Jian Cui & Miaoling Huang & Jianhao Chen & Ying Ding & Lin Zhao & Xinyan Li & Qinghua Zhang & Lin Gu & X. J, 2023. "Prominent Josephson tunneling between twisted single copper oxide planes of Bi2Sr2-xLaxCuO6+y," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Longlong Yang & Yu Yuan & Bowen Fu & Jingnan Yang & Danjie Dai & Shushu Shi & Sai Yan & Rui Zhu & Xu Han & Hancong Li & Zhanchun Zuo & Can Wang & Yuan Huang & Kuijuan Jin & Qihuang Gong & Xiulai Xu, 2023. "Revealing broken valley symmetry of quantum emitters in WSe2 with chiral nanocavities," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Hari Krishna Neupane & Bipin Bhattarai & Narayan Prasad Adhikari, 2022. "Tuning transport properties of B and C sites vacancy defects Graphene/h-BN heterostructures: first-principles study," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 95(10), pages 1-10, October.
    6. Kuichang Zuo & Xiang Zhang & Xiaochuan Huang & Eliezer F. Oliveira & Hua Guo & Tianshu Zhai & Weipeng Wang & Pedro J. J. Alvarez & Menachem Elimelech & Pulickel M. Ajayan & Jun Lou & Qilin Li, 2022. "Ultrahigh resistance of hexagonal boron nitride to mineral scale formation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Kit-Ying Chan & Xi Shen & Jie Yang & Keng-Te Lin & Harun Venkatesan & Eunyoung Kim & Heng Zhang & Jeng-Hun Lee & Jinhong Yu & Jinglei Yang & Jang-Kyo Kim, 2022. "Scalable anisotropic cooling aerogels by additive freeze-casting," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    8. Alexey Falin & Haifeng Lv & Eli Janzen & James H. Edgar & Rui Zhang & Dong Qian & Hwo-Shuenn Sheu & Qiran Cai & Wei Gan & Xiaojun Wu & Elton J. G. Santos & Lu Hua Li, 2023. "Anomalous isotope effect on mechanical properties of single atomic layer Boron Nitride," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    9. Ruoxin Wang & Jianhao Qian & Xiaofang Chen & Ze-Xian Low & Yu Chen & Hongyu Ma & Heng-An Wu & Cara M. Doherty & Durga Acharya & Zongli Xie & Matthew R. Hill & Wei Shen & Fengchao Wang & Huanting Wang, 2023. "Pyro-layered heterostructured nanosheet membrane for hydrogen separation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Seungjun Lee & Dongjea Seo & Sang Hyun Park & Nezhueytl Izquierdo & Eng Hock Lee & Rehan Younas & Guanyu Zhou & Milan Palei & Anthony J. Hoffman & Min Seok Jang & Christopher L. Hinkle & Steven J. Koe, 2023. "Achieving near-perfect light absorption in atomically thin transition metal dichalcogenides through band nesting," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    11. Christoph W. Zollitsch & Safe Khan & Vu Thanh Trung Nam & Ivan A. Verzhbitskiy & Dimitrios Sagkovits & James O’Sullivan & Oscar W. Kennedy & Mara Strungaru & Elton J. G. Santos & John J. L. Morton & G, 2023. "Probing spin dynamics of ultra-thin van der Waals magnets via photon-magnon coupling," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    12. Yufei Sun & Yujia Wang & Enze Wang & Bolun Wang & Hengyi Zhao & Yongpan Zeng & Qinghua Zhang & Yonghuang Wu & Lin Gu & Xiaoyan Li & Kai Liu, 2022. "Determining the interlayer shearing in twisted bilayer MoS2 by nanoindentation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Han, Ning & Wang, Shuo & Rana, Ashvinder K. & Asif, Saira & Klemeš, Jiří Jaromír & Bokhari, Awais & Long, Jinlin & Thakur, Vijay Kumar & Zhao, Xiaolin, 2022. "Rational design of boron nitride with different dimensionalities for sustainable applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
    14. Lingbin Xie & Longlu Wang & Xia Liu & Jianmei Chen & Xixing Wen & Weiwei Zhao & Shujuan Liu & Qiang Zhao, 2024. "Flexible tungsten disulfide superstructure engineering for efficient alkaline hydrogen evolution in anion exchange membrane water electrolysers," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    15. Junpeng Zeng & Daowei He & Jingsi Qiao & Yating Li & Li Sun & Weisheng Li & Jiacheng Xie & Si Gao & Lijia Pan & Peng Wang & Yong Xu & Yun Li & Hao Qiu & Yi Shi & Jian-Bin Xu & Wei Ji & Xinran Wang, 2023. "Ultralow contact resistance in organic transistors via orbital hybridization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    16. Ruijin Sun & Jun Deng & Xiaowei Wu & Munan Hao & Ke Ma & Yuxin Ma & Changchun Zhao & Dezhong Meng & Xiaoyu Ji & Yiyang Ding & Yu Pang & Xin Qian & Ronggui Yang & Guodong Li & Zhilin Li & Linjie Dai & , 2023. "High anisotropy in electrical and thermal conductivity through the design of aerogel-like superlattice (NaOH)0.5NbSe2," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    17. Han, Weifang & Ge, Chunhua & Zhang, Rui & Ma, Zhiyan & Wang, Lixia & Zhang, Xiangdong, 2019. "Boron nitride foam as a polymer alternative in packaging phase change materials: Synthesis, thermal properties and shape stability," Applied Energy, Elsevier, vol. 238(C), pages 942-951.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35569-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.