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Pyro-layered heterostructured nanosheet membrane for hydrogen separation

Author

Listed:
  • Ruoxin Wang

    (Monash University)

  • Jianhao Qian

    (University of Science and Technology of China)

  • Xiaofang Chen

    (Monash University
    East China Normal University)

  • Ze-Xian Low

    (Monash University
    Nanjing Tech University)

  • Yu Chen

    (Monash University)

  • Hongyu Ma

    (Monash University)

  • Heng-An Wu

    (University of Science and Technology of China)

  • Cara M. Doherty

    (CSIRO Manufacturing)

  • Durga Acharya

    (CSIRO Manufacturing)

  • Zongli Xie

    (CSIRO Manufacturing)

  • Matthew R. Hill

    (Monash University
    CSIRO Manufacturing)

  • Wei Shen

    (Monash University)

  • Fengchao Wang

    (University of Science and Technology of China)

  • Huanting Wang

    (Monash University)

Abstract

Engineering different two-dimensional materials into heterostructured membranes with unique physiochemical properties and molecular sieving channels offers an effective way to design membranes for fast and selective gas molecule transport. Here we develop a simple and versatile pyro-layering approach to fabricate heterostructured membranes from boron nitride nanosheets as the main scaffold and graphene nanosheets derived from a chitosan precursor as the filler. The rearrangement of the graphene nanosheets adjoining the boron nitride nanosheets during the pyro-layering treatment forms precise in-plane slit-like nanochannels and a plane-to-plane spacing of ~3.0 Å, thereby endowing specific gas transport pathways for selective hydrogen transport. The heterostructured membrane shows a high H2 permeability of 849 Barrer, with a H2/CO2 selectivity of 290. This facile and scalable technique holds great promise for the fabrication of heterostructures as next-generation membranes for enhancing the efficiency of gas separation and purification processes.

Suggested Citation

  • Ruoxin Wang & Jianhao Qian & Xiaofang Chen & Ze-Xian Low & Yu Chen & Hongyu Ma & Heng-An Wu & Cara M. Doherty & Durga Acharya & Zongli Xie & Matthew R. Hill & Wei Shen & Fengchao Wang & Huanting Wang, 2023. "Pyro-layered heterostructured nanosheet membrane for hydrogen separation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37932-9
    DOI: 10.1038/s41467-023-37932-9
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    References listed on IDEAS

    as
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    Cited by:

    1. JianHao Qian & HengAn Wu & FengChao Wang, 2023. "A generalized Knudsen theory for gas transport with specular and diffuse reflections," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Zongyao Zhou & Kangning Zhao & Heng-Yu Chi & Yueqing Shen & Shuqing Song & Kuang-Jung Hsu & Mojtaba Chevalier & Wenxiong Shi & Kumar Varoon Agrawal, 2024. "Electrochemical-repaired porous graphene membranes for precise ion-ion separation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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