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Electronic metal–support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction

Author

Listed:
  • Yi Shi

    (National University of Singapore)

  • Zhi-Rui Ma

    (National University of Singapore)

  • Yi-Ying Xiao

    (National University of Singapore)

  • Yun-Chao Yin

    (Nanjing University)

  • Wen-Mao Huang

    (National University of Singapore)

  • Zhi-Chao Huang

    (National University of Singapore)

  • Yun-Zhe Zheng

    (Key Laboratory of Polar Materials and Devices (MOE), Department of Electronics, East China Normal University)

  • Fang-Ya Mu

    (East China Normal University)

  • Rong Huang

    (Key Laboratory of Polar Materials and Devices (MOE), Department of Electronics, East China Normal University)

  • Guo-Yue Shi

    (East China Normal University)

  • Yi-Yang Sun

    (State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences)

  • Xing-Hua Xia

    (Nanjing University)

  • Wei Chen

    (National University of Singapore
    National University of Singapore
    Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City)

Abstract

Tuning metal–support interaction has been considered as an effective approach to modulate the electronic structure and catalytic activity of supported metal catalysts. At the atomic level, the understanding of the structure–activity relationship still remains obscure in heterogeneous catalysis, such as the conversion of water (alkaline) or hydronium ions (acid) to hydrogen (hydrogen evolution reaction, HER). Here, we reveal that the fine control over the oxidation states of single-atom Pt catalysts through electronic metal–support interaction significantly modulates the catalytic activities in either acidic or alkaline HER. Combined with detailed spectroscopic and electrochemical characterizations, the structure–activity relationship is established by correlating the acidic/alkaline HER activity with the average oxidation state of single-atom Pt and the Pt–H/Pt–OH interaction. This study sheds light on the atomic-level mechanistic understanding of acidic and alkaline HER, and further provides guidelines for the rational design of high-performance single-atom catalysts.

Suggested Citation

  • Yi Shi & Zhi-Rui Ma & Yi-Ying Xiao & Yun-Chao Yin & Wen-Mao Huang & Zhi-Chao Huang & Yun-Zhe Zheng & Fang-Ya Mu & Rong Huang & Guo-Yue Shi & Yi-Yang Sun & Xing-Hua Xia & Wei Chen, 2021. "Electronic metal–support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-23306-6
    DOI: 10.1038/s41467-021-23306-6
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    1. Hao Shi & Tanyuan Wang & Jianyun Liu & Weiwei Chen & Shenzhou Li & Jiashun Liang & Shuxia Liu & Xuan Liu & Zhao Cai & Chao Wang & Dong Su & Yunhui Huang & Lior Elbaz & Qing Li, 2023. "A sodium-ion-conducted asymmetric electrolyzer to lower the operation voltage for direct seawater electrolysis," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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    3. Huaning Jiang & Weiwei Yang & Mingquan Xu & Erqing Wang & Yi Wei & Wei Liu & Xiaokang Gu & Lixuan Liu & Qian Chen & Pengbo Zhai & Xiaolong Zou & Pulickel M. Ajayan & Wu Zhou & Yongji Gong, 2022. "Single atom catalysts in Van der Waals gaps," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
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    6. Xiaoqing Yan & Mengyang Xia & Hanxuan Liu & Bin Zhang & Chunran Chang & Lianzhou Wang & Guidong Yang, 2023. "An electron-hole rich dual-site nickel catalyst for efficient photocatalytic overall water splitting," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Tianyu Zhang & Jing Jin & Junmei Chen & Yingyan Fang & Xu Han & Jiayi Chen & Yaping Li & Yu Wang & Junfeng Liu & Lei Wang, 2022. "Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    8. Rui Wu & Jie Xu & Chuan-Lin Zhao & Xiao-Zhi Su & Xiao-Long Zhang & Ya-Rong Zheng & Feng-Yi Yang & Xu-Sheng Zheng & Jun-Fa Zhu & Jun Luo & Wei-Xue Li & Min-Rui Gao & Shu-Hong Yu, 2023. "Dopant triggered atomic configuration activates water splitting to hydrogen," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    9. Kenichi Endo & Masaki Saruyama & Toshiharu Teranishi, 2023. "Location-selective immobilisation of single-atom catalysts on the surface or within the interior of ionic nanocrystals using coordination chemistry," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Zhenglong Fan & Fan Liao & Yujin Ji & Yang Liu & Hui Huang & Dan Wang & Kui Yin & Haiwei Yang & Mengjie Ma & Wenxiang Zhu & Meng Wang & Zhenhui Kang & Youyong Li & Mingwang Shao & Zhiwei Hu & Qi Shao, 2022. "Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Dong Cao & Haoxiang Xu & Hongliang Li & Chen Feng & Jie Zeng & Daojian Cheng, 2022. "Volcano-type relationship between oxidation states and catalytic activity of single-atom catalysts towards hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    12. Jiachen Li & Yuqiang Ma & Cong Zhang & Chi Zhang & Huijun Ma & Zhaoqi Guo & Ning Liu & Ming Xu & Haixia Ma & Jieshan Qiu, 2023. "Green electrosynthesis of 3,3’-diamino-4,4’-azofurazan energetic materials coupled with energy-efficient hydrogen production over Pt-based catalysts," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    13. Yanghang Pan & Xinzhu Wang & Weiyang Zhang & Lingyu Tang & Zhangyan Mu & Cheng Liu & Bailin Tian & Muchun Fei & Yamei Sun & Huanhuan Su & Libo Gao & Peng Wang & Xiangfeng Duan & Jing Ma & Mengning Din, 2022. "Boosting the performance of single-atom catalysts via external electric field polarization," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

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