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Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density

Author

Listed:
  • Panlong Zhai

    (Dalian University of Technology)

  • Chen Wang

    (Dalian University of Technology)

  • Yuanyuan Zhao

    (Dalian University of Technology)

  • Yanxue Zhang

    (Dalian University of Technology)

  • Junfeng Gao

    (Dalian University of Technology)

  • Licheng Sun

    (Westlake University
    Biotechnology and Health KTH Royal Institute of Technology)

  • Jungang Hou

    (Dalian University of Technology)

Abstract

Rational design efficient transition metal-based electrocatalysts for oxygen evolution reaction (OER) is critical for water splitting. However, industrial water-alkali electrolysis requires large current densities at low overpotentials, always limited by intrinsic activity. Herein, we report hierarchical bimetal nitride/hydroxide (NiMoN/NiFe LDH) array as model catalyst, regulating the electronic states and tracking the relationship of structure-activity. As-activated NiMoN/NiFe LDH exhibits the industrially required current density of 1000 mA cm−2 at overpotential of 266 mV with 250 h stability for OER. Especially, in-situ electrochemical spectroscopic reveals that heterointerface facilitates dynamic structure evolution to optimize electronic structure. Operando electrochemical impedance spectroscopy implies accelerated OER kinetics and intermediate evolution due to fast charge transport. The OER mechanism is revealed by the combination of theoretical and experimental studies, indicating as-activated NiMoN/NiFe LDH follows lattice oxygen oxidation mechanism with accelerated kinetics. This work paves an avenue to develop efficient catalysts for industrial water electrolysis via tuning electronic states.

Suggested Citation

  • Panlong Zhai & Chen Wang & Yuanyuan Zhao & Yanxue Zhang & Junfeng Gao & Licheng Sun & Jungang Hou, 2023. "Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37091-x
    DOI: 10.1038/s41467-023-37091-x
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    References listed on IDEAS

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    1. Panlong Zhai & Mingyue Xia & Yunzhen Wu & Guanghui Zhang & Junfeng Gao & Bo Zhang & Shuyan Cao & Yanting Zhang & Zhuwei Li & Zhaozhong Fan & Chen Wang & Xiaomeng Zhang & Jeffrey T. Miller & Licheng Su, 2021. "Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
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    5. Zuyun He & Jun Zhang & Zhiheng Gong & Hang Lei & Deng Zhou & Nian Zhang & Wenjie Mai & Shijun Zhao & Yan Chen, 2022. "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
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    2. Shujiao Yang & Kaihang Yue & Xiaohan Liu & Sisi Li & Haoquan Zheng & Ya Yan & Rui Cao & Wei Zhang, 2024. "Electrocatalytic water oxidation with manganese phosphates," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Xiaogang Sun & Wei Shen & Hao Liu & Pinxian Xi & Mietek Jaroniec & Yao Zheng & Shi-Zhang Qiao, 2024. "Corrosion-resistant NiFe anode towards kilowatt-scale alkaline seawater electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Chen Wang & Chaoyuan Deng & Panlong Zhai & Xiaoran Shi & Wei Liu & Dingfeng Jin & Bing Shang & Junfeng Gao & Licheng Sun & Jungang Hou, 2025. "Tracking the correlation between spintronic structure and oxygen evolution reaction mechanism of cobalt-ruthenium-based electrocatalyst," Nature Communications, Nature, vol. 16(1), pages 1-13, December.
    5. Ling Zhou & Daying Guo & Lianhui Wu & Zhixi Guan & Chao Zou & Huile Jin & Guoyong Fang & Xi’an Chen & Shun Wang, 2024. "A restricted dynamic surface self-reconstruction toward high-performance of direct seawater oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Cai, Jiajia & Tang, Xiangxuan & Wang, Jianmin & Zhang, Tingting & Xie, Qian & Mao, Keke & Li, Song & Qin, Gaowu, 2024. "Self-driving photothermal anode electrocatalyst towards the robust OER for water electrolysis," Renewable Energy, Elsevier, vol. 232(C).
    7. Yizhen Lu & Bixuan Li & Na Xu & Zhihua Zhou & Yu Xiao & Yu Jiang & Teng Li & Sheng Hu & Yongji Gong & Yang Cao, 2023. "One-atom-thick hexagonal boron nitride co-catalyst for enhanced oxygen evolution reactions," Nature Communications, Nature, vol. 14(1), pages 1-8, December.

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