IDEAS home Printed from https://ideas.repec.org/a/nat/natene/v1y2016i10d10.1038_nenergy.2016.130.html
   My bibliography  Save this article

Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene

Author

Listed:
  • Yan Jiao

    (School of Chemical Engineering, The University of Adelaide)

  • Yao Zheng

    (School of Chemical Engineering, The University of Adelaide)

  • Kenneth Davey

    (School of Chemical Engineering, The University of Adelaide)

  • Shi-Zhang Qiao

    (School of Chemical Engineering, The University of Adelaide)

Abstract

The hydrogen evolution reaction (HER) is a fundamental process in electrocatalysis and plays an important role in energy conversion through water splitting to produce hydrogen. Effective candidates for HER are often based on noble metals or transition metal dichalcogenides, while carbon-based metal-free electrocatalysts generally demonstrate poorer activity. Here we report evaluation of a series of heteroatom-doped graphene materials as efficient HER electrocatalysts by combining spectroscopic characterization, electrochemical measurements, and density functional theory calculations. Results of theoretical computations are shown to be in good agreement with experimental observations regarding the intrinsic electrocatalytic activity and the HER reaction mechanism. As a result, we establish a HER activity trend for graphene-based materials, and explore their reactivity origin to guide the design of more efficient electrocatalysts. We predict that by rationally modifying particular experimentally achievable physicochemical characteristics, a practically realizable graphene-based material will have the potential to exceed the performance of the metal-based benchmark for HER.

Suggested Citation

  • Yan Jiao & Yao Zheng & Kenneth Davey & Shi-Zhang Qiao, 2016. "Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene," Nature Energy, Nature, vol. 1(10), pages 1-9, October.
  • Handle: RePEc:nat:natene:v:1:y:2016:i:10:d:10.1038_nenergy.2016.130
    DOI: 10.1038/nenergy.2016.130
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/nenergy2016130
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.

    File URL: https://libkey.io/10.1038/nenergy.2016.130?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Bohua Ren & Guobin Wen & Rui Gao & Dan Luo & Zhen Zhang & Weibin Qiu & Qianyi Ma & Xin Wang & Yi Cui & Luis Ricardez–Sandoval & Aiping Yu & Zhongwei Chen, 2022. "Nano-crumples induced Sn-Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Zengyao Wang & Jiyi Chen & Erhong Song & Ning Wang & Juncai Dong & Xiang Zhang & Pulickel M. Ajayan & Wei Yao & Chenfeng Wang & Jianjun Liu & Jianfeng Shen & Mingxin Ye, 2021. "Manipulation on active electronic states of metastable phase β-NiMoO4 for large current density hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    3. Yinghao Li & Chun-Kuo Peng & Huimin Hu & San-Yuan Chen & Jin-Ho Choi & Yan-Gu Lin & Jong-Min Lee, 2022. "Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Lee, Seung Jun & Theerthagiri, Jayaraman & Nithyadharseni, Palaniyandy & Arunachalam, Prabhakarn & Balaji, Dhandapani & Madan Kumar, Arumugam & Madhavan, Jagannathan & Mittal, Vikas & Choi, Myong Yong, 2021. "Heteroatom-doped graphene-based materials for sustainable energy applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    5. Chao Ye & Huanyu Jin & Jieqiong Shan & Yan Jiao & Huan Li & Qinfen Gu & Kenneth Davey & Haihui Wang & Shi-Zhang Qiao, 2021. "A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natene:v:1:y:2016:i:10:d:10.1038_nenergy.2016.130. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.