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Research on Quantitative Diagnosis of Dendrites Based on Titration Gas Chromatography Technology

Author

Listed:
  • Kai Yang

    (China Electric Power Research Institute, Beijing 100192, China)

  • Hongchang Cai

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

  • Suran Li

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

  • Yu Wang

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

  • Xue Zhang

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

  • Zhenxuan Wu

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

  • Yilin Lai

    (China Electric Power Research Institute, Beijing 100192, China)

  • Minella Bezha

    (International Infrastructure System Research Center, Power System Analysis Laboratory, Doshisha University, Kyoto 610-0321, Japan)

  • Klara Bezha

    (Graduate School of Science and Engineering, IIST, Intelligent Robotics Laboratory, Hosei University, Tokyo 184-8584, Japan)

  • Naoto Nagaoka

    (International Infrastructure System Research Center, Power System Analysis Laboratory, Doshisha University, Kyoto 610-0321, Japan)

  • Yuejiu Zheng

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

  • Xuning Feng

    (State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China)

Abstract

Lithium plating can cause capacity fade and thermal runaway safety issues in lithium-ion batteries. Therefore, accurately detecting the amount of lithium plating on the surface of the battery’s negative electrode is crucial for battery safety. This is especially crucial in high-energy-density applications such as battery energy storage systems or in electric vehicles (EVs). Early detection of lithium plating is crucial for evaluation of reliability and longevity. It also serves as a method for early diagnostics in practical industrial applications or infrastructure, such as EV transportation. This can enhance its impact on customers. This study validates the effectiveness of titration gas chromatography (TGC) technology in quantitatively detecting lithium plating on graphite negative electrodes in lithium-ion batteries. The results show that it can detect a minimum of 2.4 μmol of metallic lithium. Compared with the heating direct current resistance and reference electrode methods, which can be used to perform only qualitative dendrite detection, TGC has a wider range of detection. Compared with the nuclear magnetic resonance (NMR) method with higher quantitative detection accuracy, the maximum difference between the detection results of the two methods was only 7.2%, but the TGC method had lower cost and higher implementation convenience. In summary, among various dendrite detection methods, the TGC method can not only realize the effective quantitative detection of lithium plating, but also comprehensively consider its detection range, implementation convenience, cost, and detection accuracy, indicating that it is suitable for engineering applications and has the prospect of realizing large-scale quantitative detection of lithium plating in lithium-ion batteries.

Suggested Citation

  • Kai Yang & Hongchang Cai & Suran Li & Yu Wang & Xue Zhang & Zhenxuan Wu & Yilin Lai & Minella Bezha & Klara Bezha & Naoto Nagaoka & Yuejiu Zheng & Xuning Feng, 2024. "Research on Quantitative Diagnosis of Dendrites Based on Titration Gas Chromatography Technology," Energies, MDPI, vol. 17(10), pages 1-19, May.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:10:p:2409-:d:1396514
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    References listed on IDEAS

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    1. Xintong Yuan & Bo Liu & Matthew Mecklenburg & Yuzhang Li, 2023. "Ultrafast deposition of faceted lithium polyhedra by outpacing SEI formation," Nature, Nature, vol. 620(7972), pages 86-91, August.
    2. Chengcheng Fang & Jinxing Li & Minghao Zhang & Yihui Zhang & Fan Yang & Jungwoo Z. Lee & Min-Han Lee & Judith Alvarado & Marshall A. Schroeder & Yangyuchen Yang & Bingyu Lu & Nicholas Williams & Migue, 2019. "Quantifying inactive lithium in lithium metal batteries," Nature, Nature, vol. 572(7770), pages 511-515, August.
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