IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-39636-6.html
   My bibliography  Save this article

Dynamic gel as artificial interphase layer for ultrahigh-rate and large-capacity lithium metal anode

Author

Listed:
  • Chao Chen

    (South China University of Technology)

  • Jiaming Zhang

    (South China University of Technology)

  • Benrui Hu

    (South China University of Technology)

  • Qianwen Liang

    (South China University of Technology)

  • Xunhui Xiong

    (South China University of Technology)

Abstract

Constructing a stable artificial solid-electrolyte interphase has become one of the most effective strategies to overcome the poor reversibility of lithium metal anode, yet the protection role is still insufficient at elevated current densities over 10 mA cm−2 and large areal capacities over 10 mAh cm−2. Herein, we propose a dynamic gel with reversible imine groups, which is prepared via a cross linking reaction between flexible dibenzaldehyde-terminated telechelic poly(ethylene glycol) and rigid chitosan, to fabricate a protective layer for Li metal anode. The as-prepared artificial film shows combined merits of high Young’s modulus, strong ductility and high ionic conductivity. When the artificial film is fabricated on a lithium metal anode, the thin protective layer shows a dense and uniform surface owing to the interactions between the abundant polar groups and lithium metal. Besides, the polar groups in the artificial film can homogenize the distribution of Li+ at the electrode/electrolyte interface. As a result, cycle stability over 3200 h under an areal capacity of 10 mAh cm−2 and a current density of 10 mA cm−2 has been obtained for the protected lithium metal anodes. Moreover, cycling stability and rate capability has been also improved in the full cells.

Suggested Citation

  • Chao Chen & Jiaming Zhang & Benrui Hu & Qianwen Liang & Xunhui Xiong, 2023. "Dynamic gel as artificial interphase layer for ultrahigh-rate and large-capacity lithium metal anode," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39636-6
    DOI: 10.1038/s41467-023-39636-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-39636-6
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-39636-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Snehashis Choudhury & Rahul Mangal & Akanksha Agrawal & Lynden A. Archer, 2015. "A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles," Nature Communications, Nature, vol. 6(1), pages 1-9, December.
    2. Chunpeng Yang & Qisheng Wu & Weiqi Xie & Xin Zhang & Alexandra Brozena & Jin Zheng & Mounesha N. Garaga & Byung Hee Ko & Yimin Mao & Shuaiming He & Yue Gao & Pengbo Wang & Madhusudan Tyagi & Feng Jiao, 2021. "Copper-coordinated cellulose ion conductors for solid-state batteries," Nature, Nature, vol. 598(7882), pages 590-596, October.
    3. Chengcheng Fang & Jinxing Li & Minghao Zhang & Yihui Zhang & Fan Yang & Jungwoo Z. Lee & Min-Han Lee & Judith Alvarado & Marshall A. Schroeder & Yangyuchen Yang & Bingyu Lu & Nicholas Williams & Migue, 2019. "Quantifying inactive lithium in lithium metal batteries," Nature, Nature, vol. 572(7770), pages 511-515, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Pietro Iurilli & Luigi Luppi & Claudio Brivio, 2022. "Non-Invasive Detection of Lithium-Metal Battery Degradation," Energies, MDPI, vol. 15(19), pages 1-14, September.
    2. Kai Yang & Hongchang Cai & Suran Li & Yu Wang & Xue Zhang & Zhenxuan Wu & Yilin Lai & Minella Bezha & Klara Bezha & Naoto Nagaoka & Yuejiu Zheng & Xuning Feng, 2024. "Research on Quantitative Diagnosis of Dendrites Based on Titration Gas Chromatography Technology," Energies, MDPI, vol. 17(10), pages 1-19, May.
    3. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Matthew Sadd & Shizhao Xiong & Jacob R. Bowen & Federica Marone & Aleksandar Matic, 2023. "Investigating microstructure evolution of lithium metal during plating and stripping via operando X-ray tomographic microscopy," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Xiansheng Zhang & Hongwei Yan & Chongzhi Xu & Xia Dong & Yu Wang & Aiping Fu & Hao Li & Jin Yong Lee & Sheng Zhang & Jiahua Ni & Min Gao & Jing Wang & Jinpeng Yu & Shuzhi Sam Ge & Ming Liang Jin & Lil, 2023. "Skin-like cryogel electronics from suppressed-freezing tuned polymer amorphization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Jine Wu & Chenyi Liao & Tianyu Li & Jing Zhou & Linjuan Zhang & Jian-Qiang Wang & Guohui Li & Xianfeng Li, 2023. "Metal-coordinated polybenzimidazole membranes with preferential K+ transport," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    8. Jiaqi Cao & Yuansheng Shi & Aosong Gao & Guangyuan Du & Muhtar Dilxat & Yongfei Zhang & Mohang Cai & Guoyu Qian & Xueyi Lu & Fangyan Xie & Yang Sun & Xia Lu, 2024. "Hierarchical Li electrochemistry using alloy-type anode for high-energy-density Li metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    9. Ruirui Zhao & Haifeng Wang & Haoran Du & Ying Yang & Zhonghui Gao & Long Qie & Yunhui Huang, 2022. "Lanthanum nitrate as aqueous electrolyte additive for favourable zinc metal electrodeposition," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    10. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    11. Shuo Jin & Jiefu Yin & Xiaosi Gao & Arpita Sharma & Pengyu Chen & Shifeng Hong & Qing Zhao & Jingxu Zheng & Yue Deng & Yong Lak Joo & Lynden A. Archer, 2022. "Production of fast-charge Zn-based aqueous batteries via interfacial adsorption of ion-oligomer complexes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    12. Yan Zhao & Tianhong Zhou & Timur Ashirov & Mario El Kazzi & Claudia Cancellieri & Lars P. H. Jeurgens & Jang Wook Choi & Ali Coskun, 2022. "Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Suting Weng & Xiao Zhang & Gaojing Yang & Simeng Zhang & Bingyun Ma & Qiuyan Liu & Yue Liu & Chengxin Peng & Huixin Chen & Hailong Yu & Xiulin Fan & Tao Cheng & Liquan Chen & Yejing Li & Zhaoxiang Wan, 2023. "Temperature-dependent interphase formation and Li+ transport in lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    14. Yanfei Zhu & Zhoujie Lao & Mengtian Zhang & Tingzheng Hou & Xiao Xiao & Zhihong Piao & Gongxun Lu & Zhiyuan Han & Runhua Gao & Lu Nie & Xinru Wu & Yanze Song & Chaoyuan Ji & Jian Wang & Guangmin Zhou, 2024. "A locally solvent-tethered polymer electrolyte for long-life lithium metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    15. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    16. Li Huang & Jian Gao & Zhijie Bi & Ning Zhao & Jipeng Wu & Qiu Fang & Xuefeng Wang & Yong Wan & Xiangxin Guo, 2022. "Comparative Study of Stability against Moisture for Solid Garnet Electrolytes with Different Dopants," Energies, MDPI, vol. 15(9), pages 1-9, April.
    17. Minglei Mao & Xiao Ji & Qiyu Wang & Zejing Lin & Meiying Li & Tao Liu & Chengliang Wang & Yong-Sheng Hu & Hong Li & Xuejie Huang & Liquan Chen & Liumin Suo, 2023. "Anion-enrichment interface enables high-voltage anode-free lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    18. Hanwen An & Menglu Li & Qingsong Liu & Yajie Song & Jiaxuan Liu & Zhihang Yu & Xingjiang Liu & Biao Deng & Jiajun Wang, 2024. "Strong Lewis-acid coordinated PEO electrolyte achieves 4.8 V-class all-solid-state batteries over 580 Wh kg−1," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    19. Xiao Zhan & Miao Li & Xiaolin Zhao & Yaning Wang & Sha Li & Weiwei Wang & Jiande Lin & Zi-Ang Nan & Jiawei Yan & Zhefei Sun & Haodong Liu & Fei Wang & Jiayu Wan & Jianjun Liu & Qiaobao Zhang & Li Zhan, 2024. "Self-assembled hydrated copper coordination compounds as ionic conductors for room temperature solid-state batteries," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    20. Qing Zhao & Yue Deng & Nyalaliska W. Utomo & Jingxu Zheng & Prayag Biswal & Jiefu Yin & Lynden A. Archer, 2021. "On the crystallography and reversibility of lithium electrodeposits at ultrahigh capacity," Nature Communications, Nature, vol. 12(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39636-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.