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A Comprehensive Survey of Alkaline Electrolyzer Modeling: Electrical Domain and Specific Electrolyte Conductivity

Author

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  • Frank Gambou

    (Group of Research in Electrical Engineering of Nancy (GREEN), Université de Lorraine, F-54000 Nancy, France)

  • Damien Guilbert

    (Group of Research in Electrical Engineering of Nancy (GREEN), Université de Lorraine, F-54000 Nancy, France)

  • Michel Zasadzinski

    (Research Center for Automatic Control of Nancy (CRAN), UMR CNRS 7039, Université de Lorraine, F-54000 Nancy, France)

  • Hugues Rafaralahy

    (Research Center for Automatic Control of Nancy (CRAN), UMR CNRS 7039, Université de Lorraine, F-54000 Nancy, France)

Abstract

Alkaline electrolyzers are the most widespread technology due to their maturity, low cost, and large capacity in generating hydrogen. However, compared to proton exchange membrane (PEM) electrolyzers, they request the use of potassium hydroxide (KOH) or sodium hydroxide (NaOH) since the electrolyte relies on a liquid solution. For this reason, the performances of alkaline electrolyzers are governed by the electrolyte concentration and operating temperature. Due to the growing development of the water electrolysis process based on alkaline electrolyzers to generate green hydrogen from renewable energy sources, the main purpose of this paper is to carry out a comprehensive survey on alkaline electrolyzers, and more specifically about their electrical domain and specific electrolytic conductivity. Besides, this survey will allow emphasizing the remaining key issues from the modeling point of view.

Suggested Citation

  • Frank Gambou & Damien Guilbert & Michel Zasadzinski & Hugues Rafaralahy, 2022. "A Comprehensive Survey of Alkaline Electrolyzer Modeling: Electrical Domain and Specific Electrolyte Conductivity," Energies, MDPI, vol. 15(9), pages 1-20, May.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:9:p:3452-:d:811558
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    References listed on IDEAS

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    2. Liang, Tao & Chen, Mengjing & Tan, Jianxin & Jing, Yanwei & Lv, Liangnian & Yang, Wenbo, 2024. "Large-scale off-grid wind power hydrogen production multi-tank combination operation law and scheduling strategy taking into account alkaline electrolyzer characteristics," Renewable Energy, Elsevier, vol. 232(C).
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    5. Wang, Jingbo & Wen, Jianfeng & Wang, Jiarong & Yang, Bo & Jiang, Lin, 2024. "Water electrolyzer operation scheduling for green hydrogen production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 203(C).
    6. Bożena Łosiewicz, 2024. "Technology for Green Hydrogen Production: Desk Analysis," Energies, MDPI, vol. 17(17), pages 1-41, September.
    7. Jae-Hoon Kim & Chang-Yeol Oh & Ki-Ryong Kim & Jong-Pil Lee & Tae-Jin Kim, 2022. "Parameter Identification of Electrical Equivalent Circuits including Mass Transfer Parameters for the Selection of the Operating Frequencies of Pulsed PEM Water Electrolysis," Energies, MDPI, vol. 15(24), pages 1-16, December.
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