IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i7p2573-d785084.html
   My bibliography  Save this article

Decarbonizing Natural Gas: A Review of Catalytic Decomposition and Carbon Formation Mechanisms

Author

Listed:
  • Sirui Tong

    (School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798, Singapore)

  • Bin Miao

    (Energy Research Institute at NTU (ERI@N), Nanyang Technological University, 1 CleanTech Loop, Singapore 637141, Singapore)

  • Lan Zhang

    (Energy Research Institute at NTU (ERI@N), Nanyang Technological University, 1 CleanTech Loop, Singapore 637141, Singapore)

  • Siew Hwa Chan

    (School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798, Singapore
    Energy Research Institute at NTU (ERI@N), Nanyang Technological University, 1 CleanTech Loop, Singapore 637141, Singapore)

Abstract

In the context of energy conservation and the reduction of CO 2 emissions, inconsistencies between the inevitable emission of CO 2 in traditional hydrogen production methods and eco-friendly targets have become more apparent over time. The catalytic decomposition of methane (CDM) is a novel technology capable of producing hydrogen without releasing CO 2 . Since hydrogen produced via CDM is neither blue nor green, the term “turquoise” is selected to describe this technology. Notably, the by-products of methane cracking are simply carbon deposits with different structures, which can offset the cost of hydrogen production cost should they be harvested. However, the encapsulation of catalysts by such carbon deposits reduces the contact area between said catalysts and methane throughout the CDM process, thereby rendering the continuous production of hydrogen impossible. This paper mainly covers the CDM reaction mechanisms of the three common metal-based catalysts (Ni, Co, Fe) from experimental and modelling approaches. The by-products of carbon modality and the key parameters that affect the carbon formation mechanisms are also discussed.

Suggested Citation

  • Sirui Tong & Bin Miao & Lan Zhang & Siew Hwa Chan, 2022. "Decarbonizing Natural Gas: A Review of Catalytic Decomposition and Carbon Formation Mechanisms," Energies, MDPI, vol. 15(7), pages 1-30, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:7:p:2573-:d:785084
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/7/2573/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/7/2573/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Malek Msheik & Sylvain Rodat & Stéphane Abanades, 2021. "Methane Cracking for Hydrogen Production: A Review of Catalytic and Molten Media Pyrolysis," Energies, MDPI, vol. 14(11), pages 1-35, May.
    2. Song, Chunfeng & Liu, Qingling & Ji, Na & Kansha, Yasuki & Tsutsumi, Atsushi, 2015. "Optimization of steam methane reforming coupled with pressure swing adsorption hydrogen production process by heat integration," Applied Energy, Elsevier, vol. 154(C), pages 392-401.
    3. Cai, Lei & He, Tianzhi & Xiang, Yanlei & Guan, Yanwen, 2020. "Study on the reaction pathways of steam methane reforming for H2 production," Energy, Elsevier, vol. 207(C).
    4. Irfan, Muhammad F. & Usman, Muhammad R. & Kusakabe, K., 2011. "Coal gasification in CO2 atmosphere and its kinetics since 1948: A brief review," Energy, Elsevier, vol. 36(1), pages 12-40.
    5. Barelli, L. & Bidini, G. & Gallorini, F. & Servili, S., 2008. "Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review," Energy, Elsevier, vol. 33(4), pages 554-570.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sanusi, Yinka S. & Mokheimer, Esmail M.A., 2019. "Thermo-economic optimization of hydrogen production in a membrane-SMR integrated to ITM-oxy-combustion plant using genetic algorithm," Applied Energy, Elsevier, vol. 235(C), pages 164-176.
    2. Msheik, Malek & Rodat, Sylvain & Abanades, Stéphane, 2022. "Experimental comparison of solar methane pyrolysis in gas-phase and molten-tin bubbling tubular reactors," Energy, Elsevier, vol. 260(C).
    3. Lee, Sung-Wook & Park, Jong-Soo & Lee, Chun-Boo & Lee, Dong-Wook & Kim, Hakjoo & Ra, Ho Won & Kim, Sung-Hyun & Ryi, Shin-Kun, 2014. "H2 recovery and CO2 capture after water–gas shift reactor using synthesis gas from coal gasification," Energy, Elsevier, vol. 66(C), pages 635-642.
    4. Rahimpour, M.R. & Mirvakili, A. & Paymooni, K., 2011. "A novel water perm-selective membrane dual-type reactor concept for Fischer–Tropsch synthesis of GTL (gas to liquid) technology," Energy, Elsevier, vol. 36(2), pages 1223-1235.
    5. Ján Kačur & Marek Laciak & Milan Durdán & Patrik Flegner, 2023. "Investigation of Underground Coal Gasification in Laboratory Conditions: A Review of Recent Research," Energies, MDPI, vol. 16(17), pages 1-55, August.
    6. Im-orb, Karittha & Simasatitkul, Lida & Arpornwichanop, Amornchai, 2016. "Techno-economic analysis of the biomass gasification and Fischer–Tropsch integrated process with off-gas recirculation," Energy, Elsevier, vol. 94(C), pages 483-496.
    7. Barelli, L. & Ottaviano, A., 2014. "Solid oxide fuel cell technology coupled with methane dry reforming: A viable option for high efficiency plant with reduced CO2 emissions," Energy, Elsevier, vol. 71(C), pages 118-129.
    8. Ding, Haoran & Tong, Sirui & Qi, Zhifu & Liu, Fei & Sun, Shien & Han, Long, 2023. "Syngas production from chemical-looping steam methane reforming: The effect of channel geometry on BaCoO3/CeO2 monolithic oxygen carriers," Energy, Elsevier, vol. 263(PE).
    9. Duan, Zhengxiao & Zhang, Yanni & Deng, Jun & Shu, Pan & Yao, Di, 2023. "A systematic exploration of mapping knowledge domains for free radical research related to coal," Energy, Elsevier, vol. 282(C).
    10. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    11. Prabu, V. & Geeta, K., 2015. "CO2 enhanced in-situ oxy-coal gasification based carbon-neutral conventional power generating systems," Energy, Elsevier, vol. 84(C), pages 672-683.
    12. Prabowo, Bayu & Aziz, Muhammad & Umeki, Kentaro & Susanto, Herri & Yan, Mi & Yoshikawa, Kunio, 2015. "CO2-recycling biomass gasification system for highly efficient and carbon-negative power generation," Applied Energy, Elsevier, vol. 158(C), pages 97-106.
    13. He, Yahui & Li, Xiaofu & Meng, Li & Zhang, Wenqi & Wang, Yinfeng & Wang, Lei & Bi, Xiaotao & Zhu, Yuezhao, 2024. "Experimental investigation on high-temperature co-gasification and melting behavior of petrochemical sludge and bituminous coal in CO2 atmosphere," Energy, Elsevier, vol. 303(C).
    14. Zhao, Jingyu & Deng, Jun & Wang, Tao & Song, Jiajia & Zhang, Yanni & Shu, Chi-Min & Zeng, Qiang, 2019. "Assessing the effectiveness of a high-temperature-programmed experimental system for simulating the spontaneous combustion properties of bituminous coal through thermokinetic analysis of four oxidatio," Energy, Elsevier, vol. 169(C), pages 587-596.
    15. Samuel C. Bayham & Andrew Tong & Mandar Kathe & Liang-Shih Fan, 2016. "Chemical looping technology for energy and chemical production," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(2), pages 216-241, March.
    16. Byun, Manhee & Kim, Heehyang & Lee, Hyunjun & Lim, Dongjun & Lim, Hankwon, 2022. "Conceptual design for methanol steam reforming in serial packed-bed reactors and membrane filters: Economic and environmental perspectives," Energy, Elsevier, vol. 241(C).
    17. Kareemulla, Dudekula & Gusev, Sergey & Bhattacharya, Sankar & Mahajani, Sanjay M., 2024. "Entrained-flow pyrolysis and (co-)gasification characteristics of Indian high-ash coals," Energy, Elsevier, vol. 294(C).
    18. Salem, Ahmed M. & Abd Elbar, Ayman Refat, 2023. "The feasibility and performance of using producer gas as a gasifying medium," Energy, Elsevier, vol. 283(C).
    19. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
    20. Ziębik, Andrzej & Malik, Tomasz & Liszka, Marcin, 2015. "Thermodynamic evaluation of CHP (combined heat and power) plants integrated with installations of coal gasification," Energy, Elsevier, vol. 92(P2), pages 179-188.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:7:p:2573-:d:785084. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.