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Recent Advances in Methane Pyrolysis: Turquoise Hydrogen with Solid Carbon Production

Author

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  • Tamás I. Korányi

    (Department of Surface Chemistry and Catalysis, Institute for Energy Security and Environmental Safety, Centre for Energy Research, Konkoly-Thege M. u. 29-33, 1121 Budapest, Hungary)

  • Miklós Németh

    (Department of Surface Chemistry and Catalysis, Institute for Energy Security and Environmental Safety, Centre for Energy Research, Konkoly-Thege M. u. 29-33, 1121 Budapest, Hungary)

  • Andrea Beck

    (Department of Surface Chemistry and Catalysis, Institute for Energy Security and Environmental Safety, Centre for Energy Research, Konkoly-Thege M. u. 29-33, 1121 Budapest, Hungary)

  • Anita Horváth

    (Department of Surface Chemistry and Catalysis, Institute for Energy Security and Environmental Safety, Centre for Energy Research, Konkoly-Thege M. u. 29-33, 1121 Budapest, Hungary)

Abstract

Beside steam reforming, methane pyrolysis is an alternative method for hydrogen production. ‘Turquoise’ hydrogen with solid carbon is formed in the pyrolysis process, contrary to ‘grey’ or ‘blue’ hydrogen via steam methane reforming, where waste carbon dioxide is produced. Thermal pyrolysis is conducted at higher temperatures, but catalytic decomposition of methane (CDM) is a promising route for sustainable hydrogen production. CDM is generally carried out over four types of catalyst: nickel, carbon, noble metal and iron. The applied reactors can be fixed bed, fluidized bed, plasma bed or molten-metal reactors. Two main advantages of CDM are that (i) carbon-oxide free hydrogen, ideal for fuel cell applications, is formed and (ii) the by-product can be tailored into carbon with advanced morphology (e.g., nanofibers, nanotubes). The aim of this review is to reveal the very recent research advances of the last two years achieved in the field of this promising prospective technology.

Suggested Citation

  • Tamás I. Korányi & Miklós Németh & Andrea Beck & Anita Horváth, 2022. "Recent Advances in Methane Pyrolysis: Turquoise Hydrogen with Solid Carbon Production," Energies, MDPI, vol. 15(17), pages 1-14, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6342-:d:902344
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    References listed on IDEAS

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    1. Malek Msheik & Sylvain Rodat & Stéphane Abanades, 2021. "Methane Cracking for Hydrogen Production: A Review of Catalytic and Molten Media Pyrolysis," Energies, MDPI, vol. 14(11), pages 1-35, May.
    2. Jinho Boo & Eun Hee Ko & No-Kuk Park & Changkook Ryu & Yo-Han Kim & Jinmo Park & Dohyung Kang, 2021. "Methane Pyrolysis in Molten Potassium Chloride: An Experimental and Economic Analysis," Energies, MDPI, vol. 14(23), pages 1-15, December.
    3. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
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    5. Dong Kyoo Park & Ji-Hyeon Kim & Hyo-Sik Kim & Jin-Ho Kim & Jae-Hong Ryu, 2023. "Possibility Study in CO 2 Free Hydrogen Production Using Dodecane (C 12 H 26 ) from Plasma Reaction," Energies, MDPI, vol. 16(4), pages 1-13, February.
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