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A Review on Deactivation and Regeneration of Catalysts for Dimethyl Ether Synthesis

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  • Joanna Sobczak

    (Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

  • Izabela Wysocka

    (Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

  • Stanisław Murgrabia

    (Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

  • Andrzej Rogala

    (Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

Abstract

The deactivation of catalysts and their regeneration are two very important challenges that need to be addressed for many industrial processes. The most quoted reasons for the deterioration of dimethyl ether synthesis (DME) concern the sintering and the hydrothermal leaching of copper particles, their migration to acid sites, the partial formation of copper and zinc hydroxycarbonates, the formation of carbon deposits, and surface contamination with undesirable compounds present in syngas. This review summarises recent findings in the field of DME catalyst deactivation and regeneration. The most-used catalysts, their modifications, along with a comparison of the basic parameters, deactivation approaches, and regeneration methods are presented.

Suggested Citation

  • Joanna Sobczak & Izabela Wysocka & Stanisław Murgrabia & Andrzej Rogala, 2022. "A Review on Deactivation and Regeneration of Catalysts for Dimethyl Ether Synthesis," Energies, MDPI, vol. 15(15), pages 1-39, July.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5420-:d:872872
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    References listed on IDEAS

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    3. Dagde Kenneth Kekpugile & Harry Uduak Sylvanus, 2016. "Modeling of a Tubular Fixed-Bed Reactor for the Production of Dimethyl Ether Using Alumina Catalyst," International Journal of Chemical and Process Engineering Research, Conscientia Beam, vol. 3(2), pages 23-34.
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