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Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation

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  • Chen, Wei-Hsin
  • Lin, Shih-Cheng

Abstract

The reaction phenomena of CPOM (catalytic partial oxidation of methane) in a Swiss-roll reactor are studied numerically where a rhodium-based catalyst bed is embedded at the center of the reactor. CO2 is added into the feed gas and excess enthalpy recovery is performed to evaluate their influences on CPOM performance. In the study, the mole ratio of O2 to CH4 (O2/CH4 ratio) is fixed at 0.5 and the mole ratio of CO2 to O2 (CO2/O2 ratio) is in the range of 0–2. The results reveal that CO2 addition into the influent has a slight effect on methane combustion, but significantly enhances dry reforming and suppresses steam reforming. The reaction extents of steam reforming and dry reforming in CPOM without heat recovery and CO2 addition are in a comparable state. Once CO2 is added into the feed gas, the dry reforming is enhanced, thereby dominating CH4 consumption. Compared to the reactor without excess enthalpy recovery, heat recirculation drastically increases the maximum reaction temperature and CH4 conversion in the catalyst bed; it also intensifies the H2 selectivity, H2 yield, CO2 conversion, and syngas production rate. The predictions indicate that the heat recirculation is able to improve the syngas formation up to 45%.

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  • Chen, Wei-Hsin & Lin, Shih-Cheng, 2015. "Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation," Energy, Elsevier, vol. 82(C), pages 206-217.
    • Handle: RePEc:eee:energy:v:82:y:2015:i:c:p:206-217
    DOI: 10.1016/j.energy.2015.01.031
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    1. Choudhary, Vasant R. & Mondal, Kartick C., 2006. "CO2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO3 perovskite-type mixed metal-oxide catalyst," Applied Energy, Elsevier, vol. 83(9), pages 1024-1032, September.
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    9. Wan, Jianlong & Zhao, Haibo, 2017. "Dynamics of premixed CH4/air flames in a micro combustor with a plate flame holder and preheating channels," Energy, Elsevier, vol. 139(C), pages 366-379.
    10. Peng, Qingguo & Yang, Wenming & E, Jiaqiang & Li, Shaobo & Li, Zhenwei & Xu, Hongpeng & Fu, Guang, 2021. "Effects of propane addition and burner scale on the combustion characteristics and working performance," Applied Energy, Elsevier, vol. 285(C).
    11. Wang, Yuqing & Zeng, Hongyu & Shi, Yixiang & Cao, Tianyu & Cai, Ningsheng & Ye, Xiaofeng & Wang, Shaorong, 2016. "Power and heat co-generation by micro-tubular flame fuel cell on a porous media burner," Energy, Elsevier, vol. 109(C), pages 117-123.
    12. Wan, Jianlong & Zhao, Haibo, 2018. "Thermal performance of solid walls in a mesoscale combustor with a plate flame holder and preheating channels," Energy, Elsevier, vol. 157(C), pages 448-459.
    13. Wan, Jianlong & Fan, Aiwu & Yao, Hong & Liu, Wei, 2015. "Effect of pressure on the blow-off limits of premixed CH4/air flames in a mesoscale cavity-combustor," Energy, Elsevier, vol. 91(C), pages 102-109.
    14. Chen, Wei-Hsin & Li, Shu-Cheng & Lim, Steven & Chen, Zih-Yu & Juan, Joon Ching, 2021. "Reaction and hydrogen production phenomena of ethanol steam reforming in a catalytic membrane reactor," Energy, Elsevier, vol. 220(C).
    15. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).

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